corrosion; inhibitor; magnesium; plasma electrolytic oxidation; sol–gel; Surfaces and Interfaces; Surfaces, Coatings and Films; Materials Chemistry
Abstract :
[en] In this investigation, the sol–gel method is employed along with a corrosion inhibitor to seal a plasma electrolytic oxidation (PEO) coating, aiming to improve the long-term corrosion resistance of the AZ31 Mg alloy. Following an initial screening of corrosion inhibitors, 8-hydroxyquinoline (8HQ) is incorporated into the hybrid PEO/sol–gel system using two methods: (i) post-treatment of the PEO layer through immersion in an inhibitor-containing solution; (ii) loading the inhibitor into the sol–gel precursor. The characterization includes scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible spectroscopy (UV-vis), and water drop contact angle measurements. The rheological properties of the inhibitor-loaded sol–gel precursors are assessed by measuring flow curves. The corrosion processes are evaluated in a saline solution through electrochemical impedance spectroscopy (EIS) and immersion tests with unscratched and scratched specimens, respectively. The results demonstrate the successful incorporation of the inhibitor for both loading strategies. Regardless of the loading approach, systems containing 8HQ exhibit the most favourable long-term corrosion resistance.
Research center :
CRIM - Ingénierie des matériaux
Disciplines :
Materials science & engineering
Author, co-author :
Pillado, Borja; Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense, Madrid, Spain ; Institut Laue-Langevin, Grenoble, France
Matykina, Endzhe ; Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense, Madrid, Spain
Olivier, Marie-Georges ; Université de Mons - UMONS > Faculté Polytechnique > Service de Science des Matériaux
Mohedano, Marta ; Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense, Madrid, Spain
Arrabal, Raúl ; Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense, Madrid, Spain
Language :
English
Title :
Functionalization of Plasma Electrolytic Oxidation/Sol–Gel Coatings on AZ31 with Organic Corrosion Inhibitors
Publication date :
2024
Journal title :
Coatings
eISSN :
2079-6412
Publisher :
Multidisciplinary Digital Publishing Institute (MDPI)
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Funders :
MCIN/AEI/FEDER, EU Materials Institute of UMONS
Funding number :
PID2021-124341OB-C22
Funding text :
The authors gratefully acknowledge the support of PID2021-124341OB-C22 project (MCIN/AEI/FEDER, EU) and the Materials Institute of UMONS. M. Mohedano is grateful for the support of RYC-2017 21843.
Oak Ridge National Laboratory Transportation Energy Data Book 40th ed. Oak Ridge National Laboratory Oak Ridge, TN, USA 2022
Demirci E.E. Arslan E. Ezirmik K.V. Baran Ö. Totik Y. Efeoglu İ. Investigation of wear, corrosion and tribocorrosion properties of AZ91 Mg alloy coated by micro arc oxidation process in the different electrolyte solutions Thin Solid Film. 2013 528 116 122 10.1016/j.tsf.2012.07.145
Shang W. Chen B. Shi X. Chen Y. Xiao X. Electrochemical corrosion behavior of composite MAO/sol–gel coatings on magnesium alloy AZ91D using combined micro-arc oxidation and sol–gel technique J. Alloys Compd. 2009 474 541 545 10.1016/j.jallcom.2008.06.135
Guo X. Du K. Guo Q. Wang Y. Wang F. Experimental study of corrosion protection of a three-layer film on AZ31B Mg alloy Corros. Sci. 2012 65 367 375 10.1016/j.corsci.2012.08.055
Chen Q. Zheng Y. Dong S. Chen X.-B. Dong J. Effects of fluoride ions as electrolyte additives for a PEO/Ni-P composite coating onto Mg alloy AZ31B Surf. Coat. Technol. 2021 417 126883 10.1016/j.surfcoat.2021.126883
Wierzbicka E. Vaghefinazari B. Lamaka S.V. Zheludkevich M.L. Mohedano M. Moreno L. Visser P. Rodriguez A. Velasco J. Arrabal R. et al. Flash-PEO as an alternative to chromate conversion coatings for corrosion protection of Mg alloy Corros. Sci. 2021 180 109189 10.1016/j.corsci.2020.109189
Oleshko O. Kornienko V. Kyrylenko S. Simka W. Husak Y. Oleshko T. Dryhval B. Physical and Chemical Characterization of the Magnesium Surface Modified by Plasma Electrolytic Oxidation—Influence of Immersion in Simulated Body Fluid Proceedings of the 2020 IEEE 10th International Conference Nanomaterials: Applications Properties (NAP) Sumy, Ukraine 9–13 November 2022 02BA11-01 10.1109/NAP51477.2020.9309586
Ghanbari A. Bordbar-Khiabani A. Warchomicka F. Sommitsch C. Yarmand B. Zamanian A. PEO/Polymer hybrid coatings on magnesium alloy to improve biodegradation and biocompatibility properties Surf. Interfaces 2023 36 102495 10.1016/j.surfin.2022.102495
Xu L. Fu X. Su H. Sun H. Li R. Wan Y. Corrosion and tribocorrosion protection of AZ31B Mg alloy by a hydrothermally treated PEO/chitosan composite coating Prog. Org. Coat. 2022 170 107002 10.1016/j.porgcoat.2022.107002
Sampatirao H. Amruthaluru S. Chennampalli P. Lingamaneni R.K. Nagumothu R. Fabrication of ceramic coatings on the biodegradable ZM21 magnesium alloy by PEO coupled EPD followed by laser texturing process J. Magnes. Alloys 2021 9 910 926 10.1016/j.jma.2020.10.002
Li Y. Lu F. Li H. Zhu W. Pan H. Tan G. Lao Y. Ning C. Ni G. Corrosion mechanism of micro-arc oxidation treated biocompatible AZ31 magnesium alloy in simulated body fluid Prog. Nat. Sci. Mater. Int. 2014 24 516 522 10.1016/j.pnsc.2014.08.007
Pezzato L. Rigon M. Martucci A. Brunelli K. Dabalà M. Plasma Electrolytic Oxidation (PEO) as pre-treatment for sol–gel coating on aluminum and magnesium alloys Surf. Coat. Technol. 2019 366 114 123 10.1016/j.surfcoat.2019.03.023
Pezzato L. Babbolin R. Cerchier P. Marigo M. Dolcet P. Dabalà M. Brunelli K. Sealing of PEO coated AZ91magnesium alloy using solutions containing neodymium Corros. Sci. 2020 173 108741 10.1016/j.corsci.2020.108741
Gnedenkov A. Sinebryukhov S. Nomerovskii A. Filonina V. Ustinov A. Gnedenkov S. Design of self-healing PEO-based protective layers containing in-situ grown LDH loaded with inhibitor on the MA8 magnesium alloy J. Magnes. Alloys 2023 11 3688 3709 10.1016/j.jma.2023.07.016
Telmenbayar L. Gopal Ramu A. Erdenebat T.-O. Choi D. Anticorrosive lanthanum embedded PEO/GPTMS coating on magnesium alloy by plasma electrolytic oxidation with silanization Mater. Today Commun. 2022 33 104662 10.1016/j.mtcomm.2022.104662
Fernández-Hernán J.P. López A.J. Torres B. Martínez-Campos E. Matykina E. Rams J. Anticorrosion and cytocompatibility assessment of graphene-doped hybrid silica and plasma electrolytic oxidation coatings for biomedical applications ACS Biomater. Sci. Eng. 2021 7 5861 5877 10.1021/acsbiomaterials.1c00326
Chen Y. Lu X. Lamaka S.V. Ju P. Blawert C. Zhang T. Wang F. Zheludkevich M.L. Active protection of Mg alloy by composite PEO coating loaded with corrosion inhibitors Appl. Surf. Sci. 2020 504 144462 10.1016/j.apsusc.2019.144462
Ivanou D. Yasakau K. Kallip S. Lisenkov A.D. Starykevich M. Lamaka S.V. Ferreira M. Zheludkevich M.L. Active corrosion protection coating for ZE41 magnesium alloy created by combining PEO and sol–gel techniques RSC Adv. 2016 6 12553 12560 10.1039/C5RA22639B
Li T. Li L. Qi J. Chen F. Corrosion protection of Ti6Al4V by a composite coating with a plasma electrolytic oxidation layer and sol–gel layer filled with graphene oxide Prog. Org. Coat. 2020 144 105632 10.1016/j.porgcoat.2020.105632
Joo J. Kim D. Moon H.-S. Kim K. Lee J. Durable Anti-Corrosive Oil-Impregnated Porous Surface of Magnesium Alloy by Plasma Electrolytic Oxidation with Hydrothermal Treatment Appl. Surf. Sci. 2020 509 145361 10.1016/j.apsusc.2020.145361
Qian Z. Wang S. Wu Z. Corrosion Behavior Study of AZ31B magnesium Alloy by Sol–gel Silica-based Hybrid Coating. Int. J. Electrochem. Sci. 2017 12 8269 8279 10.20964/2017.09.46
Toorani M. Aliofkhazraei M. Review of electrochemical properties of hybrid coating systems on Mg with plasma electrolytic oxidation process as pretreatment Surf. Interfaces 2019 14 262 295 10.1016/j.surfin.2019.01.004
Zheng S. Li J. Inorganic-organic sol gel hybrid coatings for corrosion protection of metals J. Sol–Gel Sci. Technol. 2010 54 174 187 10.1007/s10971-010-2173-1
Malayoglu U. Tekin K. Shrestha S. Influence of post-treatment on the corrosion resistance of PEO coated AM50B and AM60B Mg alloys Surf. Coat. Technol. 2010 205 1793 1798 10.1016/j.surfcoat.2010.08.022
Figueira R. Silva C. Pereira E. Organic-inorganic hybrid sol–gel coatings for metal corrosion protection: A review of recent progress J. Coat. Technol. Res. 2014 12 1 35 10.1007/s11998-014-9595-6
Wen J. Wilkes G. Organic/Inorganic Hybrid Network Materials by the Sol–gel Approach Chem. Mater. 1996 8 1667 1681 10.1021/cm9601143
Akbarzadeh S. Santos L. Vitry V. Paint Y. Olivier M.G. Improvement of the corrosion performance of AA2024 alloy by a duplex PEO/clay modified sol–gel nanocomposite coating Surf. Coat. Technol. 2022 434 128168 10.1016/j.surfcoat.2022.128168
Balgude D. Sabnis A. Sol–gel derived hybrid coatings as an environment friendly surface treatment for corrosion protection of metals and their alloys J. Sol–Gel Sci. Technol. 2012 64 124 134 10.1007/s10971-012-2838-z
Galio A. Lamaka S.V. Zheludkevich M.L. Dick L. Muller I. Ferreira M. Inhibitor-doped sol–gel coatings for corrosion protection of magnesium alloy AZ31 Surf. Coat. Technol. 2010 204 1479 1486 10.1016/j.surfcoat.2009.09.067
Kartsonakis I. Balaskas A. Koumoulos E.P. Charitidis C.A. Kordas G. Evaluation of corrosion resistance of magnesium alloy ZK10 coated with hybrid organic–inorganic film including containers Corros. Sci. 2012 65 325 333 10.1016/j.corsci.2012.08.052
Lim T. Ryu H. Hong S.-H. Electrochemical corrosion properties of CeO2-containing coatings on AZ31 magnesium alloys prepared by plasma electrolytic oxidation Corros. Sci. 2012 62 104 111 10.1016/j.corsci.2012.04.043
Barranco V. Carmona N. Galvan J.C. Grobelny M. Kwiatkowski L. Velasco M.A. Electrochemical study of tailored sol–gel thin films as pre-treatment prior to organic coating for AZ91 magnesium alloy Prog. Org. Coat. 2010 68 347 354 10.1016/j.porgcoat.2010.02.009
Zanotto F. Grassi V. Frignani A. Zucchi F. Protection of the AZ31 magnesium alloy with cerium modified silane coatings Mater. Chem. Phys. 2011 129 1 8 10.1016/j.matchemphys.2011.05.013
Montemor M.F. Ferreira M.G.S. Electrochemical study of modified bis-[triethoxysilylpropyl] tetrasulfide silane films applied on the AZ31 Mg alloy Electrochim. Acta 2007 52 7486 7495 10.1016/j.electacta.2006.12.086
Fajardo S. Frankel G.S. Gravimetric method for hydrogen evolution measurements on dissolving magnesium J. Electrochem. Soc. 2015 162 C693 C701 10.1149/2.0241514jes
Shangyi S. Zuo Y. Zhao X. The effects of 8-hydroxyquinoline on corrosion performance of a Mg-rich coating on AZ91D magnesium alloy Corros. Sci. 2013 76 275 283 10.1016/j.corsci.2013.06.050
Cicileo G.P. Rosales B.M. Varela F.E. Vilche J.R. Inhibitory action of 8-Hydroxyquinoline on the copper corrosion process Corros. Sci. 1998 40 1915 1926 10.1016/S0010-938X(98)00090-0
Tang L. Li X. Si Y. Mu G. Liu G. The synergistic inhibition between 8-hydroxyquinoline and chloride ion for the corrosion of cold rolled steel in 0.5M sulfuric acid Mater. Chem. Phys. 2006 95 29 38 10.1016/j.matchemphys.2005.03.064
Lamaka S.V. Zheludkevich M.L. Yasakau K.A. Montemor M.F. Ferreira M.G.S. High effective organic corrosion inhibitors for 2024 aluminium alloy Electrochim. Acta 2007 52 7231 7247 10.1016/j.electacta.2007.05.058
Yasakau K.A. Zheludkevich M.L. Karavai O.V. Ferreira M.G.S. Influence of inhibitor addition on the corrosion protection performance of sol–gel coatings on AA2024 Prog. Org. Coat. 2008 63 352 361 10.1016/j.porgcoat.2007.12.002
Stankiewicz A. Self-healing nanocoatings for protection against steel corrosion Nanotechnology in Eco-Efficient Construction Pacheco-Torgal F. Diamanti M.V. Nazari A. Granqvist C.G. Pruna A. Amirkhanian S. Woodhead Publishing Cambridge, UK 2019 303 335 10.1016/B978-0-08-102641-0.00014-1
Snihirova D. Lamaka S.V. Taheri P. Mol J.M.C. Montemor M.F. Comparison of the synergistic effects of inhibitor mixtures tailored for enhanced corrosion protection of bare and coated AA2024-T3 Surf. Coat. Technol. 2016 303 342 351 10.1016/j.surfcoat.2015.10.075
Tian Z. Shi H. Liu F. Xu S. Han E.-H. Inhibiting effect of 8-hydroxyquinoline on the corrosion of silane-based sol–gel coatings on AA 2024-T3 Prog. Org. Coat. 2015 82 81 90 10.1016/j.porgcoat.2015.01.018
Arunoday M. Premkumar K.P. Kumar R. Subasri R. Multifunctional, environmental coatings on AA2024 by combining anodization with sol–gel process Ceram. Int. 2022 48 10969 10978 10.1016/j.ceramint.2021.12.316
Vaghefinazari B. Lamaka S.V. Blawert C. Serdechnova M. Scharnagl N. Karlova P. Wieland D.C. Zheludkevich M. Exploring the corrosion inhibition mechanism of 8-hydroxyquinoline for a PEO-coated magnesium alloy Corros. Sci. 2022 203 110344 10.1016/j.corsci.2022.110344
Arrabal R. Matykina E. Hashimoto T. Skeldon P. Thompson G.E. Characterization of AC PEO coatings on magnesium alloys Surf. Coat. Technol. 2009 203 2207 2220 10.1016/j.surfcoat.2009.02.011
Arrabal R. Matykina E. Pardo A. Merino M.C. Paucar K. Mohedano M. Casajús P. Corrosion behaviour of AZ91D and AM50 magnesium alloys with Nd and Gd additions in humid environments Corros. Sci. 2012 55 351 362 10.1016/j.corsci.2011.10.038
Pardo A. Casajús P. Mohedano M. Coy A.E. Viejo F. Torres B. Matykina E. Corrosion protection of Mg/Al alloys by thermal sprayed aluminium coatings Appl. Surf. Sci. 2009 255 6968 6977 10.1016/j.apsusc.2009.03.022
Lamaka S.V. Shchukin D.G. Andreeva D.V. Zheludkevich M.L. Möhwald H. Ferreira M.G.S. Sol–gel/Polyelectrolyte Active Corrosion Protection System Adv. Funct. Mater. 2008 18 3137 3147 10.1002/adfm.200800630
Abbas R. Jarad A. Nafliu I. Nechifor A. Synthesis, Characterization and Antibacterial Activity from Mixed Ligand Complexes of 8-Hydroxyquinoline and Tributylphosphine for Some Metal Ions Rev. Chim. 2019 70 36 40 10.37358/RC.19.1.6846
Karuppanan A. Govindan A.B. Perumalsamy R. Growth of <201> 8-hydroxyquinoline organic crystal by Czochralski method and its characterizations J. Therm. Anal. Calorim. 2012 110 1333 1339 10.1007/s10973-011-2121-5
Kumar S. Kumar B. Growth of an 8-hydroxyquinoline single crystal by a modified Czochralski growth technique, and crystal characterization CrystEngComm 2018 20 624 630 10.1039/C7CE01857F
Noor S.A.M. Ahmad A. Talib I.A. Rahman M.Y.A. Morphology, chemical interaction, and conductivity of a PEO-ENR50 based on solid polymer electrolyte Ionics 2009 16 161 170 10.1007/s11581-009-0385-6
Hernández-Barrios C.A. Cuao C.A. Jaimes M.A. Coy A.E. Viejo F. Effect of the catalyst concentration, the immersion time and the aging time on the morphology, composition and corrosion performance of TEOS-GPTMS sol–gel coatings deposited on the AZ31 magnesium alloy Surf. Coat. Technol. 2017 325 257 269 10.1016/j.surfcoat.2017.06.047
Narayanan S. Lee M.H. A simple strategy to modify the porous structure of plasma electrolytic oxidation coatings on magnesium RSC Adv. 2016 6 16100 16114 10.1039/C5RA20647B
Xu J. Yu Q. Liu J. Yin Y. Han Y. Li B. Preparation and characterization of polyfluoroaniline/organosiloxane hybrid films J. Sol–Gel Sci. Technol. 2013 69 580 585 10.1007/s10971-013-3260-x
Molaeipour P. Ramezanzadeh Karati M. Ramezanzadeh B. Stachys byzantina extract: A green biocompatible molecules source for graphene skeletons generation on the carbon steel for superior corrosion mitigation Bioelectrochemistry 2021 143 107970 10.1016/j.bioelechem.2021.107970 34662839
Tan A. Soutar A. Annergren I.F. Liu Y.N. Multilayer Sol–Gel Coatings for Corrosion Protection of Magnesium Surf. Coat. Technology. 2005 198 478 482 10.1016/j.surfcoat.2004.10.066
Mohedano M. Blawert C. Zheludkevich M.L. Silicate-based Plasma Electrolytic Oxidation (PEO) coatings with incorporated CeO2 particles on AM50 magnesium alloy Mater. Des. 2015 86 735 744 10.1016/j.matdes.2015.07.132
Alabbasi A. Kannan M.B. Walter R. Störmer M. Blawert C. Performance of pulsed constant current silicate-based PEO coating on pure magnesium in simulated body fluid Mater. Lett. 2013 106 18 21 10.1016/j.matlet.2013.04.047
Gnedenkov S.V. Khrisanfova O.A. Zavidnaya A.G. Sinebryukhov S.L. Egorkin V.S. Nistratova M.V. Yerokhin A. Matthews A. PEO coatings obtained on an Mg–Mn type alloy under unipolar and bipolar modes in silicate-containing electrolytes Surf. Coat. Technol. 2010 204 2316 2322 10.1016/j.surfcoat.2009.12.024
Nguyen V.N. Perrin F. Vernet J.L. Water permeability of organic/inorganic hybrid coatings prepared by sol–gel method: A comparison between gravimetric and capacitance measurements and evaluation of non-Fickian sorption models Corros. Sci. 2005 47 397 412 10.1016/j.corsci.2004.06.028
Salh R. Defect Related Luminescence in Silicon Dioxide Network: A Review Crystalline Silicon—Properties and Uses InTech London, UK 2011 10.5772/22607
Zhao W. Ji W. Zhang Y. Du L. Wang S. A competitive fluorescence quenching-based immunoassay for bisphenol A employing functionalized silica nanoparticles and nanogold RSC Adv. 2016 6 38950 38956 10.1039/C5RA26366B
Hernández-Escolano M. Juan-Díaz M. Martínez-Ibáñez M. Jiménez-Morales A. Goñi I. Gurruchaga M. Suay J. The design and characterisation of sol–gel coatings for the controlled-release of active molecules J. Sol–Gel Sci. Technol. 2012 64 442 451 10.1007/s10971-012-2876-6
Spinthaki A. Kamaratou M. Matheis J. Disci D. Hater W. The precipitation of “aluminum silicate” under geothermal stresses: Identifying its idiosyncrasies Geothermics 2021 92 102060 10.1016/j.geothermics.2021.102060
Mingo B. Arrabal R. Mohedano M. Llamazares Y. Matykina E. Yerokhin A. Pardo A. Influence of sealing post-treatments on the corrosion resistance of PEO coated AZ91 magnesium alloy Appl. Surf. Sci. 2018 433 653 667 10.1016/j.apsusc.2017.10.083
Mohedano M. Blawert C. Zheludkevich M.L. Cerium-based sealing of PEO coated AM50 magnesium alloy Surf. Coat. Technol. 2015 269 145 154 10.1016/j.surfcoat.2015.01.003
El Ojaimi M. Thummel R.P. Polydentate Analogues of 8-Hydroxyquinoline and Their Complexes with Ruthenium Inorg. Chem. 2011 50 10966 10973 10.1021/ic201524j
Prachayasittikul V. Prachayasittikul S. Ruchirawat S. Prachayasittikul V. 8-Hydroxyquinolines: A review of their metal chelating properties and medicinal applications Drug Des. Dev. Ther. 2013 7 1157 1178 10.2147/DDDT.S49763
