AA2024; GDOES; Plasma electrolytic oxidation; Sol-gel sealing; SVET; Aa2024; Plasma electrolytic oxidation coatings; Porous structures; Self-healing; Self-healing properties; Sol'gel; Chemistry (all); Chemical Engineering (all); Materials Science (all); General Materials Science; General Chemical Engineering; General Chemistry
Abstract :
[en] The inherent porous structure of PEO coatings is regarded as a drawback for long-term protection. In this investigation, the presence of pores and defects in the PEO coating was exploited as reservoirs for corrosion inhibitors to generate self-healing properties on AA2024. Smart coating systems were fabricated on the PEO layer in which 8-hydroxyquinoline (8-HQ) and benzotriazole (BTA) were employed as corrosion inhibitive layers followed by a sol-gel sealing. The protective performance relies on the mechanical interlocking between the sol-gel coating and the sublayer plus the sealing ability of the sol-gel in the presence of the intermediate layer.
Research center :
CRIM - Ingénierie des matériaux
Disciplines :
Materials science & engineering
Author, co-author :
Akbarzadeh, Sajjad ; Université de Mons - UMONS > Faculté Polytechniqu > Service de Science des Matériaux
Coelho, Leonardo Bertolucci; Materials Science Department, Faculty of Engineering, University of Mons, Mons, Belgium ; ChemSIN – Chemistry of Surfaces, Interfaces and Nanomaterials, Université libre de Bruxelles (ULB), Brussels, Belgium
Dangreau, Lisa; Materia Nova Research Centre, Mons, Belgium
Lanzutti, Alex ; Department of Chemistry Physics and Environment, University of Udine, Udine, Italy
Fedrizzi, Lorenzo; Department of Chemistry Physics and Environment, University of Udine, Udine, Italy
Olivier, Marie-Georges ; Université de Mons - UMONS > Faculté Polytechniqu > Service de Science des Matériaux ; Materia Nova Research Centre, Mons, Belgium
Language :
English
Title :
Self-healing plasma electrolytic oxidation (PEO) coating developed by an assembly of corrosion inhibitive layer and sol-gel sealing on AA2024
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Name of the research project :
4573 - SEALCERA - Corrosion and tribocorrosion performance of sealed ceramic coatings obtained by plasma electrolytic oxidation - Fédération Wallonie Bruxelles
Funding text :
The authors would like to warmly acknowledge the financial support from the University of Mons in the framework of the ARC (Action de Recherche collective) 2018 SEALCERA project (Fédération Wallonie Bruxelles). The author L.B. Coelho is a Postdoctoral Researcher at the Fonds de la Recherche Scientifique – FNRS (Belgium) which is gratefully acknowledged. Last but not least, the authors appreciate the efforts of Alexandre Mégret from the Metallurgy Department of the University of Mons in performing the GIXRD analysis.
Jothi, V., Adesina, A.Y., Madhan Kumar, A., Nirmal Ram, J.S., Influence of organic acids on the surface and corrosion resistant behavior of anodized films on aa2024 aerospace alloys in artificial seawater. Met. Mater. Int. 26 (2020), 1611–1620.
Zhang, X., Zhou, X., Hashimoto, T., Liu, B., Localized corrosion in AA2024-T351 aluminium alloy: Transition from intergranular corrosion to crystallographic pitting. Mater. Charact. 130 (2017), 230–236.
Murer, N., Oltra, R., Vuillemin, B., Néel, O., Numerical modelling of the galvanic coupling in aluminium alloys: A discussion on the application of local probe techniques. Corros. Sci. 52 (2010), 130–139.
Vukmirovic, M.B., Dimitrov, N., Sieradzki, K., Dealloying and corrosion of Al alloy 2024-T3. J. Electrochem. Soc., 149, 2002, B428.
Capelossi, V.R., Poelman, M., Recloux, I., Hernandez, R.P.B., De Melo, H.G., Olivier, M.G., Corrosion protection of clad 2024 aluminum alloy anodized in tartaric-sulfuric acid bath and protected with hybrid sol–gel coating. Electrochim. Acta 124 (2014), 69–79.
Ryabchikov, A.I., Kashkarov, E.B., Shevelev, A.E., Obrosov, A., Sivin, D.O., Surface modification of Al by high-intensity low-energy Ti-ion implantation: Microstructure, mechanical and tribological properties. Surf. Coat. Technol. 372 (2019), 1–8.
Wang, L.F., Sun, J., Yu, X.L., Shi, Y., Zhu, X.G., Cheng, L.Y., Liang, H.H., Yan, B., Guo, L.J., Enhancement in mechanical properties of selectively laser-melted AlSi10Mg aluminum alloys by T6-like heat treatment. Mater. Sci. Eng. A. 734 (2018), 299–310.
Haixiang, C., Dejun, K., Comparison on electrochemical corrosion performances of arc and laser thermal sprayed Al–Ti–Ni coatings in marine environment. Mater. Chem. Phys., 251, 2020, 123200.
Rao, G.M., Dilkush, Gopal, A.V., Effect of physical vapour deposition coated and uncoated carbide tools in turning aluminium alloy-AA6063. Mater. Today Proc. 41 (2021), 1212–1219.
Yu, F., Camilli, L., Wang, T., Mackenzie, D.M.A., Curioni, M., Akid, R., Bøggild, P., Complete long-term corrosion protection with chemical vapor deposited graphene. Carbon N. Y 132 (2018), 78–84.
Verdalet-Guardiola, X., Fori, B., Bonino, J.P., Duluard, S., Blanc, C., Nucleation and growth mechanisms of trivalent chromium conversion coatings on 2024-T3 aluminium alloy. Corros. Sci. 155 (2019), 109–120.
Akbarzadeh, S., Sopchenski Santos, L., Vitry, V., Paint, Y., Olivier, M.G., Improvement of the corrosion performance of AA2024 alloy by a duplex PEO/clay modified sol-gel nanocomposite coating. Surf. Coat. Technol., 434, 2022, 128168.
del Olmo, R., Mohedano, M., Visser, P., Matykina, E., Arrabal, R., Flash-PEO coatings loaded with corrosion inhibitors on AA2024. Surf. Coat. Technol., 402, 2020, 126317.
Arrabal, R., Mohedano, M., Matykina, E., Pardo, A., Mingo, B., Merino, M.C., Characterization and wear behaviour of PEO coatings on 6082-T6 aluminium alloy with incorporated α-Al2O3 particles. Surf. Coat. Technol. 269 (2015), 64–73.
Molaeipour, P., Allahkaram, S.R., Akbarzadeh, S., Corrosion inhibition of Ti6Al4V alloy by a protective plasma electrolytic oxidation coating modified with boron carbide nanoparticles. Surf. Coat. Technol., 430, 2022, 127987.
Mingo, B., Guo, Y., Němcová, A., Gholinia, A., Mohedano, M., Sun, M., Matthews, A., Yerokhin, A., Incorporation of halloysite nanotubes into forsterite surface layer during plasma electrolytic oxidation of AM50 Mg alloy. Electrochim. Acta 299 (2019), 772–788.
Hamrahi, B., Yarmand, B., Massoudi, A., Improved in-vitro corrosion performance of titanium using a duplex system of plasma electrolytic oxidation and graphene oxide incorporated silane coatings, Surf. Coatings Technol., 422, 2021, 127558.
Peitao, G., Mingyang, T., Chaoyang, Z., Tribological and corrosion resistance properties of graphite composite coating on AZ31 Mg alloy surface produced by plasma electrolytic oxidation. Surf. Coat. Technol. 359 (2019), 197–205.
Jun Xie, H., Liang Cheng, Y., Xian Li, S., Hui Cao, J., Cao, L., Wear and corrosion resistant coatings on surface of cast A356 aluminum alloy by plasma electrolytic oxidation in moderately concentrated aluminate electrolytes. Trans. Nonferrous Met. Soc. China 27 (2017), 336–351.
Li, K., Li, W., Zhang, G., Zhu, W., Zheng, F., Zhang, D., Wang, M., Effects of Si phase refinement on the plasma electrolytic oxidation of eutectic Al-Si alloy. J. Alloy. Compd. 790 (2019), 650–656.
Wang, L., Chen, L., Yan, Z., Fu, W., Optical emission spectroscopy studies of discharge mechanism and plasma characteristics during plasma electrolytic oxidation of magnesium in different electrolytes. Surf. Coat. Technol. 205 (2010), 1651–1658.
Snizhko, L.O., Yerokhin, A.L., Pilkington, A., Gurevina, N.L., Misnyankin, D.O., Leyland, A., Matthews, A., Anodic processes in plasma electrolytic oxidation of aluminium in alkaline solutions. Electrochim. Acta 49 (2004), 2085–2095.
Treviño, M., Mercado-Solis, R.D., Colás, R., Pérez, A., Talamantes, J., Velasco, A., Erosive wear of plasma electrolytic oxidation layers on aluminium alloy 6061. Wear 301 (2013), 434–441.
Pezzato, L., Babbolin, R., Cerchier, P., Marigo, M., Dolcet, P., Dabalà, M., Brunelli, K., Sealing of PEO coated AZ91magnesium alloy using solutions containing neodymium. Corros. Sci., 173, 2020, 108741.
Joo, J., Kim, D., Moon, H.S., Kim, K., Lee, J., Durable anti-corrosive oil-impregnated porous surface of magnesium alloy by plasma electrolytic oxidation with hydrothermal treatment. Appl. Surf. Sci., 509, 2020, 145361.
Mashtalyar, D.V., Nadaraia, K.V., Imshinetskiy, I.M., Belov, E.A., Filonina, V.S., Suchkov, S.N., Sinebryukhov, S.L., Gnedenkov, S.V., Composite coatings formed on Ti by PEO and fluoropolymer treatment. Appl. Surf. Sci., 536, 2021, 147976.
Akbarzadeh, S., Ramezanzadeh, M., Ramezanzadeh, B., Mahdavian, M., Naderi, R., Fabrication of highly effective polyaniline grafted carbon nanotubes to induce active protective functioning in a silane coating. Ind. Eng. Chem. Res. 58 (2019), 20309–20322.
Mehner, A., Zoch, H.W., Datchary, W., Pongs, G., Sol-gel coatings for high precision optical molds. CIRP Ann. 55 (2006), 589–592.
Akbarzadeh, S., Akbarzadeh, K., Ramezanzadeh, M., Naderi, R., Mahdavian, M., Olivier, M.G., Corrosion resistance enhancement of a sol-gel coating by incorporation of modified carbon nanotubes: Artificial neural network (ANN) modeling and experimental explorations. Prog. Org. Coat., 174, 2023, 107296.
Mackenzie, J.D., Bescher, E.P., Physical properties of sol-gel coatings. J. Sol. Gel Sci. Technol. 19 (2000), 23–29.
Akbarzadeh, S., Naderi, R., Mahdavian, M., Fabrication of a highly protective silane composite coating with limited water uptake utilizing functionalized carbon nano-tubes. Compos. Part B Eng., 175, 2019, 107109.
Wang, C., Shen, J., Zhang, X., Duan, B., Sang, J., In vitro degradation and cytocompatibility of a silane/Mg(OH)2 composite coating on AZ31 alloy by spin coating. J. Alloy. Compd. 714 (2017), 186–193.
Nezamdoust, S., Seifzadeh, D., Application of CeH–V/ sol–gel composite coating for corrosion protection of AM60B magnesium alloy. Trans. Nonferrous Met. Soc. China 27 (2017), 352–362.
Hu, J., Zeng, D., Zhang, Z., Shi, T., Song, G.L., Guo, X., 2-Hydroxy-4-methoxy-acetophenone as an environment-friendly corrosion inhibitor for AZ91D magnesium alloy. Corros. Sci. 74 (2013), 35–43.
Dinodi, N., Shetty, A.N., Alkyl carboxylates as efficient and green inhibitors of magnesium alloy ZE41 corrosion in aqueous salt solution. Corros. Sci. 85 (2014), 411–427.
Kartsonakis, I.A., Stanciu, S.G., Matei, A.A., Karaxi, E.K., Hristu, R., Karantonis, A., Charitidis, C.A., Evaluation of the protective ability of typical corrosion inhibitors for magnesium alloys towards the Mg ZK30 variant. Corros. Sci. 100 (2015), 194–208.
Lu, X., Li, Y., Ju, P., Chen, Y., Yang, J., Qian, K., Zhang, T., Wang, F., Unveiling the inhibition mechanism of an effective inhibitor for AZ91 Mg alloy. Corros. Sci. 148 (2019), 264–271.
Sun, M., Yerokhin, A., Bychkova, M.Y., Shtansky, D.V., Levashov, E.A., Matthews, A., Self-healing plasma electrolytic oxidation coatings doped with benzotriazole loaded halloysite nanotubes on AM50 magnesium alloy. Corros. Sci. 111 (2016), 753–769.
Kartsonakis, I.A., Athanasopoulou, E., Snihirova, D., Martins, B., Koklioti, M.A., Montemor, M.F., Kordas, G., Charitidis, C.A., Multifunctional epoxy coatings combining a mixture of traps and inhibitor loaded nanocontainers for corrosion protection of AA2024-T3. Corros. Sci. 85 (2014), 147–159.
Coelho, L.B., Mouanga, M., Druart, M.E., Recloux, I., Cossement, D., Olivier, M.G., A SVET study of the inhibitive effects of benzotriazole and cerium chloride solely and combined on an aluminium/copper galvanic coupling model. Corros. Sci. 110 (2016), 143–156.
Recloux, I., Andreatta, F., Druart, M.E., Coelho, L.B., Cepek, C., Cossement, D., Fedrizzi, L., Olivier, M.G., Stability of benzotriazole-based films against AA2024 aluminium alloy corrosion process in neutral chloride electrolyte. J. Alloy. Compd. 735 (2018), 2512–2522.
Garrigues, L., Pebere, N., Dabosi, F., An investigation of the corrosion inhibition of pure aluminum in neutral and acidic chloride solutions. Electrochim. Acta 41 (1996), 1209–1215.
Cicileo, G.P., Rosales, B.M., Varela, F.E., Vilche, J.R., Inhibitory action of 8-HYDROXYQUINOLINE on the copper corrosion process. Corros. Sci. 40 (1998), 1915–1926.
Aramaki, K., Kiuchi, T., Sumiyoshi, T., Nishihara, H., Surface enhanced Raman scattering and impedance studies on the inhibition of copper corrosion in sulphate solutions by 5-substituted benzotriazoles. Corros. Sci. 32 (1991), 593–607.
Milošev, I., Kapun, B., Rodič, P., Iskra, J., Hybrid sol–gel coating agents based on zirconium(IV) propoxide and epoxysilane. J. Sol. Gel Sci. Technol. 74 (2015), 447–459.
Sopchenski, L., Robert, J., Touzin, M., Tricoteaux, A., Olivier, M.G., Improvement of wear and corrosion protection of PEO on AA2024 via sol-gel sealing. Surf. Coat. Technol., 417, 2021, 127195.
Costenaro, H., Lanzutti, A., Paint, Y., Fedrizzi, L., Terada, M., de Melo, H.G., Olivier, M.G., Corrosion resistance of 2524 Al alloy anodized in tartaric-sulphuric acid at different voltages and protected with a TEOS-GPTMS hybrid sol-gel coating. Surf. Coat. Technol. 324 (2017), 438–450.
Molaeipour, P., Ramezanzadeh, M., Ramezanzadeh, B., Stachys byzantina extract: A green biocompatible molecules source for graphene skeletons generation on the carbon steel for superior corrosion mitigation. Bioelectrochemistry, 143, 2022, 107970.
Akbarzadeh, S., Ramezanzadeh, M., Ramezanzadeh, B., Bahlakeh, G., Detailed atomic/molecular-level/electronic-scale computer modeling and electrochemical explorations of the adsorption and anti-corrosion effectiveness of the green nitrogen-based phytochemicals on the mild steel surface in the saline solution. J. Mol. Liq., 319, 2020, 114312.
Alexander, C.L., Tribollet, B., Orazem, M.E., Contribution of surface distributions to constant-phase-element (CPE) behavior: 1. influence of roughness. Electrochim. Acta 173 (2015), 416–424.
Serdechnova, M., Mohedano, M., Kuznetsov, B., Mendis, C.L., Starykevich, M., Karpushenkov, S., Tedim, J., Ferreira, M.G.S., Blawert, C., Zheludkevich, M.L., PEO coatings with active protection based on in-situ formed LDH-nanocontainers. J. Electrochem. Soc. 164 (2017), C36–C45.
Hussein, R.O., Nie, X., Northwood, D.O., Yerokhin, A., Matthews, A., Spectroscopic study of electrolytic plasma and discharging behaviour during the plasma electrolytic oxidation (PEO) process. J. Phys. D Appl. Phys., 43, 2010, 105203.
Khan, R.H.U., Yerokhin, A., Li, X., Dong, H., Matthews, A., Surface characterisation of DC plasma electrolytic oxidation treated 6082 aluminium alloy: Effect of current density and electrolyte concentration. Surf. Coat. Technol. 205 (2010), 1679–1688.
Xue, W., Deng, Z., Lai, Y., Chen, R., Analysis of phase distribution for ceramic coatings formed by microarc oxidation on aluminum alloy. J. Am. Ceram. Soc. 81 (1998), 1365–1368.
Rosero-Navarro, N.C., Pellice, S.A., Castro, Y., Aparicio, M., Durán, A., Improved corrosion resistance of AA2024 alloys through hybrid organic–inorganic sol–gel coatings produced from sols with controlled polymerisation. Surf. Coat. Technol. 203 (2009), 1897–1903.
Studer, K., Decker, C., Beck, E., Schwalm, R., Overcoming oxygen inhibition in UV-curing of acrylate coatings by carbon dioxide inerting: Part II. Prog. Org. Coat. 48 (2003), 101–111.
Ramezanzadeh, B., Haeri, Z., Ramezanzadeh, M., A facile route of making silica nanoparticles-covered graphene oxide nanohybrids (SiO2-GO); fabrication of SiO2-GO/epoxy composite coating with superior barrier and corrosion protection performance. Chem. Eng. J. 303 (2016), 511–528.
Tagliazucca, V., Callone, E., Dirè, S., Influence of synthesis conditions on the cross-link architecture of silsesquioxanes prepared by in situ water production route. J. Sol. Gel Sci. Technol. 60 (2011), 236–245.
Hruby, S.L., Shanks, B.H., Acid–base cooperativity in condensation reactions with functionalized mesoporous silica catalysts. J. Catal. 263 (2009), 181–188.
Paquet, O., Salon, M.C.B., Zeno, E., Belgacem, M.N., Hydrolysis-condensation kinetics of 3-(2-amino-ethylamino)propyl-trimethoxysilane. Mater. Sci. Eng. C. 32 (2012), 487–493.
Fox, P.G., Lewis, G., Boden, P.J., Some chemical aspects of the corrosion inhibition of copper by benztriazole. Corros. Sci. 19 (1979), 457–467.
Roberts, R.F., X-ray photoelectron spectroscopic characterization of copper oxide surfaces treated with benzotriazole. J. Electron Spectrosc. Relat. Phenom. 4 (1974), 273–291.
Gerengi, H., Solomon, M.M., Kurtay, M., Bereket, G., Goksen, K., Yıldız, M., Kaya, E., Electrochemical and morphological assessments of inhibition level of 8-hydroxylquinoline for AA2024-T4 alloy in 3.5% NaCl solution. J. Adhes. Sci. Technol. 32 (2018), 207–223.
Tang, L., Li, X., Si, Y., Mu, G., Liu, G., The synergistic inhibition between 8-hydroxyquinoline and chloride ion for the corrosion of cold rolled steel in 0.5 M sulfuric acid. Mater. Chem. Phys. 95 (2006), 29–38.
Marcelin, S., Pébère, N., Synergistic effect between 8-hydroxyquinoline and benzotriazole for the corrosion protection of 2024 aluminium alloy: A local electrochemical impedance approach. Corros. Sci. 101 (2015), 66–74.
Akbarzadeh, S., Paint, Y., Olivier, M.-G., A comparative study of different sol-gel coatings for sealing the plasma electrolytic oxidation (PEO) layer on AA2024 alloy. Electrochim. Acta, 443, 2023, 141930.
Rosace, G., Guido, E., Colleoni, C., Barigozzi, G., Influence of textile structure and silica based finishing on thermal insulation properties of cotton fabrics. Int. J. Polym. Sci., 2016, 2016.
Reyes-Peces, M.V., Pérez-Moreno, A., De-Los-santos, D.M., Mesa-Díaz, M.D.M., Pinaglia-Tobaruela, G., Vilches-Pérez, J.I., Fernández-Montesinos, R., Salido, M., de la Rosa-Fox, N., Piñero, M., Chitosan-GPTMS-silica hybrid mesoporous aerogels for bone tissue engineering. Polymers, 12, 2020, 2723.
Ivanou, D.K., Yasakau, K.A., Kallip, S., Lisenkov, A.D., Starykevich, M., Lamaka, S.V., Ferreira, M.G.S., Zheludkevich, M.L., Active corrosion protection coating for a ZE41 magnesium alloy created by combining PEO and sol–gel techniques. RSC Adv. 6 (2016), 12553–12560.
Liu, W., Pu, Y., Liao, H., Lin, Y., He, W., Corrosion and wear behavior of PEO coatings on D16T aluminum alloy with different concentrations of graphene. Coatings, 10, 2020, 249.
Zhu, M., Song, Y., Dong, K., Shan, D., Han, E.H., Correlation between the transient variation in positive/negative pulse voltages and the growth of PEO coating on 7075 aluminum alloy. Electrochim. Acta, 411, 2022, 140056.
Amand, S., Musiani, M., Orazem, M.E., Pébère, N., Tribollet, B., Vivier, V., Constant-phase-element behavior caused by inhomogeneous water uptake in anti-corrosion coatings. Electrochim. Acta 87 (2013), 693–700.
Hernández, H.H., Reynoso, A.M.R., González, J.C.T., Morán, C.O.G., Hernández, J.G.M., Ruiz, A.M., Hernández, J.M., Cruz, R.O., Electrochemical impedance spectroscopy (EIS): a review study of basic aspects of the corrosion mechanism applied to steels. Electrochem. Impedance Spectrosc., 2020.
Akbarzadeh, S., Ramezanzadeh, M., Ramezanzadeh, B., Bahlakeh, G., A green assisted route for the fabrication of a high-efficiency self-healing anti-corrosion coating through graphene oxide nanoplatform reduction by Tamarindus indiaca extract. J. Hazard. Mater., 390, 2020, 122147.
Akbarzadeh, S., Ramezanzadeh, M., Ramezanzadeh, B., Inspection the corrosion prevention performance and dry/wet interfacial adhesion qualities of the melamine-cured polyester coating applied on the treated mild steel surface with a nanostructured composite cerium-neodymium film. Colloids Surf. A Physicochem. Eng. Asp., 590, 2020, 124472.
Pezzato, L., Rigon, M., Martucci, A., Brunelli, K., Dabalà, M., Plasma Electrolytic Oxidation (PEO) as pre-treatment for sol-gel coating on aluminum and magnesium alloys. Surf. Coat. Technol. 366 (2019), 114–123.
Arunoday, M., Premkumar, K.P., Kumar, R., Subasri, R., Multifunctional, environmental coatings on AA2024 by combining anodization with sol-gel process. Ceram. Int. 48 (2022), 10969–10978.
Chen, Y., Lu, X., Lamaka, S.V., Ju, P., Blawert, C., Zhang, T., Wang, F., Zheludkevich, M.L., Active protection of Mg alloy by composite PEO coating loaded with corrosion inhibitors. Appl. Surf. Sci., 504, 2020, 144462.
Pezzato, L., Coelho, L.B., Bertolini, R., Settimi, A.G., Brunelli, K., Olivier, M., Dabalà, M., Corrosion and mechanical properties of plasma electrolytic oxidation-coated AZ80 magnesium alloy. Mater. Corros. 70 (2019), 2103–2112.
Dimitrov, N., Mann, J.A., Vukmirovic, M., Sieradzki, K., Dealloying of Al2CuMg in alkaline media. J. Electrochem. Soc., 147, 2000, 3283.
Zheludkevich, M.L., Yasakau, K.A., Poznyak, S.K., Ferreira, M.G.S., Triazole and thiazole derivatives as corrosion inhibitors for AA2024 aluminium alloy. Corros. Sci. 47 (2005), 3368–3383.
Casenave, C., Pebere, N., Dabosi, F., An electrochemical impedance study of the corrosion inhibition of a 2024 aluminum alloy in neutral chloride solutions. Mater. Sci. Forum 192–194 (1995), 599–610.
Fix, D., Andreeva, D.V., Lvov, Y.M., Shchukin, D.G., Möhwald, H., Application of inhibitor-loaded halloysite nanotubes in active anti-corrosive coatings. Adv. Funct. Mater. 19 (2009), 1720–1727.
