Materials Chemistry; Polymers and Plastics; Organic Chemistry
Disciplines :
Chemistry
Author, co-author :
Fernández-Tena, Ainhoa ; POLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain
Pérez-Camargo, Ricardo Arpad ; Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Coulembier, Olivier ; Université de Mons - UMONS > Faculté des Sciences > Service des Matériaux Polymères et Composites
Sangroniz, Leire; POLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain
Aranburu, Nora ; POLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain
Guerrica-Echevarria, Gonzalo ; POLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain
Liu, Guoming ; Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China ; University of Chinese Academy of Science, Beijing 100049, China
Wang, Dujin ; Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China ; University of Chinese Academy of Science, Beijing 100049, China
Cavallo, Dario ; Department of Chemistry and Industrial Chemistry, University of Genova, 16146 Genova, Italy
Müller, Alejandro J. ; POLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain ; IKERBASQUE, Basque Foundation for Science, Plaza Euskadi 5, 48009 Bilbao, Spain
Language :
English
Title :
Effect of Molecular Weight on the Crystallization and Melt Memory of Poly(ε-caprolactone) (PCL)
Labet, M.; Thielemans, W. Synthesis of Polycaprolactone: A Review. Chem. Soc. Rev. 2009, 38, 3484- 3504, 10.1039/b820162p
Bartnikowski, M.; Dargaville, T. R.; Ivanovski, S.; Hutmacher, D. W. Degradation Mechanisms of Polycaprolactone in the Context of Chemistry, Geometry and Environment. Prog. Polym. Sci. 2019, 96, 1- 20, 10.1016/j.progpolymsci.2019.05.004
Jenkins, M. J.; Harrison, K. L. The Effect of Molecular Weight on the Crystallization Kinetics of Polycaprolactone. Polym. Adv. Technol. 2006, 17, 474- 478, 10.1002/pat.733
Nofar, M.; Sacligil, D.; Carreau, P. J.; Kamal, M. R.; Heuzey, M. C. Poly(Lactic Acid) Blends: Processing, Properties and Applications. Int. J. Biol. Macromol. 2019, 125, 307- 360, 10.1016/j.ijbiomac.2018.12.002
Kfoury, G.; Raquez, J.-M.; Hassouna, F.; Odent, J.; Toniazzo, V.; Ruch, D.; Dubois, P. Recent Advances in High Performance Poly(Lactide): From “Green” Plasticization to Super-Tough Materials via (Reactive) Compounding. Front. Chem. 2013, 1, 32 10.3389/fchem.2013.00032
Fortelny, I.; Ujcic, A.; Fambri, L.; Slouf, M. Phase Structure, Compatibility, and Toughness of PLA/PCL Blends: A Review. Front. Mater. 2019, 6, 206 10.3389/fmats.2019.00206
Du, Z.-X.; Ynag, Y.; Xu, J.-T.; Fan, Z.-Q. Effect of Molecular Weight on Spherulitic Growth Rate of Poly(ϵ-Caprolactone) and Poly(ϵ-Caprolactone)-b-Poly(Ethylene Glycol). J. Appl. Polym. Sci. 2007, 104, 2986- 2991, 10.1002/app.25932
Klonos, P. A.; Bikiaris, N. D.; Christodoulou, E.; Zamboulis, A.; Papageorgiou, G. Z.; Kyritsis, A. Molecular Mobility, Crystallization and Melt-Memory Investigation of Molar Mass Effects on Linear and Hydroxyl-Terminated Poly(ϵ-Caprolactone). Polymer 2022, 242, 124603 10.1016/j.polymer.2022.124603
Zabihzadeh Khajavi, M.; Ebrahimi, A.; Yousefi, M.; Ahmadi, S.; Farhoodi, M.; Mirza Alizadeh, A.; Taslikh, M. Strategies for Producing Improved Oxygen Barrier Materials Appropriate for the Food Packaging Sector. Food Eng. Rev. 2020, 12, 346- 363, 10.1007/s12393-020-09235-y
Sangroniz, L.; Ocando, C.; Cavallo, D.; Müller, A. J. Melt Memory Effects in Poly(Butylene Succinate) Studied by Differential Fast Scanning Calorimetry. Polymers 2020, 12, 2796 10.3390/polym12122796
Sangroniz, L.; Sangroniz, A.; Meabe, L.; Basterretxea, A.; Sardon, H.; Cavallo, D.; Müller, A. J. Chemical Structure Drives Memory Effects in the Crystallization of Homopolymers. Macromolecules 2020, 53, 4874- 4881, 10.1021/acs.macromol.0c00751
Liu, X.; Wang, Y.; Wang, Z.; Cavallo, D.; Müller, A. J.; Zhu, P.; Zhao, Y.; Dong, X.; Wang, D. The Origin of Memory Effects in the Crystallization of Polyamides: Role of Hydrogen Bonding. Polymer 2020, 188, 122117 10.1016/j.polymer.2019.122117
Michell, R. M.; Mugica, A.; Zubitur, M.; Müller, A. J. Self-Nucleation of Crystalline Phases within Homopolymers, Polymer Blends, Copolymers, and Nanocomposites. Adv. Polym. Sci. 2017, 276, 215- 256, 10.1007/12_2015_327
Sangroniz, L.; Cavallo, D.; Müller, A. J. Self-Nucleation Effects on Polymer Crystallization. Macromolecules 2020, 53, 4581- 4604, 10.1021/acs.macromol.0c00223
Marxsen, S. F.; Alamo, R. G. Melt-Memory of Polyethylenes with Halogen Substitution: Random vs. Precise Placement. Polymer 2019, 168, 168- 177, 10.1016/j.polymer.2019.02.030
Wang, X.; Yi, J.; Wang, L.; Feng, J. Comparison of the Melt Memory Effects in Matched Fractions Segregated from Ziegler-Natta and Metallocene-Made Isotactic Polypropylene with Similar Total Defect Content. Polymer 2021, 230, 124060 10.1016/j.polymer.2021.124060
Pérez-Camargo, R. A.; Meabe, L.; Liu, G.; Sardon, H.; Zhao, Y.; Wang, D.; Müller, A. J. Even-Odd Effect in Aliphatic Polycarbonates with Different Chain Lengths: From Poly (Hexamethylene Carbonate) to Poly (Dodecamethylene Carbonate). Macromolecules 2021, 54, 259- 271, 10.1021/acs.macromol.0c02374
Zaldua, N.; Liénard, R.; Josse, T.; Zubitur, M.; Mugica, A.; Iturrospe, A.; Arbe, A.; De Winter, J.; Coulembier, O.; Müller, A. J. Influence of Chain Topology (Cyclic versus Linear) on the Nucleation and Isothermal Crystallization of Poly(L-Lactide) and Poly(D-Lactide). Macromolecules 2018, 51, 1718- 1732, 10.1021/acs.macromol.7b02638
Pérez, R.; Córdova, M. E.; López, J. V.; Hoskins, J. N.; Zhang, B.; Grayson, S. M.; Müller, A. J. Nucleation, Crystallization, Self-Nucleation and Thermal Fractionation of Cyclic and Linear Poly(ϵ-Caprolactone)s. React. Funct. Polym. 2014, 80, 71- 82, 10.1016/j.reactfunctpolym.2013.10.013
Lorenzo, A. T.; Arnal, M. L.; Sánchez, J. J.; Müller, A. J. Effect of Annealing Time on the Self-Nucleation Behavior of Semicrystalline Polymers. J. Polym. Sci., Part B: Polym. Phys. 2006, 44, 1738- 1750, 10.1002/polb.20832
Chen, X.; Qu, C.; Alamo, R. G. Effect of Annealing Time and Molecular Weight on Melt Memory of Random Ethylene 1-Butene Copolymers. Polym. Int. 2019, 68, 248- 256, 10.1002/pi.5586
Schmalz, H.; Müller, A. J.; Abetz, V. Crystallization in ABC Triblock Copolymers with Two Different Crystalline End Blocks: Influence of Confinement on Self-Nucleation Behavior. Macromol. Chem. Phys. 2003, 204, 111- 124, 10.1002/macp.200290063
Müller, A. J.; Albuerne, J.; Marquez, L.; Raquez, J. M.; Degée, P.; Dubois, P.; Hobbs, J.; Hamley, I. W. Self-Nucleation and Crystallization Kinetics of Double Crystalline Poly(p-Dioxanone)-b-Poly(ϵ-Caprolactone) Diblock Copolymers. Faraday Discuss. 2005, 128, 231- 252, 10.1039/b403085k
Chen, H. L.; Li, L. J.; Ou-Yang, W. C.; Hwang, J. C.; Wong, W.-Y. Spherulitic Crystallization Behavior of Poly(ϵ-Caprolactone) with a Wide Range of Molecular Weight. Macomolecules 1997, 30, 1718- 1722, 10.1021/ma960673v
Wurm, A.; Zhuravlev, E.; Eckstein, K.; Jehnichen, D.; Pospiech, D.; Androsch, R.; Wunderlich, B.; Schick, C. Crystallization and Homogeneous Nucleation Kinetics of Poly(ϵ- Caprolactone) (PCL) with Different Molar Masses. Macromolecules 2012, 45, 3816- 3828, 10.1021/ma300363b
Su, H. H.; Chen, H. L.; Díaz, A.; Casas, M. T.; Puiggalí, J.; Hoskins, J. N.; Grayson, S. M.; Pérez, R. A.; Müller, A. J. New Insights on the Crystallization and Melting of Cyclic PCL Chains on the Basis of a Modified Thomson-Gibbs Equation. Polymer 2013, 54, 846- 859, 10.1016/j.polymer.2012.11.066
Córdova, M. E.; Lorenzo, A. T.; Müller, A. J.; Hoskins, J. N.; Grayson, S. M. A Comparative Study on the Crystallization Behavior of Analogous Linear and Cyclic Poly(ϵ-Caprolactones). Macromolecules 2011, 44, 1742- 1746, 10.1021/ma200394h
Li, Z.; Wang, J.; Pérez-Camargo, R. A.; Müller, A. J.; Zhang, B.; Grayson, S. M.; Hu, W. Non-Monotonic Molecular Weight Dependence of Crystallization Rates of Linear and Cyclic Poly(Epsilon-Caprolactone)s in a Wide Temperature Range. Polym. Int. 2016, 65, 1074- 1079, 10.1002/pi.5157
Shin, E. J.; Jeong, W.; Brown, H. A.; Koo, B. J.; Hedrick, J. L.; Waymouth, R. M. Crystallization of Cyclic Polymers: Synthesis and Crystallization Behavior of High Molecular Weight Cyclic Poly(ϵ-Caprolactone)s. Macromolecules 2011, 44, 2773- 2779, 10.1021/ma102970m
Skoglund, P.; Fransson, A. Continuous Cooling and Isothermal Crystallization of Polycaprolactone. J. Appl. Polym. Sci. 1996, 61, 2455- 2465, 10.1002/(SICI)1097-4628(19960926)61:13<2455::AID-APP25>3.0.CO;2-1
Ou-Yang, W. C.; Li, L. J.; Chen, H. L.; Hwang, J. C. Bulk Crystallization Behavior of Poly(ϵ-Caprolactone) with a Wide Range of Molecular Weight. Polym. J. 1997, 29, 889- 893, 10.1295/polymj.29.889
Safari, M.; Mugica, A.; Zubitur, M.; Martínez de Ilarduya, A.; Muñoz-Guerra, S.; Müller, A. J. Controlling the Isothermal Crystallization of Isodimorphic PBS-Ran-PCL Random Copolymers by Varying Composition and Supercooling. Polymers 2020, 12, 17 10.3390/polym12010017
Lorenzo, A. T.; Arnal, M. L.; Albuerne, J.; Müller, A. J. DSC Isothermal Polymer Crystallization Kinetics Measurements and the Use of the Avrami Equation to Fit the Data: Guidelines to Avoid Common Problems. Polym. Test. 2007, 26, 222- 231, 10.1016/j.polymertesting.2006.10.005
Pérez-Camargo, R. A.; Liu, G. M.; Wang, D. J.; Müller, A. J. Experimental and Data Fitting Guidelines for the Determination of Polymer Crystallization Kinetics. Chin. J. Polym. Sci. 2022, 40, 658- 691, 10.1007/s10118-022-2724-2
Hoffman, J. D.; Weeks, J. J. Melting Process and the Equilibrium Melting Temperature of Polychlorotrifluoroethylene. J. Res. Natl. Bur. Stand., Sect. A 1962, 66A, 13- 28, 10.6028/jres.066a.003
Fillon, B.; Wittmann, J. C.; Lotz, B.; Thierry, A. Self-nucleation and Recrystallization of Isotactic Polypropylene (α Phase) Investigated by Differential Scanning Calorimetry. J. Polym. Sci., Part B: Polym. Phys. 1993, 31, 1383- 1393, 10.1002/polb.1993.090311013
Sangroniz, L.; Alamo, R. G.; Cavallo, D.; Santamaría, A.; Müller, A. J.; Alegría, A. Differences between Isotropic and Self-Nucleated PCL Melts Detected by Dielectric Experiments. Macromolecules 2018, 51, 3663- 3671, 10.1021/acs.macromol.8b00708
Müller, A. J.; Hernandez, Z. H.; Arnal, M. L.; Sanchez, J. J. Successive Self-Nucleation/Annealing (SSA): A Novel Techique to Study Molecular Segregation during Crystallization. Polym. Bull. 1997, 39, 465- 472, 10.1007/s002890050174
Pérez-Camargo, R. A.; Cavallo, D.; Müller, A. J. Recent Applications of the Successive Self-Nucleation and Annealing Thermal Fractionation Technique. Front. Soft Matter 2022, 2, 1003500 10.3389/frsfm.2022.1003500
Mathot, V. B. F. The Crystallization and Melting Region. Calorymetry and Thermal Analysis of Polymers; Hanser Publishers, 1995.
Trujillo, M.; Arnal, M. L.; Müller, A. J.; Mujica, M. A.; Urbina De Navarro, C.; Ruelle, B.; Dubois, P. Supernucleation and Crystallization Regime Change Provoked by MWNT Addition to Poly(ϵ-Caprolactone). Polymer 2012, 53, 832- 841, 10.1016/j.polymer.2011.12.028
Müller, A. J.; Michell, R. M.; Lorenzo, A. T. Isothermal Crystallization Kinetics of Polymers. In Polymer Morphology; John Wiley & Sons, Inc.: Hoboken, New Jersey, 2016.
Umemoto, S.; Kobayashi, N.; Okui, N. Molecular Weight Dependence of Crystal Growth Rate and Its Degree of Supercooling Effect. J. Macromol. Sci., Part B: Phys. 2002, 41, 923- 938, 10.1081/MB-120013074
Pérez, R. A.; López, J. V.; Hoskins, J. N.; Zhang, B.; Grayson, S. M.; Casas, M. T.; Puiggalí, J.; Müller, A. J. Nucleation and Antinucleation Effects of Functionalized Carbon Nanotubes on Cyclic and Linear Poly(ϵ-Caprolactones). Macromolecules 2014, 47, 3553- 3566, 10.1021/ma5005869
Phillips, P. J.; Rensch, G. J.; Taylor, K. D. Crystallization Studies of Poly(E-caprolactone). I. Morphology and Kinetics. J. Polym. Sci., Part B: Polym. Phys. 1987, 25, 1725- 1740, 10.1002/polb.1987.090250814
Caputo, M. R.; Tang, X.; Westlie, A. H.; Sardon, H.; Chen, E. Y.; Mu, A. J. Effect of Chain Stereoconfiguration on Poly(3-Hydroxybutyrate) Crystallization Kinetics. Biomacromolecules 2022, 23, 3847- 3859, 10.1021/acs.biomac.2c00682
Colomer Vilanova, P.; Ribas, S. M.; Guzman, G. M. Isothermal Crystallization of Poly(Ethylene-Terephthalate) of Low Molecular Weight by Differential Scanning Calorimetry: 1. Crystallization Kinetics. Polymer 1985, 26, 423- 428, 10.1016/0032-3861(85)90205-8
Maiz, J.; Liu, G.; Ruipérez, F.; Delbosc, N.; Coulembier, O.; Wang, D.; Müller, A. J. How Cyclic Chain Toplogy Can Reduce the Crystallization Rate of Poly(3-Hexylthiophene) and Promote the Formation of Liquid Crystalline Phases in Comparison with Linear Analogue Chains. J. Mater. Chem. C 2019, 7, 6548- 6558, 10.1039/C9TC01609K
Fatou, J. G.; Marco, C.; Mandelkern, L. The Crystallization Kinetics of Low-Molecular-Weight Polyethylene Fractions. Polymer 1990, 31, 890- 898, 10.1016/0032-3861(90)90052-Z
Fatou, J. G.; Marco, C.; Mandelkern, L. The Influence of Molecular Weight on the Regime Crystallization of Linear Polyethylene. Polymer 1990, 31, 1685- 1693, 10.1016/0032-3861(90)90186-3
Godovsky, Y. K.; Slonimsky, G. L.; Garbar, N. M. Effect of Molecular Weight on the Crystallization and Morphology of Poly(Ethylene Oxide) Fractions. J. Polym. Sci., Part C: Polym. Symp. 2007, 38, 1- 21, 10.1002/polc.5070380103
Mandelkern, L.; Fatou, J. G.; Ohno, K. The Molecular Weight Dependence of the Crystallization Rate for Linear Polyethylene Fractions. J. Polym. Sci., Part B: Polym. Lett. 1968, 6, 615- 619, 10.1002/pol.1968.110060901
Wang, Z. G.; Hsiao, B. S.; Fu, B. X.; Liu, L.; Yeh, F.; Sauer, B. B.; Chang, H.; Schultz, J. M. Correct Determination of Crystal Lamellar Thickness in Semicrystalline Poly(Ethylene Terephthalate) by Small-Angle X-Ray Scattering. Polymer 2000, 41, 1791- 1797, 10.1016/S0032-3861(99)00327-4
Ryan, A. J.; Stanford, J. L.; Bras, W.; Nye, T. M. W. A Synchrotron X-Ray Study of Melting and Recrystallization in Isotactic Polypropylene. Polymer 1997, 38, 759- 768, 10.1016/S0032-3861(96)00583-6
Schulz, M.; Seidlitz, A.; Kurz, R.; Bärenwald, R.; Petzold, A.; Saalwächter, K.; Thurn-Albrecht, T. The Underestimated Effect of Intracrystalline Chain Dynamics on the Morphology and Stability of Semicrystalline Polymers. Macromolecules 2018, 51, 8377- 8385, 10.1021/acs.macromol.8b01102
Jiang, Z.; Wang, Y.; Fu, L.; Whiteside, B.; Wyborn, J.; Norris, K.; Wu, Z.; Coates, P.; Men, Y. Tensile Deformation of Oriented Poly(ϵ-Caprolactone) and Its Miscible Blends with Poly(Vinyl Methyl Ether). Macromolecules 2013, 46, 6981- 6990, 10.1021/ma401052x
Schulz, M.; Schäfer, M.; Saalwächter, K.; Thurn-Albrecht, T. Competition between Crystal Growth and Intracrystalline Chain Diffusion Determines the Lamellar Thickness in Semicrystalline Polymers. Nat. Commun. 2022, 13, 119 10.1038/s41467-021-27752-0
Kurz, R.; Schulz, M.; Scheliga, F.; Men, Y.; Seidlitz, A.; Thurn-Albrecht, T.; Saalwächter, K. Interplay between Crystallization and Entanglements in the Amorphous Phase of the Crystal-Fixed Polymer Poly(ϵ-Caprolactone). Macromolecules 2018, 51, 5831- 5841, 10.1021/acs.macromol.8b00809
Chatani, Y.; Okita, Y.; Tadokoro, H.; Yamashita, Y. Structural Studies of Polyesters. III. Crystal Structure of Poly-ϵ-Caprolactone. Polym. J. 1970, 1, 555- 562, 10.1295/polymj.1.555
Hu, H.; Dorset, D. L. Crystal Structure of Poly(ϵ-Caprolactone). Macromolecules 1990, 23, 4604- 4607, 10.1021/ma00223a017
Trujillo, M.; Arnal, M. L.; Müller, A. J.; Laredo, E.; Bredeau, S.; Bonduel, D.; Dubois, P. Thermal and Morphological Characterization of Nanocomposites Prepared by in-Situ Polymerization of High-Density Polyethylene on Carbon Nanotubes. Macomolecules 2007, 40, 6268- 6276, 10.1021/ma071025m
Balsamo, V.; Paolini, Y.; Ronca, G.; Müller, A. J. Crystallization of the Polyethylene Block in Polystyrene-b-Polyethylene-b-Polycaprolactone Triblock Copolymers, 1: Self-Nucleation Behavior. Macromol. Chem. Phys. 2000, 201, 2711- 2720, 10.1002/1521-3935(20001201)201:18<2711::AID-MACP2711>3.0.CO;2-6
Müller, A. J.; Balsamo, V.; Arnal, M. L. Nucleation and Crystallization in Diblock and Triblock Copolymers. In Block Copolymers II. Advances in Polymer Science; Abetz, V., Ed.; Springer: Berlin, Heidelberg, 2005; Vol. 190, pp 1- 63.
Blundell, D. J.; Keller, A. Nature of Self-Seeding Polyethylene Crystal Nuclei. J. Macromol. Sci., Part B: Phys. 1968, 2, 301- 336, 10.1080/00222346808212454
Gimenez, J.; Cassagnau, P.; Fulchiron, R.; Michel, A. Structure and Dynamics of Melt Poly(ϵ-Caprolactone) from Inverse Rheological Calculation. Macromol. Chem. Phys. 2000, 201, 479- 490, 10.1002/(SICI)1521-3935(20000301)201:5<479::AID-MACP479<3.0.CO;2-F
Ugartemendia, J. M.; Muñoz, M. E.; Sarasua, J. R.; Santamaria, A. Phase Behavior and Effects of Microstructure on Viscoelastic Properties of a Series of Polylactides and Polylactide/Poly(ϵ-Caprolactone) Copolymers. Rheol. Acta 2014, 53, 857- 868, 10.1007/s00397-014-0797-8
Noroozi, N.; Thomson, J. A.; Noroozi, N.; Schafer, L. L.; Hatzikiriakos, S. G. Viscoelastic Behaviour and Flow Instabilities of Biodegradable Poly(ϵ-Caprolactone) Polyesters. Rheol. Acta 2012, 51, 179- 192, 10.1007/s00397-011-0586-6
Sangroniz, L.; Barbieri, F.; Cavallo, D.; Santamaria, A.; Alamo, R. G.; Müller, A. J. Rheology of Self-Nucleated Poly(ϵ-Caprolactone) Melts. Eur. Polym. J. 2018, 99, 495- 503, 10.1016/j.eurpolymj.2018.01.009
Gimenez, J.; Cassagnau, P.; Michel, A. Bulk Polymerization of ϵ-Caprolactone: Rheological Predictive Laws. J. Rheol. 2000, 44, 527- 547, 10.1122/1.551099
Izuka, A.; Winter, H. H.; Hashimoto, T. Molecular Weight Dependence of Viscoelasticity of Polycaprolactone Critical Gels. Macromolecules 1992, 25, 2422- 2428, 10.1021/ma00035a020
Zhu, L.; Li, J.; Li, H.; Liu, B.; Chen, J.; Jiang, S. End Groups Affected Crystallization Behavior of Unentangled Poly(ϵ-Caprolactone)S. Polymer 2022, 241, 124534 10.1016/j.polymer.2022.124534
Pérez-Camargo, R. A.; Saenz, G.; Laurichesse, S.; Casas, M. T.; Puiggalí, J.; Avérous, L.; Müller, A. J. Nucleation, Crystallization and Thermal Fractionation of Poly(ϵ-Caprolactone)-Grafted-Lignin: Effects of Grafted Chains Length and Lignin Content. J. Polym. Sci. 2015, 53, 1736- 1750, 10.1002/polb.23897
Müller, A. J.; Arnal, M. L. Thermal Fractionation of Polymers. Prog. Polym. Sci. 2005, 30, 559- 603, 10.1016/j.progpolymsci.2005.03.001
Müller, A.; Michell, R. M.; Pérez, R. A.; Lorenzo, A. T. Successive Self-Nucleation and Annealing (SSA): Correct Design of Thermal Protocol and Applications. Eur. Polym. J. 2015, 65, 132- 154, 10.1016/j.eurpolymj.2015.01.015
Garlotta, D. A Literature Review of Poly (Lactic Acid). J. Polym. Environ. 2001, 9, 63- 84, 10.1023/A:1020200822435