Combustion; Hydrogen; Micro gas turbine; Partially stirred reactor; Reynolds-averaged navier-stokes; Energy systems; Hydrogen combustion; Hydrogen enriched combustions; Reynolds - Averaged Navier-Stokes; Energy Engineering and Power Technology
Abstract :
[en] The transition toward carbon-neutral energy systems has increased interest in carbon-free fuels, with hydrogen emerging as a key candidate for low-emission power generation. In this context, micro gas turbines (mGTs) represent an attractive solution due to their operational flexibility and suitability for decentralised heat and power production in energy systems with a high share of variable renewable sources. MGTs burn mainly natural gas, resulting in CO2 production. To reduce these emissions, natural gas can be replaced by hydrogen. However, the transition from methane to hydrogen is not straightforward and requires careful investigation. Hydrogen combustion introduces specific challenges related to its high reactivity, including increased risks of flashback, autoignition, and elevated NOx emissions in burners originally designed for methane. To this end, a partially premixed 20 kW th mGT combustor of a 3.2 kW e machine was investigated. Various experimental set points were available, ranging from pure methane to 50%volH2, including Exhaust Gas Recirculation (EGR) with a valve opening between 0% and 85%. Computational Fluid Dynamics (CFD) simulations were employed to evaluate the impact of hydrogen addition to the fuel. The numerical model was validated against experimental data, as it accurately predicted the concentrations of different species (CO2, O2, CO, and NOx) over a broad range of operating conditions, demonstrating the validity of the adopted computational approach. The validated numerical framework was then used to extrapolate toward unexplored operating conditions, extending from 50% H2 to pure hydrogen combustion. The results highlighted the need for future geometry adaptations to prevent damage to the swirler at hydrogen contents exceeding 90%, as ignition was predicted to occur upstream of the combustion chamber. Finally, a kinetic analysis of the CFD results indicated that NO formation is predominantly governed by thermal pathways, with hydrogen enrichment accelerating the chemistry and altering the NO formation process.
Disciplines :
Energy
Author, co-author :
Piscopo, Alessandro ; Université de Mons - UMONS > Faculté Polytechnique > Service de Thermique et Combustion ; Université Libre de Bruxelles, École Polytechnique de Bruxelles, Aero-Thermo-Mechanics Laboratory, Brussels, Belgium ; Université Libre de Bruxelles and Vrije Universiteit Brussel, Brussels Institute for Thermal-Fluid Systems and Clean Energy (BRITE), Brussels, Belgium
Y. Farrokhi, Farshid ; Université Libre de Bruxelles, École Polytechnique de Bruxelles, Aero-Thermo-Mechanics Laboratory, Brussels, Belgium ; Université Libre de Bruxelles and Vrije Universiteit Brussel, Brussels Institute for Thermal-Fluid Systems and Clean Energy (BRITE), Brussels, Belgium ; University of Mons, Thermal Engineering & Combustion Unit, Mons, Belgium ; UMONS Micro gAsturbine Research Centre - UMARC, Mons, Belgium
Giuntini, Lorenzo ; Université Libre de Bruxelles, École Polytechnique de Bruxelles, Aero-Thermo-Mechanics Laboratory, Brussels, Belgium ; Université Libre de Bruxelles and Vrije Universiteit Brussel, Brussels Institute for Thermal-Fluid Systems and Clean Energy (BRITE), Brussels, Belgium
De Paepe, Ward ; Université de Mons - UMONS > Faculté Polytechnique > Service de Thermique et Combustion
Parente, Alessandro; Université Libre de Bruxelles, École Polytechnique de Bruxelles, Aero-Thermo-Mechanics Laboratory, Brussels, Belgium ; Université Libre de Bruxelles and Vrije Universiteit Brussel, Brussels Institute for Thermal-Fluid Systems and Clean Energy (BRITE), Brussels, Belgium ; WEL Research Institute, Wavre, Belgium
Language :
English
Title :
A validated numerical framework for hydrogen-enriched combustion in a micro gas turbine combustor
P. W. Agostinelli, D. Laera, I. Chterev, I. G. Boxx, L. Y. M. Gicquel, T. Poinsot, On the impact of h2-enrichment on flame structure and combustion dynamics of a lean partially-premixed turbulent swirling flame, Combustion and Flame (2022). https://api.semanticscholar.org/CorpusID:249038477
Y. Zhang, J. Wu, S. Ishizuka, Hydrogen addition effect on laminar burning velocity, flame temperature and flame stability of a planar and a curved ch4–h2–air premixed flame, International Journal of Hydrogen Energy 34 (1) (2009) 519–527. doi:https://doi.org/10.1016/j.ijhydene.2008.10.065https://www.sciencedirect.com/science/article/pii/S0360319908014018
M. Emadi, D. Karkow, T. Salameh, A. Gohil, A. Ratner, Flame structure changes resulting from hydrogen-enrichment and pressurization for low-swirl premixed methane–air flames, International Journal of Hydrogen Energy 37 (13) (2012) 10397–10404, proceedings of the Symposium on Hydrogen Production and Applications at the 240th American Chemical Society National Meeting, August 22–26, 2010, Boston, Massachusetts, USA. doi:https://doi.org/10.1016/j.ijhydene.2012.04.017https://www.sciencedirect.com/science/article/pii/S0360319912008713
D. Ebi, R. Bombach, P. Jansohn, Swirl flame boundary layer flashback at elevated pressure: Modes of propagation and effect of hydrogen addition, Proceedings of the Combustion Institute 38 (4) (2021) 6345–6353. doi:https://doi.org/10.1016/j.proci.2020.06.305https://www.sciencedirect.com/science/article/pii/S1540748920303977
R. Ranjan, N. T. Clemens, Insights into flashback-to-flameholding transition of hydrogen-rich stratified swirl flames, Proceedings of the Combustion Institute 38 (4) (2021) 6289–6297. doi:https://doi.org/10.1016/j.proci.2020.06.017https://www.sciencedirect.com/science/article/pii/S1540748920300420
A. Cappelletti, F. Martelli, E. Bianchi, E. Trifoni, Numerical redesign of a 100 kw mgt combustor for 100% H2 fuelling, Energy Procedia 45 (2014) 1412–1421, aTI 2013 – 68th Conference of the Italian Thermal Machines Engineering Association. doi:10.1016/j.egypro.2014.01.148. https://www.sciencedirect.com/science/article/pii/S1876610214001490
A. Pappa, L. Bricteux, P. Bénard, W. De Paepe, Can water dilution avoid flashback on a hydrogen-enriched micro-gas turbine combustion?—a large eddy simulations study, Journal of Engineering for Gas Turbines and Power 143 (4) (2021) 041008. arXiv:https://asmedigitalcollection.asme.org/gasturbinespower/article-pdf/143/4/041008/6646585/gtp_143_04_041008.pdf, doi:10.1115/1.4049798. https://doi.org/10.1115/1.4049798
I. o. C. T. Technische Universität Berlin. H2mGT — development of a hydrogen micro gas turbine combustor. 2024. [Accessed: 14 Jan 2025].
T. Tanneberger, J. Mundstock, C. Rex, S. Rösch, C. O. Paschereit, Development of a hydrogen micro gas turbine combustor: Atmospheric pressure testing, Journal of Engineering for Gas Turbines and Power 146 (4) (2023) 041013. arXiv:https://asmedigitalcollection.asme.org/gasturbinespower/article-pdf/146/4/041013/7147419/gtp_146_04_041013.pdf, doi:10.1115/1.4063708. https://doi.org/10.1115/1.4063708
T. Tanneberger, J. Mundstock, S. Rösch, C. Rex, C. O. Paschereit, Development of a hydrogen microgas turbine combustor: Nox emissions and secondary air injection, Journal of Engineering for Gas Turbines and Power 147 (2) (2024) 021015. arXiv:https://asmedigitalcollection.asme.org/gasturbinespower/article-pdf/147/2/021015/7383487/gtp_147_02_021015.pdf, doi:10.1115/1.4066346. https://doi.org/10.1115/1.4066346
Experimental analysis of the hydrogen capability of a fuel flexible jet stabilized syngas micro gas turbine combustor under atmospheric conditions. Volume 3B: Combustion, Fuels, and Emissions Turbo Expo; 2023. 10.1115/GT2023-103418.
V. Fortunato, A. Giraldo, M. Rouabah, R. Nacereddine, M. Delanaye, A. Parente, Experimental and numerical investigation of a mild combustion chamber for micro gas turbine applications, Energies 11 (12) (2018). doi:10.3390/en11123363. https://www.mdpi.com/1996-1073/11/12/3363
Z. Li, M. Ferrarotti, A. Cuoci, A. Parente, Finite-rate chemistry modelling of non-conventional combustion regimes using a partially-stirred reactor closure: Combustion model formulation and implementation details, Applied Energy 225 (2018) 637–655.
UMONS Micro Gas Turbine Research Centre - UMARC, Umons micro gas turbine research centre (umarc), https://web.umons.ac.be/trmi/en/research-activities/umarc/, accessed: 2026-01-06 (2026).
V. Thielens, F. Demeyer, K. P. Geigle, P. Kutne, W. De Paepe, Experimental investigation of the emissions and performance of a micro gas turbine setup with enhanced egr, Applied Thermal Engineering 267 (2025) 125673. doi:https://doi.org/10.1016/j.applthermaleng.2025.125673https://www.sciencedirect.com/science/article/pii/S1359431125002649
V. Thielens, F. Demeyer, K. P. Geigle, P. Kutne, W. De Paepe, Experimental impact of exhaust gas recirculation and hydrogen injection on the emissions of a micro gas turbine, E3S Web Conf. 663 (2025) 01016. doi:10.1051/e3sconf/202566301016. https://doi.org/10.1051/e3sconf/202566301016
ANSYS Inc., ANSYS Fluent Theory Guide, release 24.1 (2024).
M. Vilespy, A. Aniello, D. Laera, T. Poinsot, T. Schuller, L. Selle, Analysis of the origin of nox emissions in non premixed dual swirl hydrogen flames, Combustion and Flame 273 (2025) 113925. doi:https://doi.org/10.1016/j.combustflame.2024.113925https://www.sciencedirect.com/science/article/pii/S0010218024006345
A. Péquin, M. J. Evans, A. Chinnici, P. R. Medwell, A. Parente, The reactor-based perspective on finite-rate chemistry in turbulent reacting flows: A review from traditional to low-emission combustion, Applications in Energy and Combustion Science 16 (2023) 100201.
S. Iavarone, A. Péquin, Z. X. Chen, N. A. K. Doan, N. Swaminathan, A. Parente, An a priori assessment of the partially stirred reactor (pasr) model for mild combustion, Proceedings of the Combustion Institute 38 (4) (2021) 5403–5414. doi:10.1016/j.proci.2020.06.234.
A. Piscopo, W. De Paepe, A. Parente, S. Iavarone, Chemical timescale analysis of the partially stirred reactor model for a hydrogen-fuelled scramjet, Results in Engineering 23 (2024) 102834. doi:https://doi.org/10.1016/j.rineng.2024.102834https://www.sciencedirect.com/science/article/pii/S2590123024010892
T. F. Smith, Z. F. Shen, J. N. Friedman, Evaluation of coefficients for the weighted sum of gray gases model, Journal of Heat Transfer 104 (4) (1982) 602–608. arXiv:https://asmedigitalcollection.asme.org/heattransfer/article-pdf/104/4/602/5563512/602_1.pdf, doi:10.1115/1.3245174. https://doi.org/10.1115/1.3245174
R. Bilger, S. Stårner, R. Kee, On reduced mechanisms for methane-air combustion in nonpremixed flames, Combustion and Flame 80 (2) (1990) 135–149.
S. Iavarone, M. Cafiero, M. Ferrarotti, F. Contino, A. Parente, A multiscale combustion model formulation for nox predictions in hydrogen enriched jet flames, International Journal of Hydrogen Energy 44 (41) (2019) 23436–23457.
S. J. Klippenstein, L. B. Harding, P. Glarborg, J. A. Miller, The role of nnh in no formation and control, Combustion and Flame 158 (4) (2011) 774–789, special Issue on Kinetics.
S. Xu, Z. Tian, H. Liu, Development of a skeletal mechanism with nox chemistry for ch4/h2 combustion over a wide range of hydrogen-blending ratios, Energy & Fuels 38 (20) (2024) 19758–19777, published: 2024-10-17. doi:10.1021/acs.energyfuels.4c02802. https://doi.org/10.1021/acs.energyfuels.4c02802
C. Fureby, Comparison of flamelet and finite rate chemistry les for premixed turbulent combustion, in: 45th AIAA aerospace sciences meeting and exhibit, 2007, p. 1413.
C. Douglas, B. Emerson, T. Lieuwen, T. Martz, R. Steele, B. Noble, Nox emissions from hydrogen-methane fuel blends, Tech. rep., Georgia Institute of Technology and Electric Power Research Institute, white Paper (January 2022). https://doi.org/10.35090/gatech/65364
Y. Gong, D. Fredrich, A. J. Marquis, W. P. Jones, Numerical investigation of combustion instabilities in swirling flames with hydrogen enrichment, Flow, Turbulence and Combustion 111 (3) (2023) 953–993. doi:10.1007/s10494-023-00476-5.
E. Petersen, J. Hall, S. Smith, J. de Vries, A. Amadio, M. Crofton, Ignition of lean methane-based fuel blends at gas turbine pressures, Journal of Engineering for Gas Turbines and Power-transactions of The Asme - J ENG GAS TURB POWER-T ASME 129 (10 2007). doi:10.1115/1.2720543.
E. E. Fordoei, K. Mazaheri, A. Mohammadpour, Effects of hydrogen addition to methane on the thermal and ignition delay characteristics of fuel-air, oxygen-enriched and oxy-fuel mild combustion, International Journal of Hydrogen Energy 46 (68) (2021) 34002–34017. doi:https://doi.org/10.1016/j.ijhydene.2021.07.065https://www.sciencedirect.com/science/article/pii/S0360319921027063
Y. B. Zel’dovich, The oxidation of nitrogen in combustion and explosions, Acta Physicochimica URSS 21 (1946) 577–628.
C. Fenimore, Formation of nitric oxide in premixed hydrocarbon flames, Symposium (International) on Combustion 13 (1) (1971) 373–380, thirteenth symposium (International) on Combustion. doi:https://doi.org/10.1016/S0082-0784(71)80040-1https://www.sciencedirect.com/science/article/pii/S0082078471800401
P. Malte, D. Pratt, Measurement of atomic oxygen and nitrogen oxides in jet-stirred combustion, Symposium (International) on Combustion 15 (1) (1975) 1061–1070, fifteenth Symposium (International) on Combustion. doi:https://doi.org/10.1016/S0082-0784(75)80371-7https://www.sciencedirect.com/science/article/pii/S0082078475803717
J. W. Bozzelli, A. M. Dean, O + nnh: A possible new route for nox formation in flames, International Journal of Chemical Kinetics 27 (11) (1995) 1097–1109.
M. Cafiero, S. Sharma, M. Mustafa Kamal, A. Coussement, A. Parente, Effect of aromatic doping on the thermal and emissions characteristics of hydrogen-rich fuels in a semi-industrial scale furnace, Fuel 358 (2024) 130075. doi:https://doi.org/10.1016/j.fuel.2023.130075https://www.sciencedirect.com/science/article/pii/S0016236123026893