[en] Energy density; [en] Reactor upscaling; [en] Salt-in-silica composite; [en] Open sorption; [en] Seasonal energy storage
Abstract :
[en] This work presents the results of the performance characterization for novel salt-in-silica composites, destined for seasonal energy storage. The materials were synthesized using the Davisil® silica gel to support the hygroscopic inorganic salts of calcium chloride (CaCl2), magnesium chloride (MgCl2) or strontium bromide (SrBr2). The experiments were carried out on an open sorption laboratory setup under constant hydration conditions. The sample mass was 245 g, which is representative of a prototype control volume of 0.5 l, and the nominal air flow rate was 215 l/min. Energy storage densities between 70 and 145 kWh/m³ of control volume were experimentally found at 30 °C (inlet air temperature) and for different inlet air relative humidity levels. Average specific thermal powers in the range between 93 and 311 W/kg were measured. Based on the experimental results, the design and upscaling of the seasonal energy storage were demonstrated. The best feasible energy storage densities ranging from 50 to 90 kWh/m³ of up-scaled reactor were predicted to deliver 1000 W of rated thermal power.
Disciplines :
Mechanical engineering Chemistry Library & information sciences
Author, co-author :
Skrylnyk, Oleksandr ; Université de Mons > Faculté Polytechnique > Service de Thermodynamique, Physique mathématiques
Courbon, Emilie ; Université de Mons > Faculté Polytechnique > Thermodynamique, Physique mathématiques
Heymans, Nicolas ; Université de Mons > Faculté Polytechnique > Service de Thermodynamique, Physique mathématiques
Frère, Marc ; Université de Mons > Faculté Polytechnique > Service de Thermodynamique, Physique mathématiques
Bougard, Jacques ; Université de Mons > Faculté Polytechnique > Thermodynamique, Physique mathématiques
Descy, Gilbert
Language :
English
Title :
Performance characterization of salt-in-silica composite materials for seasonal energy storage design
Casey, S.P., Aydin, D., Riffat, S., Elvins, J., Salt impregnated desiccant matrices for open thermochemical energy storage - Hygrothermal cyclic behaviour and energetic analysis by physical experimentation. Energy Build. 92 (2016), 128–139, 10.1016/j.enbuild.2015.01.048.
Kornhammer, K., Druske, M.-M., Fopah-Lele, A., Rammelberg, H.U., Wegscheider, N., Opel, O., Osterland, T., Ruck, W., Sorption and thermal characterization of composite materials based on chlorides for thermal energy storage. Appl. Energy 162 (2016), 1462–1472, 10.1016/j.apenergy.2015.08.037.
Hongois, S., Kuznik, F., Stevens, P., Roux, J.-J., Development and characterisation of a new MgSO4 - zeolite composite for long-term thermal energy storage. Sol. Energy Mater. Sol. Cells 95 (2011), 1831–1837, 10.1016/j.solmat.2011.01.050.
Aydin, D., Casey, S.P., Chen, X., Riffat, S., Novel open-sorption pipe reactor for solar thermal energy storage. Energy Convers. Manag. 121 (2016), 321–334, 10.1016/j.enconman.2016.05.045.
Tanguy, G., Marias, F., Neveu, P., Papillon, P., Thermodynamic analysis and experimental study of solid/gas reactor operating in open mode. Energy 66 (2014), 757–765, 10.1016/j.energy.2014.01.101.
Johannes, K., Kuznik, F., Hubert, J.-L., Durier, F., Obrecht, C., Design and characterisation of a high powered energy dense zeolite thermal energy storage system for buildings. Appl. Energy 159 (2015), 80–86, 10.1016/j.apenergy.2015.08.109.
Stitou, D., Mazet, N., Mauran, S., Experimental investigation of a solid/gas thermochemical storage process for solar air-conditioning. Energy 41 (2012), 261–270, 10.1016/j.energy.2011.07.029.
Krönauer, A., Lävemann, E., Brückner, S., Hauer, A., Mobile sorption heat storage in industrial waste heat recovery. Energy Procedia 73 (2015), 272–280, 10.1016/j.egypro.2015.07.688.
Grisel, R.J., Smelding, S.F., de Boer, R., Waste heat driven silica gel/water adsorption cooling in trigeneration. Appl. Therm. Eng. 30 (2010), 1039–1046, 10.1016/j.applthermaleng.2010.01.020.
Cabeza, L.F., Solé A., Martorell, I., State of the art on gas–solid thermochemical energy storage systems and reactors for building applications. Renew. Sustain. Energy Rev. 47 (2015), 386–398, 10.1016/j.rser.2015.03.077.
Lahmidi, H., Mauran, S., Goetz, V., Definition, test and simulation of a thermochemical storage process adapted to solar thermal systems. Sol. Energy 80 (2006), 883–893, 10.1016/j.solener.2005.01.014.
N'Tsoukpoe, K., Schmidt, T., Rammelberg, H., Watts, B., Ruck, W., A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage. Appl. Energy 124 (2014), 1–16, 10.1016/j.apenergy.2014.02.053.
Rammelberg, H.U., Osterland, T., Priehs, B., Opel, O., Ruck, W.K., Thermochemical heat storage materials - Performance of mixed salt hydrates. Sol. Energy 136 (2016), 571–589, 10.1016/j.solener.2016.07.016.
van Essen, V.M., Zondag, H.A., Cot Gores, J., Bleijendaal, L.P.J., Bakker, M., Schuitema, R., van Helden, W.G.J., He, Z., Rindt, C.C.M., Characterization of MgSO4 hydrate for thermochemical seasonal heat storage. J. Sol. Energy Eng., 131, 2009, 10.1115/1.4000275 041014-041014-7.
Jänchen, J., Schumann, K., Thrun, E., Brandt, A., Unger, B., Hellwig, U., Preparation, hydrothermal stability and thermal adsorption storage properties of binderless zeolite beads. Int. J. Low-carbon Technol. 7 (2012), 275–279, 10.1093/ijlct/cts037.
Henninger, S.K., Habib, H.A., Janiak, C., MOFs as adsorbents for low temperature heating and cooling applications. J. Am. Chem. Soc. 131 (2009), 2776–2777, 10.1021/ja808444z.
Deshmukh, H., Maiya, M., Murthy, S.S., Study of sorption based energy storage system with silica gel for heating applications. Appl. Therm. Eng. 111 (2016), 1640–1646, 10.1016/j.applthermaleng.2016.07.069.
Pardo, P., Minvielle-Anxionnaz, Z., Rougé S., Cognet, P., Cabassud, M., Ca(OH)2/CaO reversible reaction in a fluidized bed reactor for thermochermical heat storage. Sol. Energy 107 (2014), 605–616, 10.1016/j.solener.2014.06.010.
Michel, B., Mazet, N., Neveu, P., Experimental investigation of an innovative thermochemical process operating with a hydrate salt and moist air for thermal storage of solar energy: global performance. Appl. Energy 129 (2014), 177–186, 10.1016/j.apenergy.2014.04.073.
Courbon, E., D'Ans, P., Permyakova, A., Skrylnyk, O., Steunou, N., Degrez, M., Frère, M., A new composite sorbent based on SrBr2 and silica gel for solar energy storage application with high energy storage density and stability. Appl. Energy 190 (2017), 1184–1194, 10.1016/j.apenergy.2017.01.041.
Permyakova, A., Skrylnyk, O., Courbon, E., Affram, M., Wang, S., Lee, U.H., Valekar, A.H., Nouar, F., Mouchaham, G., Devic, T., de Weireld, G., Chang, J.S., Steunou, N., Frère, M., Serre, C., Synthesis optimization, shaping, and heat reallocation evaluation of the hydrophilic metal–Organic framework MIL-160(Al). ChemSusChem 10 (2017), 1–9, 10.1002/cssc.201700164.
Auroux, A., Whiting, G., Grondin, D., Bennici, S., Heats of water sorption studies on zeolite-MgSO4 composites as potential thermochemical heat storage materials. Sol. Energy Mater. Sol. Cells 112 (2013), 112–119, 10.1016/j.solmat.2013.01.020.
Jabbari-Hichri, A., Bennici, S., Auroux, A., Enhancing the heat storage density of silica-alumina by addition of hygroscopic salts (CaCl2, Ba(OH)2 and LiNO3). Sol. Energy Mater. Sol. Cells 140 (2015), 351–360, 10.1016/j.solmat.2015.04.032.
Whiting, G.T., Grondin, D., Stosic, D., Bennici, S., Auroux, A., Zeolite–MgCl2 composites as potential long-term heat storage materials: influence of zeolite properties on heats of water sorption. Sol. Energy Mater. Sol. Cells 128 (2014), 289–295, 10.1016/j.solmat.2014.05.016.
Bales, C., Gantenbein, P., Jaenig, D., Kerskes, H., Summer, K., van Essen, M., Laboratory Tests of Chemical Reactions and Prototype Sorption Storage Units. A Report of IEA Solar Heating and Cooling Programme-task 32., 2008, Solar Energy Research Center SERC, Borlänge http://www.iea-shc.org.
Mauran, S., Lahmidi, H., Goetz, V., Solar heating and cooling by a thermochemical process. First experiments of a prototype storing 60 kWh by a solid/gas reaction. Sol. Energy 82 (2008), 623–636, 10.1016/j.solener.2008.01.002.
van Helden, W., Wagner, W., Schubert, V., Krampe-Zadler, C., Kerskes, H., Bertsch, F., Mette, B., Jänchen, J., Experimental tests on a solid sorption prototype for seasonal solar thermal storage. Proc. Eurotherm Seminar No. 99: Advances in Thermal Energy Storage, 2014, 1–8.
Zondag, H., Kikkert, B., Smeding, S., de Boer, R., Bakker, M., Prototype thermochemical heat storage with open reactor system. Appl. Energy 109 (2013), 360–365, 10.1016/j.apenergy.2013.01.082.
Hongois, S., Kuznik, F., Stevens, P., Roux, J.-J., Development and characterisation of a new MgSO4−zeolite composite for long-term thermal energy storage. Sol. Energy Mater. Sol. Cells 95 (2011), 1831–1837, 10.1016/j.solmat.2011.01.050.
Freni, A., Bonaccorsi, L., Calabrese, L., Caprì A., Franzzica, A., Sapienza, A., SAPO-34 coated adsorbent heat exchanger for adsorption chillers. Appl. Therm. Eng. 82 (2015), 1–7, 10.1016/j.applthermaleng.2015.02.052.
Bonaccorsi, L., Calabrese, L., Freni, A., Proverbio, E., Restuccia, G., Zeolites direct synthesis on heat exchangers for adsorption heat pumps. Appl. Therm. Eng. 50 (2013), 1590–1595, 10.1016/j.applthermaleng.2011.10.028.
D'Ans P., Degrez M., Frère M., Courbon E. Hygroscopic salt apparatus. Belgium Patent WO2016050912, 7 april 2016.
Mauran S., Lebrun M., Prades P., Moreau M., Spinner B., Drapier C., Active composite and its use as reactive medium. France Patent US5283219, 1 February 1994.
Liu, H., Nagano, K., Togawa, J., A composite material made of mesoporous siliceous shale impregnated with lithium chloride for open sorption thermal energy storage system. Sol. Energy 111 (2015), 186–200, 10.1016/j.solener.2014.10.044.
Yu, N., Wang, R., Lu, Z., Wang, L., Study on consolidated composite sorbents impregnated with LiCl for thermal energy storage. Int. J. Heat Mass Transf. 84 (2015), 660–670, 10.1016/j.ijheatmasstransfer.2015.01.065.
Michel, B., Mazet, N., Mauran, S., Stitou, D., Xu, J., Thermochemical process for seasonal storage of solar energy: characterization and modeling of a high density reactive bed. Energy 47 (2012), 553–563, 10.1016/j.energy.2012.09.029.
Courbon, E., D'Ans, P., Permyakova, A., Skrylnyk, O., Steunou, N., Degrez, M., Frère, M., Further improvement of the synthesis of silica gel and CaCl2 composites: enhancement of energy storage density and stability over cycles for solar heat storage coupled with space heating applications. Sol. Energy 15 (2017), 532–541, 10.1016/j.solener.2017.08.034.
Courbon E., Frère M., Heymans N., D'Ans P. Hygroscopic composite material. Belgium Patent WO/2015/197788, 30 Decembre 2015.
Courbon, E., Étude Du Stockage d’énergie Thermique d'origine Solaire Par Réaction Thermochimique. PhD Thesis, 2016, Université de Mons, Mons.
Yu, N., Wang, R., Lu, Z., Wang, L., Development and characterization of silica gel–LiCl composite sorbents for thermal energy storage. Chem. Eng. Sci. 111 (2014), 73–84, 10.1016/j.ces.2014.02.012.
Zhu, D., Wu, H., Wang, S., Experimental study on composite silica gel supported CaCl2 sorbent for low grade heat storage. Int. J. Therm. Sci. 45 (2006), 804–813, 10.1016/j.ijthermalsci.2005.10.009.
Wakao, N., Funazkri, T., Effect of fluid dispersion coefficients on particle-to-fluid mass transfer coefficients in packed beds: correlation of Sherwood numbers. Chem. Eng. Sci. 33 (1978), 1375–1384, 10.1016/0009-2509(78)85120-3.
Kalogirou, S., The potential of solar industrial process heat applications. Appl. Energy 76 (2003), 337–361, 10.1016/S0306-2619(02)00176-9.
Ku, H.H., Notes on the use of propagation of error formulas. J. Res. Natl. Bur. Stand. Sect. C Eng. Instrum. 70C (1966), 263–273 https://archive.org/details/jresv70Cn4p263.