Elaboration and characterization of a multifunctional silane/ZnO hybrid nanocomposite coating

[en] The present study aims at investigating the elaboration of a ZnO/sol-gel nanocomposite coating, whichcan provide a number of properties such as UV-absorption, mechanical and barrier effects, etc. depend-ing on targeted applications. The sol-gel coating formulation is an inorganic-organic hybrid based ontetraethoxysilane (TEOS) and glycidyloxypropyltrimethoxysilane (GPTMS). In order to ensure good dis-persion in the sol-gel matrix, ZnO nanoparticles were surface-modified with a silane coupling agent.The functionalization was confirmed by Fourier transform infrared (FTIR) and thermogravimetric (TGA)analyses. Field emission gun-scanning electron microscopy (FEG-SEM) characterization of the nanocom-posite film reveals a homogeneous distribution and dispersion of the ZnO nanoparticles throughout thefilm. Glow discharge optical emission spectrometry (GDOES) analysis allows evaluating the thicknessof coatings and getting a depth composition profile. Some properties such as UV-absorption and bar-rier effect are highlighted using a UV-visible spectrometer and electrochemical impedance spectroscopy(EIS), respectively. The effect of ZnO concentration is also presented.

Research center :

CIRMAP - Centre d'Innovation et de Recherche en Matériaux Polymères
CRIM - Ingénierie des matériaux

Disciplines :

Materials science & engineering

Author, co-author :

Nicolay, Arnaud ; Université de Mons > Faculté Polytechnique > Science des Matériaux

Lanzutti, Alex

Poelman, Mireille ; Université de Mons > Unités externes > Materia Nova ASBL

Ruelle, Benoît ; Université de Mons > Unités externes > Materia Nova ASBL

Fedrizzi, Lorenzo

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Olivier, Marie-Georges ; Université de Mons > Faculté Polytechnique > Service de Science des Matériaux

Language :

English

Title :

Elaboration and characterization of a multifunctional silane/ZnO hybrid nanocomposite coating

Publication date :

01 February 2015

Journal title :

Applied Surface Science

ISSN :

0169-4332

eISSN :

1873-5584

Publisher :

Elsevier, Netherlands

Volume :

327

Pages :

379-388

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites
F502 - Science des Matériaux

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Available on ORBi UMONS :

since 12 January 2015

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