Lanthanide complexes on Ag nanoparticles: Designing contrast agents for magnetic resonance imaging

[en] This paper describes colloidal particles that are designed to induce hyper-intensity contrast (T-1 relaxation) in MRI. The contrast agents consist of discrete gadolinium complexes tethered to 10 rim diameter silver nanoparticles. The gadolinium complexes (1) [Gd(DTPA-bisamido cysteine)](2-) and (2) [Gd(cystine-NTA)(2)](3-), undergo chemisorption to particle Surfaces through thiol or disulfide groups, respectively, to form two new contrast agents. The resulting nanoparticulate constructs are characterized on the basis of their syntheses, composition, spectra and contrast enhancing power. The average r(1) relaxivities of the of the Surface bound complexes (obtained at 9.4 T and 25 degrees C) are 10.7 and 9.7 s(-1) mM(-1), respectively, as compared to 4.7 s(-1) mM(-1) for the clinical agent Magnevist(TM). Correspondingly, the respective whole particle relaxivities are 27927 and 13153 s(-1) mM(-1). (C) 2009 Elsevier Inc. All rights reserved.

Disciplines :

Radiology, nuclear medicine & imaging
Chemistry

Author, co-author :

Siddiqui, T.S.

Jani, A.

Williams, F.

Muller, Robert ; Université de Mons > Faculté de Médecine et de Pharmacie > Chimie générale, organique et biomédicale

Vander Elst, Luce ; Université de Mons > Faculté de Médecine et de Pharmacie > Chimie générale, organique et biomédicale

Laurent, Sophie ; Université de Mons > Faculté de Médecine et de Pharmacie > Chimie générale, organique et biomédicale

Yao, F.

Wadghiri, Y.Z.

Walters, M.A.

Language :

English

Title :

Lanthanide complexes on Ag nanoparticles: Designing contrast agents for magnetic resonance imaging

Publication date :

01 January 2009

Journal title :

Journal of Colloid and Interface Science

ISSN :

0021-9797

eISSN :

1095-7103

Publisher :

Elsevier, Atlanta, United States - Florida

Volume :

337

Issue :

Pages :

88-96

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

M108 - Chimie générale, organique et biomédicale

Available on ORBi UMONS :

since 10 June 2010

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