[en] Polydimethylsiloxane (PDMS)/carbon nanotube nanocomposite-based coatings are prepared and their surface proper¬ties are characterized by contact angle measurements and Atomic Force Microscopy. The addition of a tiny amount of multiwall carbon nanotubes (0.1 wt.% MWCNTs) within the polymeric matrix leads to dramatic changes in the wettability and the surface morphology of the material, which take place during immersion in demineralised water. We attribute these phenomena to deep modifications of the organization and mobility of the polysiloxane chains due to the strong affinity between the studied MWCNTs and PDMS. These results provide fundamental insights for the preparation and the use of a novel class of silicone-based coatings, e.g., in antifouling applications.
Disciplines :
Materials science & engineering Chemistry Physics
Author, co-author :
Beigbeder, Alexandre
Jeusette, Mélanie
Mincheva, Rosica ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites
Claes, Michael
Brocorens, Patrick ; Université de Mons > Faculté des Sciences > Chimie des matériaux nouveaux
Lazzaroni, Roberto ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux
Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites
Language :
English
Title :
On The Effect of Carbon Nanotubes on The Wettability and Surface Morphology of Hydrosilylation-Curing Silicone Coatings
Publication date :
12 June 2009
Journal title :
Journal of Nanostructured Polymers and Nanocomposites
ISSN :
1790-4439
Publisher :
ADCOTEC Ltd, United Kingdom
Volume :
5
Issue :
23
Pages :
37-43
Peer reviewed :
Peer Reviewed verified by ORBi
Research unit :
S816 - Matériaux Polymères et Composites S817 - Chimie des matériaux nouveaux
Research institute :
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Lee W.A., Rutherford R.A., In Polymer Handbook 2nd ed., J. Brandup and E.H. Immergut [Eds], Wiley: New York 1975, PIII, 139.
Bullock S., Johnston E. E.: Wilson T., Gatenholm P. and Wynne K. J., Surface science of a filled polydimethylsiloxane-based alkoxysilane-cured elastomer: RTV11 », J. Coll. Inter. Sci. 210 (1999) 18.
Beigbeder A., Linares M., Devalckenaere M., Degée Ph., Claes M., Beljonne D., Lazzaroni R. and Dubois Ph., « CH-pi Interactions as the Driving Force for Silicone-Based Nanocomposites with Exceptional Properties », Adv. Mater. 20 (2008) 1003.
Beigbeder A., Degée Ph., Conlan S.L, Mutton R., Clare A.S, Pettitt M.E., Callow M.E., Callow J.A. and Dubois Ph., Preparation and characterisation of silicone-based coatings filled with carbon nanotubes and natural sepiolite and their application as marine fouling-release coatings» Biofouling 24 (2008) 291.
Beigbeder A., Bonduel D., Claes M., Degée Ph., Dubois Ph., "Use of a marine anti-biofouling and fouling release coating composition", WO2008046166, (2008).
Hillborg H. and Gedde U.W., "Hydrophobicity recovery of polydimethylsiloxane after exposure to corona discharges», Polymer 39 (1998) 1991.
Khorosani M.T. and Mirzadeh H., "BHK cells behaviour on laser treated polydimethylsiloxane surface», Colloids Surf. B Biointerfaces 35 (2004) 67.
Morra M., Ochiello E., Marola R., Garbassi F., Humphury P. and Johnson D., On the aging of oxygen plasma-treated polydimethylsiloxane surfaces», J. Colloid Interf. Sci. 137 (1990) 11.
Hillborg H. and Gedde., U.W., Hydrophobicity changes in silicone rubbers», IEE Trans. Dielectr. Electr. Insul. 6 (1999) 703.
Kim J., Chadhury M.K and Owen M.J., Hydrophobicity loss and recovery of silicone HV insulation», IEE Trans. Dielectr. Electr. Insul. 6 (1999) 695.
Chen C., Wang J. and Chen Z., Surface Restructuring Behavior of Various Types of Poly(dimethylsiloxane) in Water Detected by SFG», Langmuir 20 (2004) 10186.
Carlos A., Barrios C.A., Xu Q., Cutright T. and Newby B.Z., Incorporating zosteric acid into silicone coatings to achieve its slow release while reducing fresh water bacterial attachment », Colloids Surf. B Biointerfaces 41 (2005) 83.
To check that the change in morphology observed after the immersion is not due to an experimental artefact [for instance related to the AFM imaging procedure itself], the investigated coatings were imaged at different tapping forces by varying the set point to free amplitude ratio [Rsp] from 0.4 to 0.9. No significant differences were detected. Similar morphological reorganizations of the surfaces were observed whatever the applied tapping force.
Vlachopoulou M.E., Tserepi A., Beltsios K., Boulousis G. and Gogolides E., Nanostructuring of PDMS surfaces: Dependence on casting solvents», Microelectronic Engineering 84 (2007) 1476.