Chemical dynamics; Complex chemical phenomena; Deterministic patterns; Deterministics; Interferometric methods; Nonequilibrium system; Oscillatory behaviors; Oscillatory reaction; Stochastics; Transition dynamics; Electronic, Optical and Magnetic Materials; Energy (all); Physical and Theoretical Chemistry; Surfaces, Coatings and Films; General Energy
Abstract :
[en] This paper presents a holographic study of the phase transition that occurs in a nonequilibrium system. The chosen model is a unique Briggs-Rauscher oscillatory reaction that, first, follows a deterministic pattern (namely, an oscillatory behavior) and, later, exhibits a phase transition occurring randomly and without any known link with the previous deterministic state. The presented research opens up a new way to reveal complex chemical phenomena and dynamics in situ, without disturbing significantly the nonequilibrium system and its pathways. Simultaneously, it unfolds a new route for applications of interferometric methods in different areas of materials science. Under the applied conditions, we show that the holographic method is more sensitive to the phase transition dynamics than the commonly used potentiometric method.
Disciplines :
Physics
Author, co-author :
Pagnacco, Maja C. ; Center for Catalysis and Chemical Engineering, Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Belgrade, Serbia
Simović-Pavlović, Marina; Center for Photonics, Institute of Physics, University of Belgrade, Belgrade, Serbia ; Faculty of Mechanical Engineering, University of Belgrade, Belgrade, Serbia
Grujić, Dušan Ž.; Center for Photonics, Institute of Physics, University of Belgrade, Belgrade, Serbia
Vasiljević, Darko M.; Center for Photonics, Institute of Physics, University of Belgrade, Belgrade, Serbia
Bokic, Bojana; Center for Photonics, Institute of Physics, University of Belgrade, Belgrade, Serbia
Mouchet, Sébastien R. ; Department of Physics & Namur Institute of Structured Matter (NISM), University of Namur, Namur, Belgium ; School of Physics, University of Exeter, Exeter, United Kingdom
Verbiest, Thierry; Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Heverlee, Belgium
Caudano, Yves; Department of Physics & Namur Institute of Structured Matter (NISM), University of Namur, Namur, Belgium ; Namur Institute for Complex Systems (naXys), University of Namur, Namur, Belgium
Kolaric, Branko ; Université de Mons - UMONS > Faculté des Science > Service des Matériaux Micro et Nanophotoniques ; Center for Photonics, Institute of Physics, University of Belgrade, Belgrade, Serbia
Language :
English
Title :
Stochastic Phase Transition Dynamics in Nonequilibrium System: Holographic Study
Publication date :
08 June 2023
Journal title :
Journal of Physical Chemistry. C, Nanomaterials and interfaces
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Funders :
Herculesstichting North Atlantic Treaty Organization H2020 Marie Sklodowska-Curie Actions Office of Naval Research Global F.R.S.-FNRS - Fonds de la Recherche Scientifique Ministarstvo Prosvete, Nauke i Tehnolo?kog Razvoja Waalse Gewest
Funding text :
M.S.P., D.Ž.G., D.V., and B.K. acknowledge support of the project Biological and bioinspired structures for multispectral surveillance, funded by NATO SPS (NATO Science for Peace and Security) 2019-2022. B.K., D.V., B.B., D.Ž.G., and M.S.-P. acknowledge funding provided by the Institute of Physics Belgrade, through the institutional funding by the Ministry of Education, Science, and Technological Development of the Republic of Serbia. Y.C. is a research associate of the Fund for Scientific Research F.R.S.-FNRS. Additionally, B.K. acknowledges support from F.R.S.-FNRS. M.C.P. acknowledges support from the Ministry of Education, Science and Technological Development of the Republic of Serbia, Contract number 451-03-9/2021-14/200026. S.R.M. was supported by a BEWARE Fellowship (Convention no. 2110034) of the Walloon Region (Marie Skłodowska-Curie Actions of the European Union - COFUND - contract 847587), as a postdoctoral researcher. T.V. acknowledges financial support from the Hercules Foundation. D.V., M.S.P., D.Ž.G., M.P., B.B., and B.K. acknowledge the support of the Office of Naval Research Global through the Research Grant N62902-22-1-2024.M.S.P., D.Ž.G., D.V., and B.K. acknowledge support of the project Biological and bioinspired structures for multispectral surveillance, funded by NATO SPS (NATO Science for Peace and Security) 2019–2022. B.K., D.V., B.B., D.Ž.G., and M.S.-P. acknowledge funding provided by the Institute of Physics Belgrade, through the institutional funding by the Ministry of Education, Science, and Technological Development of the Republic of Serbia. Y.C. is a research associate of the Fund for Scientific Research F.R.S.-FNRS. Additionally, B.K. acknowledges support from F.R.S.-FNRS. M.C.P. acknowledges support from the Ministry of Education, Science and Technological Development of the Republic of Serbia, Contract number 451-03-9/2021-14/200026. S.R.M. was supported by a BEWARE Fellowship (Convention no. 2110034) of the Walloon Region (Marie Skłodowska-Curie Actions of the European Union - COFUND - contract 847587), as a postdoctoral researcher. T.V. acknowledges financial support from the Hercules Foundation. D.V., M.S.P., D.Ž.G., M.P., B.B., and B.K. acknowledge the support of the Office of Naval Research Global through the Research Grant N62902-22-1-2024.
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