Latent, thermally activated organic catalysts for the on-demand living polymerization of lactide

[en] It's all about control: Alcohol adducts of stable N-heterocyclic carbenes function as excellent single-component catalysts/initiators for the ring-opening polymerization of lactide (see scheme). This polymerization can be reversibly terminated simply by modulating the temperature. The use of multifunctional macroinitiators enables the synthesis of more complex polymer architectures.

Disciplines :

Chemistry

Author, co-author :

Coulembier, Olivier ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Dove, A.P.

Pratt, Russel C

Sentman, A.C.

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Mespouille, Laetitia

Waymouth, R.M.

Hedrick, James L.

Culkin, D.A.

Language :

English

Title :

Latent, thermally activated organic catalysts for the on-demand living polymerization of lactide

Publication date :

05 August 2005

Journal title :

Angewandte Chemie International Edition

ISSN :

1433-7851

eISSN :

1521-3773

Publisher :

Wiley, Weinheim, Germany

Volume :

Issue :

Pages :

4964-4968

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publié en ligne le 11 juillet 2005 Lecture en ligne: http://onlinelibrary.wiley.com/doi/10.1002/anie.200500723/pdf

Available on ORBi UMONS :

since 10 July 2010

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112

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