Metastable dimethyl phthalate molecular ions: does the loss of a methoxyl radical proceed with or without anchimeric assistance?

Gerbaux, Pascal; Flammang, Robert; De Winter, Julien; Nguyen, Vinh Son; Nguyen, Minh Tho

doi:10.1016/j.ijms.2009.12.012

Article (Scientific journals)

Metastable dimethyl phthalate molecular ions: does the loss of a methoxyl radical proceed with or without anchimeric assistance?

Gerbaux, Pascal; Flammang, Robert; De Winter, Julien et al.

2010 • In International Journal of Mass Spectrometry, 290 (2-3), p. 127-132

Peer Reviewed verified by ORBi

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https://hdl.handle.net/20.500.12907/1545

DOI
10.1016/j.ijms.2009.12.012

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Abstract :

[en] Using MS/MS/MS experiments and quantum chemical calculations, it is demonstrated that oxygen (carbonyl) methylated phthalic anhydride cations are produced when metastable dimethyl phthalate molecular ions expel a methoxyl radical. At higher internal energ

Disciplines :

Chemistry

Author, co-author :

Gerbaux, Pascal ; Université de Mons > Faculté des Sciences > Synthèse et spectrométrie de masse organiques

Flammang, Robert

De Winter, Julien ; Université de Mons > Faculté des Sciences > Synthèse et spectrométrie de masse organiques

Nguyen, Vinh Son

Nguyen, Minh Tho

Language :

English

Title :

Metastable dimethyl phthalate molecular ions: does the loss of a methoxyl radical proceed with or without anchimeric assistance?

Publication date :

01 January 2010

Journal title :

International Journal of Mass Spectrometry

ISSN :

1387-3806

Publisher :

Elsevier, Netherlands

Volume :

290

Issue :

2-3

Pages :

127-132

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites
S836 - Synthèse et spectrométrie de masse organiques

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publié en ligne le 29 décembre 2009 Lecture en ligne: http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6VND-4Y1VSN4-2-S&_cdi=6176&_user=532054&_pii=S1387380609003868&_origin=search&_coverDate=02%2F15%2F2010&_sk=997099997&view=c&wchp=dGLzVlb-zSkzS&md5=5296f4cbdc0ab04aee68e2cc06b0fbc1

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