Reactivity ratios in conventional and nickel-mediated radical copolymerization of methyl methacrylate and functionalized methacrylate monomers

Ydens, I.; Degée, Philippe; Haddleton, D.; Dubois, Philippe

doi:10.1016/j.eurpolymj.2005.04.012

Article (Scientific journals)

Reactivity ratios in conventional and nickel-mediated radical copolymerization of methyl methacrylate and functionalized methacrylate monomers

Ydens, I.; Degée, Philippe; Haddleton, D. et al.

2005 • In European Polymer Journal, 41 (10), p. 2255-2263

Peer Reviewed verified by ORBi

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https://hdl.handle.net/20.500.12907/2630

DOI
10.1016/j.eurpolymj.2005.04.012

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Abstract :

[en] Copolymerization of an excess of methyl methacrylate (MMA) relative to 2-hydroxyethyl methacrylate (HEMA) was carried out in toluene at 80 °C according to both conventional and controlled Ni-mediated radical polymerizations. Reactivity ratios were derived from the copolymerization kinetics using the Jaacks method for MMA and integrated conversion equation for HEMA (rMMA = 0.62 ± 0.04; rHEMA = 2.03 ± 0.74). Poly(ethylene glycol) a-methyl ether, ?-methacrylate (PEGMA, Mn = 475 g mol-1) was substituted for HEMA in the copolymerization experiments and reactivity ratios were also determined (rMMA = 0.75 ± 0.07; rPEGMA ~ 1.33). Both the functionalized comonomers were consumed more rapidly than MMA indicating the preferred formation of heterogeneous bottle-brush copolymer structures with bristles constituted by the hydrophilic (macro)monomers. Reactivity ratios for nickel-mediated living radical polymerization were comparable with those obtained by conventional free radical copolymerization. Interactions between functional monomers and the catalyst (NiBr2(PPh3)2) were observed by 1H NMR spectroscopy.

Disciplines :

Chemistry

Author, co-author :

Ydens, I.

Degée, Philippe

Haddleton, D.

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Language :

English

Title :

Reactivity ratios in conventional and nickel-mediated radical copolymerization of methyl methacrylate and functionalized methacrylate monomers

Publication date :

01 October 2005

Journal title :

European Polymer Journal

ISSN :

0014-3057

eISSN :

1873-1945

Publisher :

Elsevier, United Kingdom

Volume :

Issue :

Pages :

2255-2263

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publié en ligne le 24 juin 2005 Lecture en ligne: http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TWW-4GG8W4S-3-12&_cdi=5573&_user=532054&_pii=S0014305705001692&_origin=search&_coverDate=10%2F31%2F2005&_sk=999589989&view=c&wchp=dGLbVtb-zSkzS&md5=eccf756569b0bd07a12df68e9a7bc75

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