Cathodic protection (C); Electrodeposited films (C); Rare earth elements (A); Electrodeposited film (C); Electrodeposited films; Galvanic corrosion; Galvanic coupling; Inhibition performance; Rare earth element (A); Sacrificial coatings; Surface corrosion; Top surface; Chemistry (all); Chemical Engineering (all); Materials Science (all); General Materials Science; General Chemical Engineering; General Chemistry
Abstract :
[en] The effect of Ce(III) on the top surface and galvanic corrosion of ZnFe coating electrodeposited on steel was investigated. The inhibition performance was assessed by Electrochemical Impedance Spectroscopy on the surface of the Zn and ZnFe electrodeposited coatings. The ZnFe/steel galvanic coupling was investigated based on a model coupling studied from the polarization curves while Scanning Vibrating Electrode Technique gave information on a cut-edge configuration. Cerium increases the corrosion of zinc in a galvanic coupling with steel. Inhibitive species decrease the activity of ZnFe during cut-edge corrosion and has an influence on the precipitation products and their localization.
Research center :
CRIM - Ingénierie des matériaux
Disciplines :
Materials science & engineering
Author, co-author :
Arrighi, Céline; UMONS - Université de Mons [BE]
Nguyen, Thi Thao ; Université de Mons - UMONS > Faculté Polytechnique > Service de Science des Matériaux
Paint, Yoann; Materia Nova
Savall, Catherine; La Rochelle Université
Bertolucci Coelho, Leonardo; ULB - Université Libre de Bruxelles [BE]
Creus, Juan; La Rochelle University
Olivier, Marie-Georges ; Université de Mons - UMONS > Faculté Polytechnique > Service de Science des Matériaux ; Materia Nova
Language :
English
Title :
Study of Ce(III) as a potential corrosion inhibitor of Zn-Fe sacrificial coatings electrodeposited on steel
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Funding text :
This study was co-supported by the Nouvelle Aquitaine Region in France through the Project Dursadh: 2017-1R10101 and the University of Mons in Belgium through the Research Council , the Materials Institute and the Materials Science Department .
Marchandise, D., Cuntz, J.M., Creus, J., Gavrila, M., Rothea, C., Idrissi, H., Millet, J.P., Caractérisation de revêtements électrodéposés de zinc-nickel. Matér. Tech. 85 (1997), 33–38.
Gavrila, M., Millet, J.P., Mazille, H., Marchandise, D., Cuntz, J.M., Corrosion behaviour of zinc-nickel coatings, electrodeposited on steel. Surf. Coatings Technol. 123 (2000), 164–172, 10.1016/S0257-8972(99)00455-7.
ANNEX XVII TO REACH – Conditions of restriction - Nickel, n.d.
Genchi, G., Carocci, A., Lauria, G., Sinicropi, M.S., Nickel: human health and environmental toxicology. Int. J. Environ. Res. Public Health, 17, 2020, 679.
Lan, C.J., Liu, W.Y., Chin, T.S., Electrodeposition of Zn–Fe Alloys Using Electrolytes of the System ZnO–(ferrous gluconate)–KOH. J. Electrochem. Soc., 154, 2007, D30, 10.1149/1.2393011.
Lan, C.J., Liu, W.Y., Ke, S.T., Chin, T.S., Potassium salt based alkaline bath for deposition of Zn-Fe alloys. Surf. Coat. Technol. 201 (2006), 3103–3108, 10.1016/j.surfcoat.2006.06.027.
Bajat, J.B., Mišković-Stanković, V.B., Maksimović, M.D., Dražić, D.M., Zec, S., Electrochemical deposition and characterization of Zn-Fe alloys. J. Serb. Chem. Soc. 69 (2004), 807–815, 10.2298/JSC0410807B.
Nayana, K.O., Venkatesha, T.V., Chandrappa, K.G., Influence of additive on nanocrystalline, bright Zn-Fe alloy electrodeposition and its properties. Surf Coat. Technol. 235 (2013), 461–468, 10.1016/j.surfcoat.2013.08.003.
Bhat, R.S., Hegde, A.C., Electroplating and corrosion study of Zn-Co, Zn-Fe and Zn-Co-Fe alloys. Anal. Bioanal. Electrochem. 4 (2012), 593–609.
Park, H., Szpunar, J.A., The role of texture and morphology in optimizing the corrosion resistance of zinc-based electrogalvanized coatings. Corros. Sci. 40 (1998), 525–545, 10.1016/S0010-938X(97)00148-0.
Arrighi, C., Savall, C., Cohendoz, S., Grosseau-Poussard, J.L., Baissac, L., Olivier, M.G., Creus, J., Optimization of the morphology, structure and properties of high iron content Zn–Fe coatings by pulse electrodeposition. Mater. Chem. Phys., 263, 2021, 124366, 10.1016/j.matchemphys.2021.124366.
ANNEX XVII TO REACH – Conditions of restriction - Chromium, 2015.
Hinton, B.R.W., Corrosion inhibition with rare earth metal salts. J. Alloy. Compd. 180 (1992), 15–25, 10.1016/0925-8388(92)90359-H.
Aramaki, K., Treatment of zinc surface with cerium(III) nitrate to prevent zinc corrosion in aerated 0.5 M NaCl. Corros. Sci. 43 (2001), 2201–2215, 10.1016/S0010-938X(00)00189-X.
Arenas, M.A., De Damborenea, J.J., Growth mechanisms of cerium layers on galvanised steel. Electrochim. Acta 48 (2003), 3693–3698, 10.1016/S0013-4686(03)00507-3.
Arenas, M.A., de Damborenea, J., Interference by cerium cations during the multi-step zinc dissolution process in a chloride-containing electrolyte. Corros. Sci. 48 (2006), 3196–3207, 10.1016/j.corsci.2005.10.015.
Arenas, M.A., de Damborenea, J.J., Surface characterisation of cerium layers on galvanised steel. Surf. Coat. Technol. 187 (2004), 320–325, 10.1016/j.surfcoat.2004.02.033.
Arenas, M.A., Bethencourt, M., Botana, F.J., De Damborenea, J., Marcos, M., Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts. Corros. Sci. 43 (2001), 157–170, 10.1016/S0010-938X(00)00051-2.
Olivier, M., Lanzutti, A., Motte, C., Fedrizzi, L., Influence of oxidizing ability of the medium on the growth of lanthanide layers on galvanized steel. Corros. Sci. 52 (2010), 1428–1439, 10.1016/j.corsci.2010.01.011.
De Damborenea, J., Conde, A., Arenas, M.A., Corrosion Inhibition with Rare Earth Metal Compounds in Aqueous Solutions. 2014, Woodhead Publishing Limited, 10.1533/9780857093585.84.
Prosek, T., Nazarov, A., Xue, H.B., Lamaka, S., Thierry, D., Progress in Organic Coatings Role of steel and zinc coating thickness in cut edge corrosion of coil coated materials in atmospheric weathering conditions; Part 1: laboratory study. Prog. Org. Coat. 99 (2016), 356–364, 10.1016/j.porgcoat.2016.06.013.
Marques, A.G., Taryba, M.G., Panão, A.S., Lamaka, S.V., Simões, A.M., Application of scanning electrode techniques for the evaluation of iron – zinc corrosion in nearly neutral chloride solutions. Eval. Program Plann. 104 (2016), 123–131, 10.1016/j.corsci.2015.12.002.
Thébault, F., Vuillemin, B., Oltra, R., Allely, C., Ogle, K., Protective mechanisms occurring on zinc coated steel cut-edges in immersion conditions. Electrochim. Acta 56 (2011), 8347–8357, 10.1016/j.electacta.2011.07.016.
Ogle, K., Morel, S., Jacquet, D., Observation of self healing functions on the cut edge of galvanised steel using scanning vibrating electrode technique (SVET) and pH microscopy. Local Probe Tech. Corros. Res., 2007, 12–22, 10.1533/9781845692599.12.
Souto, R.M., González-García, Y., Bastos, A.C., Simões, A.M., Investigating corrosion processes in the micrometric range: A SVET study of the galvanic corrosion of zinc coupled with iron. Corros. Sci. 49 (2007), 4568–4580, 10.1016/j.corsci.2007.04.016.
Simões, A.M., Fernandes, J.C.S., Studying phosphate corrosion inhibition at the cut edge of coil coated galvanized steel using the SVET and EIS. Prog. Org. Coat. 69 (2010), 219–224, 10.1016/j.porgcoat.2010.04.022.
Custódio, J.V., Agostinho, S.M.L., Simões, A.M.P., Electrochemistry and surface analysis of the effect of benzotriazole on the cut edge corrosion of galvanized steel. Electrochim. Acta 55 (2010), 5523–5531, 10.1016/j.electacta.2010.03.072.
Taryba, M., Lamaka, S.V., Snihirova, D., Ferreira, M.G.S., Montemor, M.F., Wijting, W.K., Electrochimica Acta The combined use of scanning vibrating electrode technique and micro-potentiometry to assess the self-repair processes in defects on “ smart ” coatings applied to galvanized steel. Electrochim. Acta 56 (2011), 4475–4488, 10.1016/j.electacta.2011.02.048.
Simões, A.M., Bastos, A.C., Ferreira, M.G., González-García, Y., González, S., Souto, R.M., Use of SVET and SECM to study the galvanic corrosion of an iron-zinc cell. Corros. Sci. 49 (2007), 726–739, 10.1016/j.corsci.2006.04.021.
Coelho, L.B., Fava, E.B., Kooijman, A.M., Gonzalez-Garcia, Y., Olivier, M.G., Molybdate as corrosion inhibitor for hot dip galvanised steel scribed to the substrate: a study based on global and localised electrochemical approaches. Corros. Sci., 175, 2020, 108893, 10.1016/j.corsci.2020.108893.
Oliveira, M., Bastos, A.C., Kallip, S., Hack, T., Zheludkevich, M.L., Ferreira, M.G.S., Corrosion inhibition and acceleration by rare earth ions in galvanic couples. J. Electrochem. Soc. 166 (2020), C642–C648, 10.1149/2.0761916jes.
Qing, Y., Hu, C., Yang, C., An, K., Tang, F., Tan, J., Liu, C., Rough structure of electrodeposition as a template for an ultrarobust self-cleaning surface. ACS Appl. Mater. Interfaces 9 (2017), 16571–16580, 10.1021/acsami.6b15745.
Qing, Y., Yang, C., Yu, Z., Zhang, Z., Hu, Q., Liu, C., Large-area fabrication of superhydrophobic zinc surface with reversible wettability switching and anticorrosion. J. Electrochem. Soc. 163 (2016), D385–D391, 10.1149/2.0571608jes.
Kondo, K., Hinotani, S., Ohmori, Y., Crystal structure and morphology of electrodeposited zinc-iron binary alloys. J. Appl. Electrochem. 18 (1988), 154–161, 10.1007/BF01016220.
Kanagasabapathy, M., Jayakrishnan, S., Textural and morphological studies on zinc-iron alloy electrodeposits. J. Chem. Sci. 123 (2011), 357–364, 10.1007/s12039-011-0074-7.
Huang, J.-F., Sun, I.-W., Nonanomalous electrodeposition of zinc-iron alloys in an acidic zinc chloride-1-ethyl-3-methylimidazolium chloride ionic liquid. J. Electrochem. Soc., 151, 2004, C8, 10.1149/1.1628235.
Exbrayat, L., Steyer, P., Rébéré, C., Berziou, C., Savall, C., Ayrault, P., Tertre, E., Joly-Pottuz, G.L., Creus, J., Electrodeposition of zinc-ceria nanocomposite coatings in alkaline bath. J. Solid State Electrochem 18 (2014), 223–233, 10.1007/s10008-013-2264-3.
Tran, M., Fiaud, C., Sutter, E.M.M., Cathodic reactions on steel in aqueous solutions containing Y(III). J. Electrochem. Soc., 153, 2006, B83, 10.1149/1.2163828.
Tran, M., Dubot, P., Sutter, E.M.M., Activation of water reduction in the presence of REM salts in aqueous solution. Int. J. Hydrogen Energy 33 (2008), 937–944, 10.1016/j.ijhydene.2007.11.025.
Gustavsson, J., Lindbergh, G., Cornell, A., In-situ activation of hydrogen evolution in pH-neutral electrolytes by additions of multivalent cations. Int. J. Hydrogen Energy 37 (2012), 9496–9503, 10.1016/j.ijhydene.2012.03.061.
Tran, M., Mohammedi, D., Fiaud, C., Sutter, E.M.M., Corrosion behaviour of steel in the presence of Y (III) salts: kinetic and mechanistic studies. Corros. Sci. 48 (2006), 4257–4273, 10.1016/j.corsci.2006.03.015.
Nylén, L., Gustavsson, J., Cornell, A., Cathodic reactions on an Iron RDE in the presence of Y(III). J. Electrochem. Soc. 155 (2008), 136–142, 10.1149/1.2958299.
Izquierdo, J., Nagy, L., Varga, Á., Bitter, I., Nagy, G., Souto, R.M., Electrochimica Acta Scanning electrochemical microscopy for the investigation of corrosion processes: measurement of Zn 2 + spatial distribution with ion selective microelectrodes. Electrochim. Acta 59 (2012), 398–403, 10.1016/j.electacta.2011.10.076.
Bastos, A.C., Taryba, M.G., Karavai, O.V., Zheludkevich, M.L., Lamaka, S.V., Ferreira, M.G.S., Electrochemistry communications micropotentiometric mapping of local distributions of Zn 2 + relevant to corrosion studies. Electrochem. Commun. 12 (2010), 394–397, 10.1016/j.elecom.2010.01.002.
Tada, E., Satoh, S., Kaneko, H., The spatial distribution of Zn2+ during galvanic corrosion of a Zn/steel couple. Electrochim. Acta 49 (2004), 2279–2285, 10.1016/j.electacta.2004.01.008.
