Messersmith PB, Giannelis EP (1995) Synthesis and barrier properties of poly(e-caprolactone)-layered silicate nanocomposites. J Polym Sci Part A: Polym Chem 33:1047-1057
Albertsson AC (2002) Degradable aliphatic polyesters. Adv Polym Sci 157:1-179
Dubois P (2000) Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater Sci Eng R 28:1-63
Bergaya F, Theng BKG, Lagaly G (2006) Handbook of clay science. Developments in Clay Science Editor, Oxford
Benali S, Olivier A, Brocorens P et al (2008) Fire and gas barrier properties of poly(styreneco-acrylonitrile) nanocomposites using polycaprolactone/clay nanohybrid based-masterbatch. Adv Mater Sci Eng 11. doi:10.1155/2008/394235
Urbanczyk L, Calberg C, Benali S et al (2008) Poly(caprolactone)/clay masterbatches prepared in supercritical CO2 as efficient clay delamination promoters in poly(styreneco-acrylonitrile). J Mater Chem 18:4623-4630
Urbanczyk L, Calberg C, Stassin F et al (2008) Synthesis of PCL/clay masterbatches in supercritical carbon dioxide. Polymer 49:3979-3986
Benali S, Peeterbroeck S, Brocorens P et al (2008) Chlorinated polyethylene nanocomposites using PCL/clay nanohybrid masterbatches. Eur Polym J 44:1673-1685
Broekaert C, Peeterbroeck S, Benali S et al (2007) Chlorinated polyethylene/layered silicate nanocomposites: poly(e-caprolactone)-based "masterbatch" approach. Eur Polym J 43: 4160-4168
Brocorens P, Benali S, Broekaert C et al (2008) Microscopic morphology of chlorinated polyethylene-based nanocomposites synthesized from poly(e-caprolactone)/clay masterbatches. Langmuir 24:2072-2080
Brigatti MF, Galan E, Theng BKG (2006) Structures and mineralogy of clay minerals. In: ES Ltd Handbook of clay science. Elsevier Science, Oxford
Sinha Ray S, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28:1539-1641
Pollet E, Paul M-A, Dubois P (2003) New aliphatic polyester layered silicate nanocomposites. In: Chiellini E, Solaro R (eds) Biodegradable polymers and plastics. Klumer Academic, Plenum Publishers, New-York
Lepoittevin B, Pantoustier N, Devalckenaere M et al (2002) Poly(e-caprolactone)/clay nanocomposites by in situ intercalative polymerization catalyzed by dibutyltin dimethoxide. Macromolecules 35:8385-8390
Tartaglione G, Tabuani D, Camino G et al (2008) PP and PBT composites filled with sepiolite: morphology and thermal behaviour. Compos Sci Technol 68:451-460
Fukushima K, Tabuani D, Camino G (2009) Nanocomposites of PLA and PCL based on montmorillonite and sepiolite. Mater Sci Eng C 29:1433-1441
Duquesne E, Moins S, Alexandre M et al (2007) How can nanohybrids enhance polyester/ sepiolite nanocomposite properties? Macromol Chem Phys 208:2542-2550
Liu Q, Peng Z, Chen D (2007) Nonisothermal crystallization behavior of poly(ecaprolactone)/ attapulgite nanocomposites by DSC analysis. Polym Eng Sci 47:460-466
Liu Q, Chen D (2008) Viscoelastic behaviors of poly(e-caprolactone)/attapulgite nanocomposites. Eur Polym J 44:2046-2050
Chen J, Wang H, Luo W et al (2010) Preparation of poly (e-caprolactone)@attapulgite nanocomposites via a combination of controlled ring-opening polymerization and click chemistry. Colloid Polym Sci 288:173-179
Messersmith PB, Giannelis EP (1993) Polymer-layered silicate nanocomposites: in situ intercalative polymerization of ε-caprolactone in layered silicates. Chem Mater 5:1064-1066
Gardebien F, Gaudel-Siri A, Bredas J-L et al (2004) Molecular dynamics simulations of intercalated poly(e-Caprolactone)-montmorillonite clay nanocomposites. J Phys Chem B 108:10678-10686
Haouas M, Harrane A, Belbachir M et al (2007) Solid state NMR characterization of formation of poly(e-caprolactone)/maghnite nanocomposites by in situ polymerization. J Polym Sci Part B: Polym Phys 45:3060-3068
Mecerreyes D, Jérôme R, Dubois P (1999) Novel macromolecular architectures based on aliphatic polyesters relevance of the 'coordination-insertion' ring-opening polymerization. Adv Polym Sci 147:1-59
Kubies D, Pantoustier N, Dubois P et al (2002) Controlled ring-opening polymerization of e-Caprolactone in the presence of layered silicates and formation of nanocomposites. Macromolecules 35:3318-3320
Lepoittevin B, Pantoustier N, Alexandre M et al (2002) Polyester layered silicate nanohybrids by controlled grafting polymerization. J Mater Chem 12:3528-3532
Lepoittevin B, Pantoustier N, Alexandre M et al (2002) Layered silicate/polyester nanohybrids by controlled ring-opening polymerization. Macromol Symp 183:95-102
Gorrasi G, Tortora M, Vittoria V et al (2003) Vapor barrier properties of polycaprolactone montmorillonite nanocomposites: effect of clay dispersion. Polymer 44:2271-2279
Viville P, Lazzaroni R, Pollet E et al (2003) Surface characterization of poly(e-caprolactone)-based nanocomposites. Langmuir 19:9425-9433
Gain O, Espuche E, Pollet E et al (2004) Gas barrier properties of poly(e-caprolactone)/clay nanocomposites: influence of the morphology and polymer/clay interactions. J Polym Sci Part B: Polym Phys 43:205-214
Chrissafis K, Antoniadis G, Paraskevopoulos KM et al (2007) Comparative study of the effect of different nanoparticles on the mechanical properties and thermal degradation mechanism of in situ prepared poly(e-caprolactone) nanocomposites. Compos Sci Technol 67:2165-2174
Tarkin-Tas E, Goswami SK, Nayak BR et al (2008) Highly exfoliated poly(e-caprolactone)/ organomontmorillonite nanocomposites prepared by in situ polymerization. J Appl Polym Sci 107:976-984
Pollet E, Delcourt C, Alexandre M et al (2004) Organic-inorganic nanohybrids obtained by sequential copolymerization of ε-caprolactone and L, L-lactide from activated clay surface. Macromol Chem Phys 205:2235-2244
Liao L, Zhang C, Gong S (2007) Preparation of poly(e-caprolactone)/clay nanocomposites by microwave-assisted in situ ring-opening polymerization. Macromol Rapid Commun 28:1148-1154
Liao L, Zhang C, Gong S (2007) Microwave-assisted synthesis and characterization of poly(e-caprolactone)/montmorillonite nanocomposites. Macromol Chem Phys 208: 1301-1309
Jimenez G, Ogata N, Kawai H et al (1997) Structure and thermal/mechanical properties of poly(e-caprolactone)-clay blend. J Appl Polym Sci 64:2211-2220
Ludueña LN, Alvarez VA, Vazquez A (2007) Processing and microstructure of PCL/clay nanocomposites. Mater Sci Eng A A460-A461:121-129
Bordes P, Pollet E, Avérous L (2009) Nano-biocomposites: biodegradable polyester/nanoclay systems. Prog Polym Sci 34:125-155
Kim SW, Jo WH, Lee MS et al (2001) Preparation of clay-dispersed poly(styrene-coacrylonitrile) nanocomposites using poly(e-caprolactone) as a compatibilizer. Polymer 42:9837-9842
Pantoustier N, Alexandre M, Degree P et al (2001) Poly(e-caprolactone) layered silicate nanocomposites: effect of clay surface modifiers on the melt intercalation process. e-Polym 9
Lepoittevin B, Devalckenaere M, Pantoustier N et al (2002) Poly(. vepsiln.-caprolactone)/clay nanocomposites prepared by melt intercalation: mechanical, thermal and rheological properties. Polymer 43:4017-4023
Shieh Y-T, Lai J-G, Tang W-L (2008) Preparation of polyester/montmorillonite nanocomposites in supercritical CO2. In: 235th ACS national meeting. American Chemical Society, New Orleans, United State
Shieh Y-T, Lai J-G, Tang W-L et al (2009) Supercritical CO2 intercalation of polycaprolactone in layered silicates. J Supercrit Fluids 49:385-393
Pucciariello R, Villani V, Gorrasi G et al (2005) Phase behavior of blends of poly(ecaprolactone) and a modified montmorillonite-poly(e-caprolactone) nanocomposite. J Macromol Sci Phys B44:79-92
Lepoittevin B, Pantoustier N, Devalckenaere M et al (2003) Polymer/layered silicate nanocomposites by combined intercalative polymerization and melt intercalation: a masterbatch process. Polymer 44:2033-2040
Pollet E, Delcourt C, Alexandre M et al (2006) Transesterification catalysts to improve clay exfoliation in synthetic biodegradable polyester nanocomposites. Eur Polym J 42:1330-1341
Luo ZP, Koo JH (2008) Quantification of the layer dispersion degree in polymer layered silicate nanocomposites by transmission electron microscopy. Polymer 49:1841-1852
Gupta RK, Kennel E, Kim KJ (2010) Polymer nanocomposites handbook. CRC Press, Boca Raton
Miltner HE, Watzeels N, Block C et al (2010) Qualitative assessment of nanofiller dispersion in poly(e-caprolactone) nanocomposites by mechanical testing, dynamic rheometry and advanced thermal analysis. Eur Polym J 46:984-996
Chen B, Evans JRG (2006) Nominal and effective volume fractions in polymer-clay nanocomposites. Macromolecules 39:1790-1796
Pucciariello R, Villani V, Belviso S et al (2004) Phase behavior of modified montmorillonitepoly(ε-caprolactone) nanocomposites. J Polym Sci Part B: Polym Phys 42:1321-1332
Homminga D, Goderis B, Dolbnya I et al (2006) Crystallization behavior of polymer/ montmorillonite nanocomposites. Part II. Intercalated poly(e-caprolactone)/montmorillonite nanocomposites. Polymer 47:1620-1629
Wu T, Xie T, Yang G (2009) Preparation and characterization of poly(e-caprolactone)/Na+-MMT nanocomposites. Appl Clay Sci 45:105-110
Di ME, Iannace S, Sorrentino L et al (2004) Isothermal crystallization in PCL/clay nanocomposites investigated with thermal and rheometric methods. Polymer 45:8893-8900
Luduena LN, Vazquez A, Alvarez VA (2008) Crystallization of polycaprolactone-clay nanocomposites. J Appl Polym Sci 109:3148-3156
Marras SI, Kladi KP, Tsivintzelis I et al (2008) Biodegradable polymer nanocomposites: the role of nanoclays on the thermomechanical characteristics and the electrospun fibrous structure. Acta Biomater 4:756-765
Pantoustier N, Lepoittevin B, Alexandre M et al (2002) Biodegradable polyester layered silicate nanocomposites based on poly(e-caprolactone). Polym Eng Sci 42:1928-1937
Di Y, Iannac S, Sanguigno L et al (2005) Barrier and mechanical properties of poly(caprolactone)/organoclay nanocomposites. Macromol Symp 228:115-124
Fukushima K, Abbate C, Tabuani D et al (2010) Biodegradation trend of poly(ecaprolactone) and nanocomposites. Mater Sci Eng C 30:566-574
Krishnamoorti R, Giannelis EP (1997) Rheology of end-tethered polymer layered silicate nanocomposites. Macromolecules 30:4097-4102
Giannelis EP (1998) Polymer-layered silicate nanocomposites: synthesis, properties and applications. Appl Organomet Chem 12:675-680
Ko MB (2000) One-pot synthesis of clay-dispersed poly(styrene-co-acrylonitrile) copolymer nanocomposite using poly(e-caprolactone) as a compatibilizer. Korea Polym J 8:186-191
Krishnamoorti R, Giannelis EP (2001) Strain hardening in model polymer brushes under shear. Langmuir 17:1448-1452
Gorrasi G, Tortora M, Vittoria V et al (2002) Transport and mechanical properties of blends of poly(e-caprolactone) and a modified montmorillonite-poly(e-caprolactone) nanocomposite. J Polym Sci Part B: Polym Phys 40:1118-1124
Kwak S-Y, Oh KS (2003) Effect of thermal history on structural changes in melt-intercalated poly(e-caprolactone)/organoclay nanocomposites investigated by dynamic viscoelastic relaxation measurements. Macromol Mater Eng 288:503-508
Pantoustier N, Alexandre M, Degee P et al (2003) Intercalative polymerization of cyclic esters in layered silicates: thermal vs. catalytic activation. Compos Interfaces 10:423-433
Calberg C, Jerome R, Grandjean J (2004) Solid-state NMR study of poly(e-caprolactone)/ clay nanocomposites. Langmuir 20:2039-2041
Karaman VM, Privalko EG, Privalko VP et al (2005) Stretching calorimetry studies of poly(e-caprolactone)/organoclay nanocomposites. Polymer 46:1943-1948
Pucciariello R, Villani V, Guadagno L et al (2005) Equilibrium thermal behavior and morphology of organophilic montmorillonite/poly(e-caprolactone) nanocomposites. J Polym Sci Part B: Polym Phys 44:22-32
Shibata M, Teramoto N, Someya Y et al (2007) Nanocomposites based on poly(ecaprolactone) and the montmorillonite treated with dibutylamine-terminated ε-caprolactone oligomer. J Appl Polym Sci 104:3112-3119
Liao H-T (2008) A new application of biosurfactant for the preparation of polycaprolactone/ layered silicate nanocomposites. Polym Eng Sci 48:1524-1531
Sasmal A, Sahoo D, Nanda R et al (2009) Biodegradable nanocomposites from maleated polycaprolactone/soy protein isolate blend with organoclay: preparation, characterization, and properties. Polym Compos 30:708-714
Campbell K, Qi S, Craig DQM et al (2009) Paracetamol-loaded poly(. vepsiln.-caprolactone) layered silicate nanocomposites prepared using hot-melt extrusion. J Pharm Sci 98:4831-4843
Labidi S, Azema N, Perrin D et al (2010) Organo-modified montmorillonite/poly(. vepsiln.-caprolactone) nanocomposites prepared by melt intercalation in a twin-screw extruder. Polym Degrad Stab 95:382-388
Liu H, Han C, Dong L (2010) Study of the biodegradable poly(. vepsiln.-caprolactone)/clay nanocomposite foams. J Appl Polym Sci 115:3120-3129
Singh NK, Das PB, Roy JK et al (2010) Nanoparticle-induced controlled biodegradation and its mechanism in poly(e-caprolactone). ACS Appl Mater Interfaces 2:69-81
Hoidy WH, Ahmad MB, EaJ Al-Mulla et al (2010) Preparation and characterization of polyactic acid/polycaprolactone clay nanocomposites. J Appl Sci 10:97-106
Harrane A, Meghabar R, Belbachir M (2006) Kinetics of the ring opening polymerization of ε-caprolactone catalyzed by a proton exchanged montmorillonite clay. React Funct Polym 66:1696-1702
Kiersnowski A, Gutmann JS, Piglowski J (2007) Influence of organic modifiers on morphology and crystallization of poly(e-caprolactone)/synthetic clay intercalated nanocomposites. J Polym Sci Part B: Polym Phys 45:2350-2367
Kiersnowski A, Kozak M, Jurga S et al (2004) Structure and crystallization behaviour of poly(e-caprolactone)/clay intercalated nanocomposites. Polym Polym Compos 12:727-737
Kiersnowski A, Piglowski J (2004) Polymer-layered silicate nanocomposites based on poly(. vepsiln.-caprolactone). Eur Polym J 40:1199-1207
Mao Q, Schleidt S, Zimmermann H et al (2007) Molecular motion in surfactant layers inside polymer composites with synthetic magadiite. Macromol Chem Phys 208:2145-2160
Gorrasi G, Tortora M, Vittoria V et al (2004) Physical properties of poly(e-caprolactone) layered silicate nanocomposites prepared by controlled grafting polymerization. J Polym Sci Part B: Polym Phys 42:1466-1475
Kim HB, Lee CH, Choi JS et al (2005) Preparation and rheological characteristics of poly(ecaprolactone)/ organoclay nanocomposites. J Ind Eng Chem (Seoul, Repub Korea) 11:769-772
Tortora M, Vittoria V, Galli G et al (2002) Transport properties of modified montmorillonitepoly(ε-caprolactone) nanocomposites. Macromol Mater Eng 287:243-249
Wang X-L, Huang F-Y, Zhou Y et al (2009) Nonisothermal crystallization kinetics of poly(ecaprolactone)/ montmorillonite nanocomposites. J Macromol Sci Part B Phys 48:710-722
Kiersnowski A, Dabrowski P, Budde H et al (2004) Synthesis and structure of poly(ecaprolactone)/ synthetic montmorillonite nano-intercalates. Eur Polym J 40:2591-2598
Pucciariello R, Villani V, Langerame F et al (2004) Interfacial effects in organophilic montmorillonite-poly(e-caprolactone) nanocomposites. J Polym Sci Part B: Polym Phys 42:3907-3919
Marrazzo C, Di ME, Iannace S (2008) Conventional and nanometric nucleating agents in poly(e-caprolactone) foaming: crystals vs. bubbles nucleation. Polym Eng Sci 48:336-344
Hong CH, Lee CH, Choi JS et al (2007) Rheological characteristics of solvent-cast poly(ecaprolactone)/ organoclay nanocomposite. Diffus Defect Data Part B 121-123:1455-1458