Comprehensive study on the formation of novel polyelectrolyte complexes from (quaternized) poly[2-dimethylamino)ethyl methacrylate] and poly[2-acryloylamido-2-methylpropane sodium sulfonate]

Paneva, Dilyana; Mespouille, Laetitia; Manolova, Nevena; Degée, Philippe; Rashkov, Iliya; Dubois, Philippe

doi:10.1002/pola.21594

Article (Scientific journals)

Comprehensive study on the formation of novel polyelectrolyte complexes from (quaternized) poly[2-dimethylamino)ethyl methacrylate] and poly[2-acryloylamido-2-methylpropane sodium sulfonate]

Paneva, Dilyana; Mespouille, Laetitia; Manolova, Nevena et al.

2006 • In Journal of Polymer Science. Part A-1, Polymer Chemistry, 44 (19), p. 5468-5479

Peer Reviewed verified by ORBi

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https://hdl.handle.net/20.500.12907/17959

DOI
10.1002/pola.21594

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Abstract :

[en] Polyelectrolyte complexes (PECs) have been prepared from well-defined (quaternized) poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) and high molecular weight poly(2-acrylamido-2-methylpropane sodium sulfonate) (PAMPSNa) after a thorough study of their viscometric properties. The effect of pH and quaternization degree of PDMAEMA on PECs stoichiometry has been examined. PEC-based materials have been characterized in terms of thermal stability, equilibrium swelling degree, and free/bound water composition. The stoichiometry and swellability of the physically crosslinked hydrogels obtained from fully quaternized PDMAEMA/PAMPSNa complexes do not depend on pH. In contrast, PECs made of non quaternized PDMAEMA and PAMPSNa are highly affected by pH, and could reversibly disintegrate at pH = 9. Partially quaternized PDMAEMA/PAMPSNa PECs exhibit intermediate properties and form stable loose structures in the whole investigated pH range. Finally, stable dispersions of PECs nanoparticles have been successfully produced from dilute solutions of the complementary polyelectrolytes. The nanoparticle average diameter as determined by dynamic light scattering proved to depend on the molar fraction of DMAEMA-based subunits and on the initial polyelectrolyte concentration.

Disciplines :

Chemistry

Author, co-author :

Paneva, Dilyana

Mespouille, Laetitia

Manolova, Nevena

Degée, Philippe

Rashkov, Iliya

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Language :

English

Title :

Comprehensive study on the formation of novel polyelectrolyte complexes from (quaternized) poly[2-dimethylamino)ethyl methacrylate] and poly[2-acryloylamido-2-methylpropane sodium sulfonate]

Publication date :

01 October 2006

Journal title :

Journal of Polymer Science. Part A-1, Polymer Chemistry

ISSN :

0449-296X

eISSN :

1542-9350

Publisher :

Interscience Publishers, United Kingdom

Volume :

Issue :

Pages :

5468-5479

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publié le 21 août 2006 Lecture en ligne: http://onlinelibrary.wiley.com/doi/10.1002/pola.21594/pdf

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since 10 July 2010

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