Influence of the Macromolecular Architecture on the Self-assembly of Amphiphilic Copolymers Based on Poly(N,N-dimethylamino-2-ethyl methacrylate) and Poly(epsilon-caprolactone)

Bougard, F.; Giacomelli, C.; Mespouille, Laetitia; Borsali, R.; Dubois, Philippe; Lazzaroni, Roberto

doi:10.1021/la800765y

Article (Scientific journals)

Influence of the Macromolecular Architecture on the Self-assembly of Amphiphilic Copolymers Based on Poly(N,N-dimethylamino-2-ethyl methacrylate) and Poly(epsilon-caprolactone)

Bougard, F.; Giacomelli, C.; Mespouille, Laetitia et al.

2008 • In Langmuir, 24 (15), p. 8272-8279

Peer Reviewed verified by ORBi

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https://hdl.handle.net/20.500.12907/18928

DOI
10.1021/la800765y

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Abstract :

[en] The self-assembly of amphiphilic copolymers consisting of poly( N, N-dimethylamino-2-ethyl methacrylate) (PDMAEMA) and poly(-caprolactone) (PCL) segments arranged in graft and linear diblock architectures was investigated in this work by means of dynamic light scattering (DLS) in aqueous solution and by atomic force microscopy (AFM) on thin deposits. The solid-state deposits of the micelles were generated by a 'freeze-drying' technique that preserves the initial micelle morphology in solution. A comparison between the morphological properties of graft copolymers with corresponding diblock copolymers was established to demonstrate the effect of the copolymer architecture on the micelle structure and organization.

Disciplines :

Chemistry
Physics

Author, co-author :

Bougard, F.

Giacomelli, C.

Mespouille, Laetitia ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Borsali, R.

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Lazzaroni, Roberto ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux

Language :

English

Title :

Influence of the Macromolecular Architecture on the Self-assembly of Amphiphilic Copolymers Based on Poly(N,N-dimethylamino-2-ethyl methacrylate) and Poly(epsilon-caprolactone)

Publication date :

05 August 2008

Journal title :

Langmuir

ISSN :

0743-7463

eISSN :

1520-5827

Publisher :

American Chemical Society, United States - District of Columbia

Volume :

Issue :

Pages :

8272-8279

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites
S817 - Chimie des matériaux nouveaux

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publié en ligne le 2 juillet 2008

Available on ORBi UMONS :

since 10 June 2010

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