Article (Scientific journals)
Synthesis of p-Conjugated Systems from Methyldiazines and Aromatic Aldehydes under PTC conditions and without organic solvent
Pascal, Laurent; Vanden Eynde, Jean-Jacques; Van Haverbeke, Yves et al.
2004In Letters in Organic Chemistry, 1 (2), p. 112 - 118
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Keywords :
Organic Chemistry; Biochemistry
Abstract :
[en] The condensation reactions of 4-methylpyrimidine and methylpyrazine with p-anisaldehyde have been studied in NaOH 5M in the presence of catalytic amount of a quaternary ammonium salt ('quat'). This study seems to give credit to a PTC/OH extraction process where an hydroxide ion would be transferred into the 'pseudo organic phase' consisted by liquid reagents. However, an IPTC process cannot be ruled out for some of tested quats.
Disciplines :
Chemistry
Author, co-author :
Pascal, Laurent
Vanden Eynde, Jean-Jacques 
Van Haverbeke, Yves
Dubois, Philippe  ;  Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites
Language :
English
Title :
Synthesis of p-Conjugated Systems from Methyldiazines and Aromatic Aldehydes under PTC conditions and without organic solvent
Publication date :
01 April 2004
Journal title :
Letters in Organic Chemistry
ISSN :
1570-1786
eISSN :
1875-6255
Publisher :
Bentham Science Publishers, Netherlands
Volume :
1
Issue :
2
Pages :
112 - 118
Peer reviewed :
Peer Reviewed verified by ORBi
Research unit :
S816 - Matériaux Polymères et Composites
S836 - Synthèse et spectrométrie de masse organiques
Research institute :
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
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