[en] The purpose of the present work was to investigate, for a gas issued from a full oxy-fuel combustion in the cement industry, a CO2 de-SOx and de-NOx process, called 'Sour-Compression Unit' (SCU),thanks to simulations with Aspen PlusTM. An important stage necessary for the SCU modeling has been the construction of an accurate chemical mechanism. Two-column and single-column
configurations have been evaluated and compared. A parametric study and a Design Of Experiments have been conducted on a single-column process to study the influence of the operating parameters
on the SOx and NOx abatement ratios. As a demonstration of the effectiveness of the model, three SOx and NOx purity specifications (depending on the further applications of the CO2) were applied to the purified gas. The feature of the investigated model lies on optimizing the way to reach the purity
target in order to decrease installation costs (CAPEX) and energy requirements (OPEX).
Ajdari, S., Normann, F., Andersson, K., Johnsson, F., Reduced mechanism for nitrogen and sulfur chemistry in pressurized flue gas systems. Ind. Eng. Chem. Res. 55 (2016), 5514–5525, 10.1021/acs.iecr.5b04670.
Ajdari, S., Normann, F., Andersson, K., Johnsson, F., Modeling the nitrogen and sulfur chemistry in pressurized flue gas systems. Ind. Eng. Chem. Res. 54 (2015), 1216–1227, 10.1021/ie504038s.
Armitage, J.W., Cullis, C.F., Studies of the reaction between nitrogen dioxide and sulfur dioxide. Combust. Flame 16 (1971), 125–130, 10.1016/S0010-2180(71)80077-9.
Bataille, V., Snieder, H., MacGregor, A.J., Sasieni, P., Spector, T.D., The influence of genetics and environmental factors in the pathogenesis of acne: a twin study of acne in women. J. Invest. Dermatol. 119 (2002), 1317–1322, 10.1046/j.1523-1747.2002.19621.x.
Bjerge, L., Brevik, P., CO2 Capture in the cement industry, norcem CO2 capture. Energy Proc. 63 (2014), 6455–6463, 10.1016/j.egypro.2014.11.680.
Bonner, F.T., Hughes, M.N., The aqueous solution chemistry of nitrogen in low positive oxidation states. Comments Inorg. Chem. 7 (1988), 215–234, 10.1080/02603598808072309.
Carrasco-Maldonado, F., Sporl, R., Fleiger, K., Hoenig, V., Maier, J., Scheffknecht, G., Oxy-fuel combustion technology for cement production –state of the art research and technology development. Int. J. Greenh. Gas Control 45 (2016), 189–199, 10.1016/j.ijggc.2015.12.014.
Chang, S.G., Littlejohn, D., Lin, N.H., Kinetics of reactions in a wet flue gas simultaneous desulfurization and denitrification system. Am. Chem. Soc. 188 (1982), 127–152, 10.1021/bk-1982-0188.ch007.
Corriveau, C.E., The Absorption of N2O3 into Water. Master's thesis, 1971, Chemical Engineering University, California, Berkeley, 226.
Cullivan, J., Cullivan, B., Economic and chemical comparisons of hydrochloric acid recovery technologies for iron pickling operations. Technical Report, 2016, Beta Control Systems Inc., Beaverton, Oregon, 1–12.
Dejak, M., Munns, K., 2017. Acid Purification and recovery using resin sorption technology–a review. Environ. II Sess. F 1–20.
Dreier, I., Kotz, S., A note on the characteristic function of the t-distribution. Stat. Probab. Lett. 57 (2002), 221–224, 10.1016/S0167-7152(02)00032-9.
Eco-Tec, 2016. Acid purification system - advanced resource recovery and purification solutions - Technical Report, Eco-Tec Limited, Ontario.
ECRA (European Cement Research Academy). ECRA CCS project., 2012, ECRA Technical report on Phase III, ECRA website, https//www.ecra-online.org, ref. TR-ECRA-119/2012.
England, C., Corcoran, W.H., The rate and mechanism of the air oxidation of parts-per-million concentrations of nitric oxide in the presence of water vapor. Ind. Eng. Chem. Fundam. 14 (1975), 55–63.
European Commission. Quarterly report on European electricity markets, market observatory for energy. Quarterly report on European electricity markets, market observatory for energy, 10, 2017, DG Energy, 2.
Goupy, J., Lee, C., Introduction to Design Of Experiments with JMP® Examples. Third ed., 2007, SAS Institute Inc, Cary, NC.
Greenland, S., Senn, S.J., Rothman, K.J., Carlin, J.B., Poole, C., Goodman, S.N., Altman, D.G., Statistical tests, P values, confidence intervals, and power: a guide to misinterpretations. Eur. J. Epidemiol. 31 (2016), 337–350, 10.1007/s10654-016-0149-3.
Hills, T., Sceats, M., Rennie, D., Fennell, P., White, V., Wright, A., Tappe, S., Yan, J., LEILAC: low cost CO2 capture for the cement and lime industries. Energy Procedia 114 (2017), 6166–6170, 10.1016/j.egypro.2017.03.1753.
Hoftyzer, P.J., Kwanten, J.G., 1972. Absorption of nitrous gases, Gas Purification Processes for air pollution control, 2nd ed., London.: Nonhebel G, Newnes, 164–187.
Holma, H., Sohlo, J., A mathematical model of an absorption tower of nitrogen oxides in nitric acid production. Comput. Chem. Eng. 3 (1979), 135–141.
IEA (International Energy Agency), 2013. Technology roadmap carbon capture and storage - Report, 2013 edition.
Iloeje, C., Field, R., Ghoniem, A.F., Modeling and parametric analysis of nitrogen and sulfur oxide removal from oxy-combustion flue gas using a single column absorber. Fuel 160 (2015), 178–188, 10.1016/j.fuel.2015.07.057.
International Energy Agency. Energy technology perspectives 2017 excerpt-informing energy sector transformations. Track. Clean Energy Progress., 2017, International Energy Agency.
Jaffe, S., Klein, F.S., Photolysis of NO2 in the Presence of SO2 at 3660 A. Trans. Faraday Soc. 62 (1966), 2150–2157.
Jordal, K., Voldsund, M., Størset, S., Fleiger, K., Ruppert, J., Spörl, R., Hornberger, M., Cinti, G., CEMCAP–making CO2 capture retrofittable to cement plants. Energy Procedia 114 (2017), 6175–6180, 10.1016/j.egypro.2017.03.1755.
Kather, A., Kownatzki, S., Assessment of the different parameters affecting the CO2 purity from coal fired oxy-fuel process. Int. J. Greenh. Gas Control 5 (2011), S204–S209, 10.1016/j.ijggc.2011.05.025.
Laribi, S., Dubois, L., Weireld, G.De, Thomas, D., Optimization of the Sour Compression Unit (SCU) process for CO2 purification applied to flue gases coming from oxy-combustion cement industries. Energy Procedia 114 (2017), 458–470, 10.1016/j.egypro.2017.03.1188.
Li, K., Leigh, W., Feron, P., Yu, H., Tade, M., Systematic study of aqueous monoethanolamine (MEA)-based CO2 capture process: techno-Economic assessment of the MEA process and its improvements. Appl. Energy 165 (2016), 648–659, 10.1016/j.apenergy.2015.12.109.
Markočič, E., Knez, Ž., Redlich–Kwong equation of state for modelling the solubility of methane in water over a wide range of pressures and temperatures. Fluid Phase Equilib. 408 (2016), 108–114, 10.1016/j.fluid.2015.08.021.
Mathias, P.M., A versatile phase equilibrium equation-of-state. Ind. Eng. Chem. Process Des. Dev. 22 (1983), 385–391, 10.1021/i200022a008.
Naiditch, S., Yost, D.M., The rate and mechanism of the hydrolysis of hydroxylamine disulfonate ion Contribution from the Gates and Crellin Laboratories of chemistry. J. Am. Chem. Soc. 63:8 (1941), 2123–2127, 10.1021/ja01853a028.
Normann, F., Jansson, E., Petersson, T., Andersson, K., Nitrogen and sulphur chemistry in pressurised flue gas systems: a comparison of modelling and experiments. Int. J. Greenh. Gas Control 12 (2013), 26–34, 10.1016/j.ijggc.2012.11.012.
Oblath, S.B., Markowitz, S.S., Novakov, T., Chang, S.G., Kinetics of the initial reaction of nitrite ion in bisulfite solutions. J. Phys. Chem 86 (1982), 4853–4857.
Park, J.Y., Lee, Y.N., Solubility and decomposition kinetics of nitrous acid in aqueous solution. J. Phys. Chem. 92 (1988), 6294–6302.
Penzhorn, R.D., Canosa, C.E., 2nd derivative UV spectroscopy study of the thermal and photochemical-reaction of NO2 with SO2 and SO3. J. Phys. Chem. 87 (1983), 648–654.
Pipitone, G., Bolland, O., Power generation with CO2 capture: Technology for CO2 purification. Int. J. Greenh. Gas Control 3 (2009), 528–534, 10.1016/j.ijggc.2009.03.001.
Project DYNAMIS, 2007. Towards hydrogen and electricity production with carbon dioxide capture and storage, European Project Report, no.:19672.
Rayson, M.S., Mackie, J.C., Kennedy, E.M., Dlugogorski, B.Z., Accurate rate constants for decomposition of aqueous nitrous acid. Inorg. Chem. 51 (2012), 2178–2185, 10.1021/ic202081z.
Santos, S., Update and Status of Development of CO2 Processing Unit. 2015, IEA Greenhouse Gas R&D Programme, 1–29.
Spero, C., Montagner, F., Chapman, L., Ranie, D., Yamada, T., Callide oxy-fuel project: lessons learned., 2014, Global CCS Institute, 1–52 Report supported by.
Stéphenne, K., Start-up of world's first commercial post-combustion coal fired ccs project: Contribution of shell cansolv to saskpower boundary dam ICCS project. Energy Procedia 63 (2014), 6106–6110, 10.1016/j.egypro.2014.11.642.
Stichlmair, J., Bravo, J.L., Fair, J.R., General model for prediction of pressure drop and capacity of countercurrent gas/liquid packed column. Gas Sep. Purif. 3 (1989), 19–28.
Sun, L., Doyle, S., Smith, R., Understanding steam costs for energy conservation projects. Appl. Energy 161 (2016), 647–655, 10.1016/j.apenergy.2015.09.046.
Syndicat français de l'industrie cimentière, 2011. Réduction des émissions de CO2: La contribution de l'industrie cimentière.
Taylor, R., Krishna, R., Modelling reactive distillation. Chem. Eng. Sci. 55:22 (2000), 5183–5229, 10.1016/S0009-2509(00)00120-2.
Torrente-Murciano, L., White, V., Petrocelli, F., Chadwick, D., Sour compression process for the removal of SOx and NOx from oxy-fuel-derived CO2. Energy Procedia 4 (2011), 908–916, 10.1016/j.egypro.2011.01.136.
White, V., Wright, A., Tappe, S., Yan, J., The air products vattenfall oxy-fuel CO2 compression and purification pilot plant at Schwarze Pumpe. Energy Procedia 37 (2013), 1490–1499, 10.1016/j.egypro.2013.06.024.
White, V., Wright, A., Tappe, S., Yan, J., The air products-vattenfall oxy-fuel CO2 compression and purification pilot plant at Schwarze Pumpe. 3rd Oxy-fuel Combust. Conf., 2013, 1–23, 10.1016/j.egypro.2013.06.024.