VOCs catalytic removal over hierarchical porous zeolite NaY supporting Pt or Pd nanoparticles

[en] The present work reports the impregnation of palladium (Pd) or platinum (Pt) on hierarchical porous zeolite catalysts for Volatile Organic Compounds (VOCs) oxidation. The hierarchical porous zeolite (NaYmod) was synthesized via a top-down approach to incorporate mesoporosity into the microporous zeolite NaY. This process was achieved through a three steps synthesis: dealumination, desilication and alkaline treatment. 0.5 wt% of Pd and Pt precursors were then added to NaY and NaYmod supports by wet impregnation in order to elaborate efficient catalysts for the total oxidation of two types of VOCs, ethanol and toluene, which are probe molecules for oxygenated VOCs and BTEX compounds respectively. The supported and unsupported samples were char- acterized by X-Ray Diffraction (XRD), N2-physisorption, Transmission Electron Microscopy (TEM), and X-Ray Photoelectron Spectroscopy (XPS). The modified mesostructured support ensures a better dispersion of the active phases and led to a partial presence of highly reactive Pt(II) species in the case of platinum-based samples. Whatever the oxidation reaction, these latter demonstrate higher conversions compared to palladium-based ones. The presence of Pt(II) species provided a high catalytic performance, with a total degradation of both VOC probe molecules at temperatures lower than 170 ◦ C. Such temperatures have not been recorded before for NaY sup- ported materials.

Disciplines :

Chemical engineering
Chemistry
Energy

Author, co-author :

El Khawaja, Rebecca

Sonar, Shilpa

Barakat, Tarek

Heymans, Nicolas ; Université de Mons - UMONS > Faculté Polytechnique > Service de Thermodynamique, Physique mathématiques

Su, Bao-Lian

Löfberg, Axel

Lamonier, Jean-François

Giraudon, Jean-Marc

De Weireld, Guy ; Université de Mons - UMONS > Faculté Polytechnique > Service de Thermodynamique, Physique mathématiques

Poupin, Christophe

Cousin, Renaud

Siffert, Stéphane

Language :

English

Title :

VOCs catalytic removal over hierarchical porous zeolite NaY supporting Pt or Pd nanoparticles

Publication date :

16 May 2022

Journal title :

Catalysis Today

ISSN :

0920-5861

eISSN :

1873-4308

Publisher :

Elsevier BV

Peer reviewed :

Peer Reviewed verified by ORBi

Development Goals :

13. Climate action

Additional URL :

https://api.elsevier.com/content/article/PII:S0920586122001808?httpAccept=text/xml

Research unit :

Thermodynamics and Mathematical Physics

Research institute :

Energie

Name of the research project :

3145 - DepollutAir - Couplages innovants de techniques de traitement des Composés Organiques Volatils - Sources publiques européennes

Funders :

Interreg France-Wallonie-Vlaanderen [BE]

Funding number :

1.1.18

Funding text :

The “DepollutAir” project (grant number 1.1.18) of the European Program INTERREG V France-Wallonie-Vlaanderen (European Regional Development Fund (ERDF), Europe), R ́egion Wallone (Belgium) and R ́egion Hauts-de-France (France) are acknowledged for the funding and their support for this work.

Available on ORBi UMONS :

since 25 May 2022

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Bibliography

Soni, V., Singh, P., Shree, V., Goel, V., Effects of VOCs on human health. Energy Environ. Sustain., 2018, 119–142, 10.1007/978-981-10-7185-0_8.
Billionnet, C., Sherrill, D., Annesi-Maesano, I., Estimating the health effects of exposure to multi-pollutant mixture. Ann. Epidemiol. 22 (2012), 126–141, 10.1016/j.annepidem.2011.11.004.
Méausoone, C., El Khawaja, R., Tremolet, G., Siffert, S., Cousin, R., Cazier, F., Billet, S., Courcot, D., Landkocz, Y., In vitro toxicological evaluation of emissions from catalytic oxidation removal of industrial VOCs by air/liquid interface (ALI) exposure system in repeated mode. Toxicol. In Vitro 58 (2019), 110–117, 10.1016/j.tiv.2019.03.030.
Li, N., Jiang, Q., Wang, F., Xie, J., Li, Y., Li, J., Wu, S., Emission behavior, environmental impact and priority-controlled pollutants assessment of volatile organic compounds (VOCs) during asphalt pavement construction based on laboratory experiment. J. Hazard. Mater., 398, 2020, 10.1016/j.jhazmat.2020.122904.
Mizukoshi, A., Kumagai, K., Yamamoto, N., Noguchi, M., Yoshiuchi, K., Kumano, H., Yanagisawa, Y., A novel methodology to evaluate health impacts caused by VOC exposures using real-time VOC and Holter monitors. Int. J. Environ. Res. Public Health 7 (2010), 4127–4138, 10.3390/ijerph7124127.
Le Cloirec, P., COV (composés organiques volatils). 2004, Tech. l'Ingénieur.
Sillman, S., The relation between ozone, NOx and hydrocarbons in urban and polluted rural environments. Atmos. Environ., 33, 1999, 10.1016/S1474-8177(02)80015-8.
Kuśtrowski, P., Rokicińska, A., Kondratowicz, T., Abatement of volatile organic compounds emission as a target for various human activities including energy production. Adv. Inorg. Chem. 72 (2018), 385–419, 10.1016/bs.adioch.2018.05.004.
Kamal, M.S., Razzak, S.A., Hossain, M.M., Catalytic oxidation of volatile organic compounds (VOCs) - a review. Atmos. Environ. 140 (2016), 117–134, 10.1016/j.atmosenv.2016.05.031.
Avgouropoulos, G., Oikonomopoulos, E., Kanistras, D., Ioannides, T., Complete oxidation of ethanol over alkali-promoted Pt/Al2O3 catalysts. Appl. Catal. B Environ. 65 (2006), 62–69, 10.1016/j.apcatb.2005.12.016.
Liotta, L.F., Catalytic oxidation of volatile organic compounds on supported noble metals. Appl. Catal. B Environ. 100 (2010), 403–412, 10.1016/j.apcatb.2010.08.023.
Santos, V.P., Carabineiro, S.A.C., Tavares, P.B., Pereira, M.F.R., Órfão, J.J.M., Figueiredo, J.L., Oxidation of CO, ethanol and toluene over TiO2 supported noble metal catalysts. Appl. Catal. B Environ. 99 (2010), 198–205, 10.1016/j.apcatb.2010.06.020.
Finol, M.F., Rooke, J., Su, B.L., Trentesaux, M., Giraudon, J.M., Lamonier, J.F., Additional effects of Pt and Nb on hierarchically porous titania in the catalytic removal of n-butanol. Catal. Today 192 (2012), 154–159, 10.1016/j.cattod.2011.11.004.
Tidahy, H.L., Hosseni, M., Siffert, S., Cousin, R., Lamonier, J.F., Aboukaïs, A., Su, B.L., Giraudon, J.M., Leclercq, G., Nanostructured macro-mesoporous zirconia impregnated by noble metal for catalytic total oxidation of toluene. Catal. Today 137 (2008), 335–339, 10.1016/j.cattod.2007.09.008.
Tidahy, H.L., Siffert, S., Lamonier, J.F., Zhilinskaya, E.A., Aboukaïs, A., Yuan, Z.Y., Vantomme, A., Su, B.L., Canet, X., De Weireld, G., Frère, M., N'Guyen, T.B., Giraudon, J.M., Leclercq, G., New Pd/hierarchical macro-mesoporous ZrO2, TiO2 and ZrO2-TiO2 catalysts for VOCs total oxidation. Appl. Catal. A Gen. 310 (2006), 61–69, 10.1016/j.apcata.2006.05.020.
Navlani-García, M., Miguel-García, I., Berenguer-Murcia, Á., Lozano-Castelló, D., Cazorla-Amorós, D., Yamashita, H., Pd/zeolite-based catalysts for the preferential CO oxidation reaction: ion-exchange, Si/Al and structure effect. Catal. Sci. Technol. 6 (2016), 2623–2632, 10.1039/c5cy02044a.
Sasikala, R., Gaikwad, A.P., Sudarsan, V., Rao, R., Jagannath, Viswanadh, B., Bharadwaj, S.R., The dual role of palladium in enhancing the photocatalytic activity of CdS dispersed on NaY-zeolite. Phys. Chem. Chem. Phys. 17 (2015), 6896–6904, 10.1039/c4cp06105e.
Jabłońska, M., Król, A., Kukulska-Zajac, E., Tarach, K., Girman, V., Chmielarz, L., Góra-Marek, K., Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration. Appl. Catal. B Environ. 166–167 (2015), 353–365, 10.1016/j.apcatb.2014.11.047.
Verboekend, D., Vilé, G., Pérez-Ramírez, J., Hierarchical Y and USY zeolites designed by post-synthetic strategies. Adv. Funct. Mater. 22 (2012), 916–928, 10.1002/adfm.201102411.
Cundy, C.S., Cox, P.A., The hydrothermal synthesis of zeolites: history and development from the earliest days to the present time. Chem. Rev. 103 (2003), 663–702, 10.1021/cr020060i.
Zhu, J., Cui, Y., Wang, Y., Wei, F., Direct synthesis of hierarchical zeolite from a natural layered material w. Chem. Commun., 2009, 3282–3284, 10.1039/b902661d.
Li, Y., Yu, J., New stories of zeolite structures: their descriptions, determinations, predictions, and evaluations. Chem. Rev. 114 (2014), 7268–7316, 10.1021/cr500010r.
Zhao, J., Yin, Y., Li, Y., Chen, W., Liu, B., Synthesis and characterization of mesoporous zeolite Y by using block copolymers as templates. Chem. Eng. J. 284 (2016), 405–411, 10.1016/j.cej.2015.08.143.
Verboekend, D., Nuttens, N., Locus, R., Van Aelst, J., Verolme, P., Groen, J.C., Pérez-Ramírez, J., Sels, B.F., Synthesis, characterisation, and catalytic evaluation of hierarchical faujasite zeolites: milestones, challenges, and future directions. Chem. Soc. Rev. 45 (2016), 3331–3352, 10.1039/c5cs00520e.
Ennaert, T., Van Aelst, J., Dijkmans, J., De Clercq, R., Schutyser, W., Dusselier, M., Verboekend, D., Sels, B.F., Potential and challenges of zeolite chemistry in the catalytic conversion of biomass. Chem. Soc. Rev., 2016, 584–611, 10.1039/c5cs00859j.
Li, W., Zheng, J., Luo, Y., Da, Z., Effect of hierarchical porosity and phosphorus modification on the catalytic properties of zeolite Y. Appl. Surf. Sci. 382 (2016), 302–308, 10.1016/j.apsusc.2016.04.146.
White, R.J., Fischer, A., Goebel, C., Thomas, A., A sustainable template for mesoporous zeolite synthesis. J. Am. Chem. Soc. 136 (2014), 2715–2718, 10.1021/ja411586h.
Saceda, J.J.F., Rintramee, K., Khabuanchalad, S., Prayoonpokarach, S., de Leon, R.L., Wittayakun, J., Properties of zeolite Y in various forms and utilization as catalysts or supports for cerium oxide in ethanol oxidation. J. Ind. Eng. Chem. 18 (2012), 420–424, 10.1016/j.jiec.2011.11.108.
Travkina, O.S., Agliullin, M.R., Filippova, N.A., Khazipova, A.N., Danilova, I.G., Grigor'Eva, N.G., Narender, N., Pavlov, M.L., Kutepov, B.I., Template-free synthesis of high degree crystallinity zeolite y with micro-meso-macroporous structure. RSC Adv. 7 (2017), 32581–32590, 10.1039/c7ra04742h.
Zhu, M., Liang, L., Wang, H., Liu, Y., Wu, T., Zhang, F., Li, Y., Kumakiri, I., Chen, X., Kita, H., Influences of acid post-treatment on high silica SSZ-13 zeolite membrane. Ind. Eng. Chem. Res. 58 (2019), 14037–14043, 10.1021/acs.iecr.9b01250.
Wang, Y., Sun, Y., Lancelot, C., Lamonier, C., Morin, J.C., Revel, B., Delevoye, L., Rives, A., Effect of post treatment on the local structure of hierarchical Beta prepared by desilication and the catalytic performance in Friedel-Crafts alkylation. Microporous Mesoporous Mater. 206 (2015), 42–51, 10.1016/j.micromeso.2014.12.017.
Guo, R., Qin, Y., Qiao, L., Chen, J., Wu, X., Yao, Y., Enhancement of the catalytic performance in Pd-Cu/NaY catalyst for carbonylation of methyl nitrite to dimethyl carbonate: effects of copper doping. Catal. Commun. 88 (2017), 94–98, 10.1016/j.catcom.2016.10.007.
Rosso, I., Galletti, C., Fiorot, S., Saracco, G., Garrone, E., Specchia, V., Preferential CO oxidation over Pt/3A zeolite catalysts in H 2-rich gas for fuel cell application. J. Porous Mater. 14 (2007), 245–250, 10.1007/s10934-006-9060-8.
Geng, L., Gong, J., Qiao, G., Ye, S., Zheng, J., Zhang, N., Chen, B., Effect of metal precursors on the performance of Pt/SAPO-11 catalysts for n-dodecane hydroisomerization. ACS Omega 4 (2019), 12598–12605, 10.1021/acsomega.9b01216.
Kinnunen, N.M., Suvanto, M., Moreno, M.A., Savimäki, A., Kallinen, K., Kinnunen, T.J.J., Pakkanen, T.A., Methane oxidation on alumina supported palladium catalysts: effect of Pd precursor and solvent. Appl. Catal. A Gen. 370 (2009), 78–87, 10.1016/j.apcata.2009.09.018.
Llewellyn, P., Rouquerol, J., Luciani, L., Denoyel, R., Rouquerol, F., Texture des matériaux pulvérulents ou poreux. 2003, Tech. l'Ingénieur.
Bunmai, K., Osakoo, N., Deekamwong, K., Rongchapo, W., Keawkumay, C., Chanlek, N., Prayoonpokarach, S., Wittayakun, J., Extraction of silica from cogon grass and utilization for synthesis of zeolite NaY by conventional and microwave-assisted hydrothermal methods. J. Taiwan Inst. Chem. Eng. 83 (2018), 152–158, 10.1016/j.jtice.2017.11.024.
Kulawong, S., Chanlek, N., Osakoo, N., Facile synthesis of hierarchical structure of NaY zeolite using silica from cogon grass for acid blue 185 removal from water. J. Environ. Chem. Eng., 8, 2020, 104114, 10.1016/j.jece.2020.104114.
Oruji, S., Khoshbin, R., Karimzadeh, R., Preparation of hierarchical structure of Y zeolite with ultrasonic-assisted alkaline treatment method used in catalytic cracking of middle distillate cut: the effect of irradiation time. Fuel Process. Technol. 176 (2018), 283–295, 10.1016/j.fuproc.2018.03.035.
Tsung, C.K., Kuhn, J.N., Huang, W., Aliaga, C., Hung, L.I., Somorjai, G.A., Yang, P., Sub-10 nm Platinum nanocrystals with size and shape control: catalytic study for Ethylene and pyrrole hydrogenation. J. Am. Chem. Soc. 131 (2009), 5816–5822, 10.1021/ja809936n.
Song, H., Rioux, R.M., Hoefelmeyer, J.D., Komor, R., Niesz, K., Grass, M., Yang, P., Somorjai, G.A., Hydrothermal growth of mesoporous SBA-15 silica in the presence of PVP-stabilized Pt nanoparticles: synthesis, characterization, and catalytic properties. J. Am. Chem. Soc. 128 (2006), 3027–3037, 10.1021/ja057383r.
Pushkarev, V.V., An, K., Alayoglu, S., Beaumont, S.K., Somorjai, G.A., Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: elucidation of the Pt particle size effect on reaction kinetics. J. Catal. 292 (2012), 64–72, 10.1016/j.jcat.2012.04.022.
Chunyu Chen, F., Chen, L., Zhang, S., Pan, C., Bian, X., Zheng, X., Meng Xiao, F., Importance of platinum particle size for complete oxidation of toluene over Pt/ZSM-5 catalysts. Chem. Commun. 51 (2015), 5936–5938, 10.1039/b000000x.
Liu, S., Wu, X., Luo, H., Weng, D., Ran, R., Pt/Zeolite catalysts for soot oxidation: influence of hydrothermal aging. J. Phys. Chem. C 119 (2015), 17218–17227, 10.1021/acs.jpcc.5b04882.
Pyra, K., Tarach, K.A., Śrębowata, A., Melián-Cabrera, I., Góra-Marek, K., Pd-modified beta zeolite for modulated hydro-cracking of low-density polyethylene into a paraffinic-rich hydrocarbon fuel. Appl. Catal. B Environ., 277, 2020, 119070, 10.1016/j.apcatb.2020.119070.
Noah, M.P.S., Plymale, T., Youn-Geun, Kim, Bruce, N., Brunschwig, S., Lewis, S., Synthesis, characterization, and reactivity of ethynyl- and propynyl-terminated Si(111) surfaces. J. Phys. Chem, 119, 2015, 19847–19862, 10.1021/acs.jpcc.5b05028.
de Souza, M.O., Mendes, F.M.T., de Souza, R.F., dos Santos, J.H.Z., XPS characterization of nickel-acetylacetonate impregnated in NaX and NaY zeolites. Microporous Mesoporous Mater. 69 (2004), 217–221, 10.1016/j.micromeso.2003.12.001.
Kaushik, V.K., Ravindranathan, M., X.p.s. study of copper-containing Y zeolites for the hydration of acrylonitrile to acrylamide. Zeolites 12 (1992), 415–419, 10.1016/0144-2449(92)90039-R.
Wang, X., Wang, K., Plackowski, C.A., Nguyen, A.V., Sulfuric acid dissolution of 4A and Na-Y synthetic zeolites and effects on Na-Y surface and particle properties. Appl. Surf. Sci. 367 (2016), 281–290, 10.1016/j.apsusc.2016.01.103.
Islam, R.U., Witcomb, M.J., Scurrell, M.S., Van Der Lingen, E., Van Otterlo, W., Mallick, K., Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems. Catal. Sci. Technol. 1 (2011), 308–315, 10.1039/c0cy00071j.
McEleney, K., Crudden, C.M., Horton, J.H., X-ray photoelectron spectroscopy and the auger parameter as tools for characterization of silica-supported pd catalysts for the suzuki-miyaura reaction. J. Phys. Chem. C 113 (2009), 1901–1907, 10.1021/jp808837k.
Jiang, X., Koizumi, N., Guo, X., Song, C., Bimetallic Pd-Cu catalysts for selective CO2 hydrogenation to methanol. Appl. Catal. B Environ. 170–171 (2015), 173–185, 10.1016/j.apcatb.2015.01.010.
Dai, C., Li, X., Zhang, A., Liu, C., Song, C., Guo, X., Pd and Pd-CuO nanoparticles in hollow silicalite-1 single crystals for enhancing selectivity and activity for the Suzuki-Miyaura reaction. RSC Adv. 5 (2015), 40297–40302, 10.1039/c5ra05952f.
Dong, Y., Shen, Y., Zhao, Y., Wang, S., Ma, X., Synergy between palladium and potassium species for efficient activation of carbon monoxide in the synthesis of dimethyl carbonate. ChemCatChem 7 (2015), 2460–2466, 10.1002/cctc.201500317.
Yang, J., Fan, W., Bell, C.M., Effect of calcination atmosphere on microstructure and H2/CO2 separation of palladium-doped silica membranes. Sep. Purif. Technol. 210 (2019), 659–669, 10.1016/j.seppur.2018.08.041.
Abdelouahab-Reddam, Z., El Mail, R., Coloma, F., Sepúlveda-Escribano, A., Platinum supported on highly-dispersed ceria on activated carbon for the total oxidation of VOCs. Appl. Catal. A Gen. 494 (2015), 87–94, 10.1016/j.apcata.2015.01.026.
Xu, J., Xu, X.C., Ouyang, L., Yang, X.J., Mao, W., Su, J., Han, Y.F., Mechanistic study of preferential CO oxidation on a Pt/NaY zeolite catalyst. J. Catal. 287 (2012), 114–123, 10.1016/j.jcat.2011.12.012.
Park, S.H., Tzou, M.S., Sachtler, W.M.H., Temperature programmed reduction and re-oxidation of platinum in Y-zeolites. J. Chem. Inf. Model 24 (1986), 85–98, 10.1016/S0166-9834(00)81259-2.
Rintramee, K., Föttinger, K., Rupprechter, G., Wittayakun, J., Ethanol adsorption and oxidation on bimetallic catalysts containing platinum and base metal oxide supported on MCM-41. Appl. Catal. B Environ. 115–116 (2012), 225–235, 10.1016/j.apcatb.2011.11.050.
Trawczyński, J., Bielak, B., Miśta, W., Oxidation of ethanol over supported manganese catalysts - effect of the carrier. Appl. Catal. B Environ. 55 (2005), 277–285, 10.1016/j.apcatb.2004.09.005.
Yin, F., Ji, S., Wu, P., Zhao, F., Li, C., Deactivation behavior of Pd-based SBA-15 mesoporous silica catalysts for the catalytic combustion of methane. J. Catal. 257 (2008), 108–116, 10.1016/j.jcat.2008.04.010.
Barakat, T., Rooke, J.C., Chlala, D., Cousin, R., Lamonier, J.F., Giraudon, J.M., Casale, S., Massiani, P., Su, B.L., Siffert, S., Oscillatory behavior of Pd-Au catalysts in toluene total oxidation. Catalysts 8 (2018), 1–11, 10.3390/catal8120574.
Kim, S.C., Shim, W.G., Properties and performance of Pd based catalysts for catalytic oxidation of volatile organic compounds. Appl. Catal. B Environ. 92 (2009), 429–436, 10.1016/j.apcatb.2009.09.001.
Shim, W.G., Lee, J.W., Kim, S.C., Analysis of catalytic oxidation of aromatic hydrocarbons over supported palladium catalyst with different pretreatments based on heterogeneous adsorption properties. Appl. Catal. B Environ. 84 (2008), 133–141, 10.1016/j.apcatb.2008.03.011.
Chen, C., Zhu, J., Chen, F., Meng, X., Zheng, X., Gao, X., Xiao, F.S., Enhanced performance in catalytic combustion of toluene over mesoporous Beta zeolite-supported platinum catalyst. Appl. Catal. B Environ. 140–141 (2013), 199–205, 10.1016/j.apcatb.2013.03.050.
Ying, J., Peng, H., Xu, X., Wang, R., Yu, F., Sun, Q., Liu, W., Gao, Z., Wang, X., Thermally stable ultra-small Pd nanoparticles encapsulated by silica: elucidating the factors determining the inherent activity of noble metal catalysts. Catal. Sci. Technol. 6 (2016), 5405–5414, 10.1039/c6cy00201c.
Chen, C., Wang, X., Zhang, J., Pan, S., Bian, C., Wang, L., Chen, F., Meng, X., Zheng, X., Gao, X., Xiao, F.S., Superior performance in catalytic combustion of toluene over KZSM-5 zeolite supported platinum catalyst. Catal. Lett. 144 (2014), 1851–1859, 10.1007/s10562-014-1295-4.
Hao, Y., Chen, S., Wu, L., Chen, R., Sun, P., Chen, T., Hierarchically porous silica supported ceria and platinum nanoparticles for catalytic combustion of toluene. J. Alloy. Compd., 867, 2021, 159030, 10.1016/j.jallcom.2021.159030.