Spatial Control of 3D Energy Transfer in Supramolecular Nanostructured Host-Guest Architectures

[en] Systematic control of 3D energy transfer (ET) dynamics is achieved in supramolecular nanostructured host-guest systems using spacer-functionalized guest chromophores. Quantum chemistry-based Monte Carlo simulations reveal the strong impact of the spacer length on the ET dynamics, efficiency, and dimensionality. Remarkably high exciton diffusion lengths demonstrate that there is ample scope for optimizing oligomeric or polymeric optoelectronic devices.

Disciplines :

Chemistry
Physics

Author, co-author :

Viani, Lucas

Poulsen Tolbod, L.

Jazdzyk, M.

Patrinoiu, G.

Cordella, F.

Mura, A.

Bongiovanni, G.

Botta, C.

Beljonne, David ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux

Cornil, Jérôme ; Université de Mons > Faculté des Sciences > Chimie des matériaux nouveaux

More authors (3 more)

Language :

English

Title :

Spatial Control of 3D Energy Transfer in Supramolecular Nanostructured Host-Guest Architectures

Publication date :

06 August 2009

Journal title :

Journal of Physical Chemistry B

ISSN :

1520-6106

Publisher :

American Chemical Society, United States - District of Columbia

Volume :

113

Issue :

Pages :

10566-10570

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S817 - Chimie des matériaux nouveaux

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publié en ligne le 10 juillet 2009

Available on ORBi UMONS :

since 10 June 2010

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Bibliography

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