Advanced pH-responsive copolymer structures by combination of 'click' chemistry and atom transfer radical polymerization

Van Camp, Wim; Germonpre, V.; Mespouille, Laetitia; Dubois, Philippe; Goethals, E.J.; Du Prez, F.E.

doi:10.1016/j.reactfunctpolym.2007.07.004

Article (Scientific journals)

Advanced pH-responsive copolymer structures by combination of 'click' chemistry and atom transfer radical polymerization

Van Camp, Wim; Germonpre, V.; Mespouille, Laetitia et al.

2007 • In Reactive and Functional Polymers, 67 (11), p. 1168-1180

Peer Reviewed verified by ORBi

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https://hdl.handle.net/20.500.12907/39412

DOI
10.1016/j.reactfunctpolym.2007.07.004

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Abstract :

[en] In this paper, the combination of atom transfer radical polymerization (ATRP) of 1-ethoxyethyl acrylate (EEA) and the copper(I) catalyzed ''click' 1,3-dipolar cycloaddition reaction of azides and terminal alkynes was evaluated as a method to synthesize diverse amphiphilic copolymer structures. Using the 1-ethoxyethyl protecting group strategy, the application field was broadened with the synthesis of complex polymer structures containing poly(acrylic acid) (PAA) segments. A modular approach has been used: polymers with alkyne functionalities as well as azide functionalities have been synthesized. These polymers were subsequently ''clicked' together to yield block copolymers. Furthermore, graft copolymers were synthesized by grafting alkyne-containing polymers onto a polymer backbone with multiple azide functions using the combination of ATRP and ''click' reactions.

Disciplines :

Chemistry

Author, co-author :

Van Camp, Wim

Germonpre, V.

Mespouille, Laetitia ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Goethals, E.J.

Du Prez, F.E.

Language :

English

Title :

Advanced pH-responsive copolymer structures by combination of 'click' chemistry and atom transfer radical polymerization

Publication date :

01 October 2007

Journal title :

Reactive and Functional Polymers

ISSN :

1381-5148

Publisher :

Elsevier, Netherlands

Volume :

Issue :

Pages :

1168-1180

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Lecture en ligne: http://www.pcr.ugent.be/research/Wim-Vanessa-Laetitia2007.pdf Publié en ligne le 14 juillet 2007

Available on ORBi UMONS :

since 10 July 2010

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