Hydrogen-bonding catalyst based on fluorinated alcohol derivatives for living polymerization

[en] Recognize this! A hydrogen-bonding motif based on hexafluorinated alcohol derivatives (see picture; O red, F yellow) activates electrophilic substrates. The catalytic activity of the hydrogen-bonded systems was demonstrated for the ring-opening polymerization of a variety of strained heterocycles. Narrowly dispersed polymers with predictable molecular weights were obtained with end-group fidelity.

Disciplines :

Chemistry

Author, co-author :

Coulembier, Olivier ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Sanders, D.P.

Nelson, Alshakim

Hollenbeck, A.N.

Horn, H.W.

Rice, J.E.

Fujiwara, M.

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Hedrick, James L.

Language :

English

Title :

Hydrogen-bonding catalyst based on fluorinated alcohol derivatives for living polymerization

Publication date :

29 June 2009

Journal title :

Angewandte Chemie International Edition

ISSN :

1433-7851

eISSN :

1521-3773

Publisher :

Wiley, Weinheim, Germany

Volume :

Issue :

Pages :

5170-5173

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Lectue en ligne: http://onlinelibrary.wiley.com/doi/10.1002/anie.200901006/pdf Publié en ligne le 12 juin 2009

Available on ORBi UMONS :

since 10 July 2010

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