Li, Y.; Sonar, P.; Murphy, L.; Hong, W. High Mobility Diketopyrrolopyrrole (DPP)-Based Organic Semiconductor Materials for Organic Thin Film Transistors and Photovoltaics. Energy Environ. Sci. 2013, 6 (6), 1684, 10.1039/c3ee00015j
Xie, W.; Frisbie, C. D. Electrolyte Gated Single-Crystal Organic Transistors to Examine Transport in the High Carrier Density Regime. MRS Bull. 2013, 38 (01), 43-50, 10.1557/mrs.2012.310
Sirringhaus, H. 25th Anniversary Article: Organic Field-Effect Transistors: The Path Beyond Amorphous Silicon. Adv. Mater. 2014, 26 (9), 1319-1335, 10.1002/adma.201304346
Wang, C.; Dong, H.; Hu, W.; Liu, Y.; Zhu, D. Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics. Chem. Rev. 2012, 112 (4), 2208-2267, 10.1021/cr100380z
Mas-Torrent, M.; Rovira, C. Role of Molecular Order and Solid-State Structure in Organic Field-Effect Transistors. Chem. Rev. 2011, 111 (8), 4833-4856, 10.1021/cr100142w
Giri, G.; Verploegen, E.; Mannsfeld, S. C. B.; Atahan-Evrenk, S.; Kim, D. H.; Lee, S. Y.; Becerril, H. A.; Aspuru-Guzik, A.; Toney, M. F.; Bao, Z. Tuning Charge Transport in Solution-Sheared Organic Semiconductors Using Lattice Strain. Nature 2011, 480 (7378), 504-508, 10.1038/nature10683
Takeyama, Y.; Ono, S.; Matsumoto, Y. Organic Single Crystal Transistor Characteristics of Single-Crystal Phase Pentacene Grown by Ionic Liquid-Assisted Vacuum Deposition. Appl. Phys. Lett. 2012, 101 (8), 083303, 10.1063/1.4747148
Yuan, Y.; Giri, G.; Ayzner, A. L.; Zoombelt, A. P.; Mannsfeld, S. C. B.; Chen, J.; Nordlund, D.; Toney, M. F.; Huang, J.; Bao, Z. Ultra-High Mobility Transparent Organic Thin Film Transistors Grown by an off-Centre Spin-Coating Method. Nat. Commun. 2014, 5 (1), 3005, 10.1038/ncomms4005
Schweicher, G.; Lemaur, V.; Niebel, C.; Ruzié, C.; Diao, Y.; Goto, O.; Lee, W.-Y.; Kim, Y.; Arlin, J.-B.; Karpinska, J. Bulky End-Capped [1]Benzothieno[3,2-b]Benzothiophenes: Reaching High-Mobility Organic Semiconductors by Fine Tuning of the Crystalline Solid-State Order. Adv. Mater. 2015, 27 (19), 3066, 10.1002/adma.201500322
Schweicher, G.; Olivier, Y.; Lemaur, V.; Geerts, Y. H. What Currently Limits Charge Carrier Mobility in Crystals of Molecular Semiconductors?. Isr. J. Chem. 2014, 54 (5-6), 595, 10.1002/ijch.201400047
Podzorov, V.; Menard, E.; Rogers, J. A.; Gershenson, M. E. Hall Effect in the Accumulation Layers on the Surface of Organic Semiconductors. Phys. Rev. Lett. 2005, 95 (22), 226601, 10.1103/PhysRevLett.95.226601
Yi, H. T.; Gartstein, Y. N.; Podzorov, V. Charge Carrier Coherence and Hall Effect in Organic Semiconductors. Sci. Rep. 2016, 6 (1), 23650, 10.1038/srep23650
Mitsui, C.; Okamoto, T.; Yamagishi, M.; Tsurumi, J.; Yoshimoto, K.; Nakahara, K.; Soeda, J.; Hirose, Y.; Sato, H.; Yamano, A. et al. High-Performance Solution-Processable N-Shaped Organic Semiconducting Materials with Stabilized Crystal Phase. Adv. Mater. 2014, 26 (26), 4546-4551, 10.1002/adma.201400289
D'Avino, G.; Olivier, Y.; Muccioli, L.; Beljonne, D. Do Charges Delocalize over Multiple Molecules in Fullerene Derivatives?. J. Mater. Chem. C 2016, 4 (17), 3747-3756, 10.1039/C5TC03283K
McCulloch, I.; Heeney, M.; Bailey, C.; Genevicius, K.; MacDonald, I.; Shkunov, M.; Sparrowe, D.; Tierney, S.; Wagner, R.; Zhang, W. et al. Liquid-Crystalline Semiconducting Polymers with High Charge-Carrier Mobility. Nat. Mater. 2006, 5 (4), 328-333, 10.1038/nmat1612
Kim, B. J.; Lee, H.-S.; Lee, J. S.; Cho, S.; Kim, H.; Son, H. J.; Kim, H.; Ko, M. J.; Park, S.; Kang, M. S. et al. Correlation between Crystallinity, Charge Transport, and Electrical Stability in an Ambipolar Polymer Field-Effect Transistor Based on Poly(Naphthalene-Alt-Diketopyrrolopyrrole). J. Phys. Chem. C 2013, 117 (22), 11479-11486, 10.1021/jp400664r
Steyrleuthner, R.; Di Pietro, R.; Collins, B. A.; Polzer, F.; Himmelberger, S.; Schubert, M.; Chen, Z.; Zhang, S.; Salleo, A.; Ade, H. et al. The Role of Regioregularity, Crystallinity, and Chain Orientation on Electron Transport in a High-Mobility n-Type Copolymer. J. Am. Chem. Soc. 2014, 136 (11), 4245-4256, 10.1021/ja4118736
Hamadani, B. H.; Gundlach, D. J.; McCulloch, I.; Heeney, M. Undoped Polythiophene Field-Effect Transistors with Mobility of 1cm2V-1s-1. Appl. Phys. Lett. 2007, 91 (24), 243512, 10.1063/1.2824845
Wang, S.; Kappl, M.; Liebewirth, I.; Müller, M.; Kirchhoff, K.; Pisula, W.; Müllen, K. Organic Field-Effect Transistors Based on Highly Ordered Single Polymer Fibers. Adv. Mater. 2012, 24 (3), 417-420, 10.1002/adma.201103057
Tsao, H. N.; Cho, D. M.; Park, I.; Hansen, M. R.; Mavrinskiy, A.; Yoon, D. Y.; Graf, R.; Pisula, W.; Spiess, H. W.; Müllen, K. Ultrahigh Mobility in Polymer Field-Effect Transistors by Design. J. Am. Chem. Soc. 2011, 133 (8), 2605-2612, 10.1021/ja108861q
Crossland, E. J. W.; Tremel, K.; Fischer, F.; Rahimi, K.; Reiter, G.; Steiner, U.; Ludwigs, S. Anisotropic Charge Transport in Spherulitic Poly(3-Hexylthiophene) Films. Adv. Mater. 2012, 24 (6), 839-844, 10.1002/adma.201104284
Sirringhaus, H.; Brown, P. J.; Friend, R. H.; Nielsen, M. M.; Bechgaard, K.; Langeveld-Voss, B. M. W.; Spiering, A. J. H.; Janssen, R. A. J.; Meijer, E. W.; Herwig, P. et al. Two-Dimensional Charge Transport in Self-Organized, High-Mobility Conjugated Polymers. Nature 1999, 401 (6754), 685-688, 10.1038/44359
Oosterbaan, W. D.; Bolsée, J.-C.; Wang, L.; Vrindts, V.; Lutsen, L. J.; Lemaur, V.; Beljonne, D.; McNeill, C. R.; Thomsen, L.; Manca, J. V. On the Relation between Morphology and FET Mobility of Poly(3-Alkylthiophene)s at the Polymer/SiO2 and Polymer/Air Interface. Adv. Funct. Mater. 2014, 24 (14), 1994, 10.1002/adfm.201303298
Zhao, N.; Noh, Y.-Y.; Chang, J.-F.; Heeney, M.; McCulloch, I.; Sirringhaus, H. Polaron Localization at Interfaces in High-Mobility Microcrystalline Conjugated Polymers. Adv. Mater. 2009, 21 (37), 3759-3763, 10.1002/adma.200900326
Statz, M.; Venkateshvaran, D.; Jiao, X.; Schott, S.; McNeill, C. R.; Emin, D.; Sirringhaus, H.; Di Pietro, R. On the Manifestation of Electron-Electron Interactions in the Thermoelectric Response of Semicrystalline Conjugated Polymers with Low Energetic Disorder. Commun. Phys. 2018, 1 (1), 16, 10.1038/s42005-018-0016-5
Broch, K.; Venkateshvaran, D.; Lemaur, V.; Olivier, Y.; Beljonne, D.; Zelazny, M.; Nasrallah, I.; Harkin, D. J.; Statz, M.; Pietro, R. D.; Kronemeijer, A. J.; Sirringhaus, H. Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor-Acceptor Copolymers. Adv. Electron. Mater. 2017, 3 (11), 1700225, 10.1002/aelm.201700225
Wang, S.; Fabiano, S.; Himmelberger, S.; Puzinas, S.; Crispin, X.; Salleo, A.; Berggren, M. Experimental Evidence That Short-Range Intermolecular Aggregation Is Sufficient for Efficient Charge Transport in Conjugated Polymers. Proc. Natl. Acad. Sci. U. S. A. 2015, 112 (34), 10599-10604, 10.1073/pnas.1501381112
Liu, T.; Troisi, A. Understanding the Microscopic Origin of the Very High Charge Mobility in PBTTT: Tolerance of Thermal Disorder. Adv. Funct. Mater. 2014, 24 (7), 925-933, 10.1002/adfm.201302069
Back, J. Y.; Yu, H.; Song, I.; Kang, I.; Ahn, H.; Shin, T. J.; Kwon, S.-K.; Oh, J. H.; Kim, Y.-H. Investigation of Structure-Property Relationships in Diketopyrrolopyrrole-Based Polymer Semiconductors via Side-Chain Engineering. Chem. Mater. 2015, 27 (5), 1732-1739, 10.1021/cm504545e
Han, A.-R.; Dutta, G. K.; Lee, J.; Lee, H. R.; Lee, S. M.; Ahn, H.; Shin, T. J.; Oh, J. H.; Yang, C. ϵ-Branched Flexible Side Chain Substituted Diketopyrrolopyrrole-Containing Polymers Designed for High Hole and Electron Mobilities. Adv. Funct. Mater. 2015, 25 (2), 247-254, 10.1002/adfm.201403020
Baeg, K.-J.; Caironi, M.; Noh, Y.-Y. Toward Printed Integrated Circuits Based on Unipolar or Ambipolar Polymer Semiconductors. Adv. Mater. 2013, 25 (31), 4210-4244, 10.1002/adma.201205361
Lee, J.; Han, A.-R.; Kim, J.; Kim, Y.; Oh, J. H.; Yang, C. Solution-Processable Ambipolar Diketopyrrolopyrrole-Selenophene Polymer with Unprecedentedly High Hole and Electron Mobilities. J. Am. Chem. Soc. 2012, 134 (51), 20713-20721, 10.1021/ja308927g
Mei, J.; Kim, D. H.; Ayzner, A. L.; Toney, M. F.; Bao, Z. Siloxane-Terminated Solubilizing Side Chains: Bringing Conjugated Polymer Backbones Closer and Boosting Hole Mobilities in Thin-Film Transistors. J. Am. Chem. Soc. 2011, 133 (50), 20130-20133, 10.1021/ja209328m
Bronstein, H.; Chen, Z.; Ashraf, R. S.; Zhang, W.; Du, J.; Durrant, J. R.; Shakya Tuladhar, P.; Song, K.; Watkins, S. E.; Geerts, Y. et al. Thieno[3,2-b ]Thiophene-Diketopyrrolopyrrole-Containing Polymers for High-Performance Organic Field-Effect Transistors and Organic Photovoltaic Devices. J. Am. Chem. Soc. 2011, 133 (10), 3272-3275, 10.1021/ja110619k
Zhang, X.; Bronstein, H.; Kronemeijer, A. J.; Smith, J.; Kim, Y.; Kline, R. J.; Richter, L. J.; Anthopoulos, T. D.; Sirringhaus, H.; Song, K. et al. Molecular Origin of High Field-Effect Mobility in an Indacenodithiophene-benzothiadiazole Copolymer. Nat. Commun. 2013, 4 (1), 2238, 10.1038/ncomms3238
Zhang, W.; Smith, J.; Watkins, S. E.; Gysel, R.; McGehee, M.; Salleo, A.; Kirkpatrick, J.; Ashraf, S.; Anthopoulos, T.; Heeney, M. et al. Indacenodithiophene Semiconducting Polymers for High-Performance, Air-Stable Transistors. J. Am. Chem. Soc. 2010, 132 (33), 11437-11439, 10.1021/ja1049324
Noriega, R.; Rivnay, J.; Vandewal, K.; Koch, F. P. V.; Stingelin, N.; Smith, P.; Toney, M. F.; Salleo, A. A General Relationship between Disorder, Aggregation and Charge Transport in Conjugated Polymers. Nat. Mater. 2013, 12 (11), 1038-1044, 10.1038/nmat3722
Venkateshvaran, D.; Nikolka, M.; Sadhanala, A.; Lemaur, V.; Zelazny, M.; Kepa, M.; Hurhangee, M.; Kronemeijer, A. J.; Pecunia, V.; Nasrallah, I. Approaching Disorder-Free Transport in High-Mobility Conjugated Polymers. Nature 2014, 515 (7527), 384, 10.1038/nature13854
Brocorens, P.; Van Vooren, A.; Chabinyc, M. L.; Toney, M. F.; Shkunov, M.; Heeney, M.; McCulloch, I.; Cornil, J.; Lazzaroni, R. Solid-State Supramolecular Organization of Polythiophene Chains Containing Thienothiophene Units. Adv. Mater. 2009, 21 (10-11), 1193-1198, 10.1002/adma.200801668
Yan, H.; Chen, Z.; Zheng, Y.; Newman, C.; Quinn, J. R.; Dötz, F.; Kastler, M.; Facchetti, A. A High-Mobility Electron-Transporting Polymer for Printed Transistors. Nature 2009, 457 (7230), 679-686, 10.1038/nature07727
Mayo, S. L.; Olafson, B. D.; Goddard, W. A. DREIDING: A Generic Force Field for Molecular Simulations. J. Phys. Chem. 1990, 94 (26), 8897-8909, 10.1021/j100389a010
Besler, B. H.; Merz, K. M.; Kollman, P. A. Atomic Charges Derived from Semiempirical Methods. J. Comput. Chem. 1990, 11 (4), 431-439, 10.1002/jcc.540110404
Lemaur, V.; Muccioli, L.; Zannoni, C.; Beljonne, D.; Lazzaroni, R.; Cornil, J.; Olivier, Y. On the Supramolecular Packing of High Electron Mobility Naphthalene Diimide Copolymers: The Perfect Registry of Asymmetric Branched Alkyl Side Chains. Macromolecules 2013, 46 (20), 8171, 10.1021/ma401124r
Niedzialek, D.; Lemaur, V.; Dudenko, D.; Shu, J.; Hansen, M. R.; Andreasen, J. W.; Pisula, W.; Müllen, K.; Cornil, J.; Beljonne, D. Probing the Relation between Charge Transport and Supramolecular Organization down to Ångström Resolution in a Benzothiadiazole-Cyclopentadithiophene Copolymer. Adv. Mater. 2013, 25 (13), 1939, 10.1002/adma.201201058
Olivier, Y.; Niedzialek, D.; Lemaur, V.; Pisula, W.; Müllen, K.; Koldemir, U.; Reynolds, J. R.; Lazzaroni, R.; Cornil, J.; Beljonne, D. 25th Anniversary Article: High-Mobility Hole and Electron Transport Conjugated Polymers: How Structure Defines Function. Adv. Mater. 2014, 26 (14), 2119, 10.1002/adma.201305809
Chabinyc, M. L.; Toney, M. F.; Kline, R. J.; McCulloch, I.; Heeney, M. X-Ray Scattering Study of Thin Films of Poly(2,5-Bis(3-Alkylthiophen-2-Yl)Thieno[3,2-b ]Thiophene). J. Am. Chem. Soc. 2007, 129 (11), 3226-3237, 10.1021/ja0670714
Schuettfort, T.; Thomsen, L.; McNeill, C. R. Observation of a Distinct Surface Molecular Orientation in Films of a High Mobility Conjugated Polymer. J. Am. Chem. Soc. 2013, 135 (3), 1092-1101, 10.1021/ja310240q
Rivnay, J.; Steyrleuthner, R.; Jimison, L. H.; Casadei, A.; Chen, Z.; Toney, M. F.; Facchetti, A.; Neher, D.; Salleo, A. Drastic Control of Texture in a High Performance N-Type Polymeric Semiconductor and Implications for Charge Transport. Macromolecules 2011, 44 (13), 5246-5255, 10.1021/ma200864s
Rivnay, J.; Toney, M. F.; Zheng, Y.; Kauvar, I. V.; Chen, Z.; Wagner, V.; Facchetti, A.; Salleo, A. Unconventional Face-On Texture and Exceptional In-Plane Order of a High Mobility n-Type Polymer. Adv. Mater. 2010, 22 (39), 4359-4363, 10.1002/adma.201001202
Luzio, A.; Criante, L.; D'Innocenzo, V.; Caironi, M. Control of Charge Transport in a Semiconducting Copolymer by Solvent-Induced Long-Range Order. Sci. Rep. 2013, 3, 3425, 10.1038/srep03425
Steyrleuthner, R.; Schubert, M.; Howard, I.; Klaumünzer, B.; Schilling, K.; Chen, Z.; Saalfrank, P.; Laquai, F.; Facchetti, A.; Neher, D. Aggregation in a High-Mobility n-Type Low-Bandgap Copolymer with Implications on Semicrystalline Morphology. J. Am. Chem. Soc. 2012, 134 (44), 18303-18317, 10.1021/ja306844f
Cornil, J.; Gueli, I.; Dkhissi, A.; Sancho-Garcia, J. C.; Hennebicq, E.; Calbert, J. P.; Lemaur, V.; Beljonne, D.; Brédas, J. L. Electronic and Optical Properties of Polyfluorene and Fluorene-Based Copolymers: A Quantum-Chemical Characterization. J. Chem. Phys. 2003, 118 (14), 6615, 10.1063/1.1561054
Vakhshouri, K.; Smith, B. H.; Chan, E. P.; Wang, C.; Salleo, A.; Wang, C.; Hexemer, A.; Gomez, E. D. Signatures of Intracrystallite and Intercrystallite Limitations of Charge Transport in Polythiophenes. Macromolecules 2016, 49 (19), 7359-7369, 10.1021/acs.macromol.6b01086
Hsu, B. B.-Y.; Cheng, C.-M.; Luo, C.; Patel, S. N.; Zhong, C.; Sun, H.; Sherman, J.; Lee, B. H.; Ying, L.; Wang, M. et al. The Density of States and the Transport Effective Mass in a Highly Oriented Semiconducting Polymer: Electronic Delocalization in 1D. Adv. Mater. 2015, 27 (47), 7759-7765, 10.1002/adma.201502820
Yuan, Z.; Fu, B.; Thomas, S.; Zhang, S.; DeLuca, G.; Chang, R.; Lopez, L.; Fares, C.; Zhang, G.; Bredas, J.-L. et al. Unipolar Electron Transport Polymers: A Thiazole Based All-Electron Acceptor Approach. Chem. Mater. 2016, 28 (17), 6045-6049, 10.1021/acs.chemmater.6b01929
Wetzelaer, G.-J. A. H.; Kuik, M.; Olivier, Y.; Lemaur, V.; Cornil, J.; Fabiano, S.; Loi, M. A.; Blom, P. W. M. Asymmetric Electron and Hole Transport in a High-Mobility n-Type Conjugated Polymer. Phys. Rev. B: Condens. Matter Mater. Phys. 2012, 86 (16), 165203, 10.1103/PhysRevB.86.165203
Vezie, M. S.; Few, S.; Meager, I.; Pieridou, G.; Dörling, B.; Ashraf, R. S.; Goñi, A. R.; Bronstein, H.; McCulloch, I.; Hayes, S. C. et al. Exploring the Origin of High Optical Absorption in Conjugated Polymers. Nat. Mater. 2016, 15 (7), 746-753, 10.1038/nmat4645
