[en] Well-defined conjugated polymers remain intensively studied polymers, since they reveal promising applications in the field of molecular electronics.1 These polymers significantly owe their potential to the fact that their polymerization can proceed via a
Disciplines :
Chemistry
Author, co-author :
Smeets, Alfons
De Winter, Julien ; Université de Mons > Faculté des Sciences > Synthèse et spectrométrie de masse organiques
Gerbaux, Pascal ; Université de Mons > Faculté des Sciences > Synthèse et spectrométrie de masse organiques
Verbiest, Thierry
Koeckelberghs, Guy
Language :
English
Title :
Incorporation of different end-groups in conjugated polymers using functional nickel initiators
Publication date :
01 January 2009
Journal title :
Macromolecules
ISSN :
0024-9297
Publisher :
American Chemical Society (ACS), United States - District of Columbia
Volume :
42
Issue :
20
Pages :
7638-7641
Peer reviewed :
Peer Reviewed verified by ORBi
Research unit :
S816 - Matériaux Polymères et Composites S836 - Synthèse et spectrométrie de masse organiques
Research institute :
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Liu, J.; Loewe, R. S.; McCullough, R. D. Macromolecules 1999, 32, 5777-5785.
Bronstein, H. A.; Luscombe, C. K. J. Am. Chem. Soc. DOI: 10.102 l/ja9054977.
Yokoyama, A.; Suzuki, H.; Kubota, Y.; Ohuchi, K.; Higashimura, H.; Yokozawa, T. J. Am. Chem. Soc. 2007, 129, 7236-7237.
Doubina, N.; Ho, A., Jen, A. K.-Y.; Luscombe, C. K. Macromolecules DOI: 10.1021/ma901410k.
Senkovskyy, V.; Khanduyeva, N.; Komber, H.; Oertel, U.; Stamm, M.; Kuckling, D.; Kiriy, A. J. Am. Chem. Soc. 2007, 129, 6626-6632.
Van Soolingen, J. Nickel-Catalysed Cyanation of Aryl Halides; Utrecht, 1999.
Meyer, G.; Rollin, Y.; Périchon, J. J. Organomet. Chem. 1987, 33, 263-267.
Chatt, J.; Shaw, B. L. J. Chem. Soc. 1960, 1718-1729.
Loewe, R. S.; Ewbank, P. C.; Liu, J.; Zhai, L.; McCullough, R. D. Macromolecules 2001, 34, 4324-4333.
Khanduyeva, N.; Senkovskyy, V.; Beryozkina, T.; Horecha, M.; Stamm, M.; Uhrich, C.; Riede, M.; Leo, K.; Kiriy, A. J. Am. Chem. Soc. 2009, 131, 153-161.
Khanduyeva, N.; Senkovskyy, V.; Beryozkina, T.; Bocharova, V.; Simon, F.; Nitschke, M.; Stamm, M.; Grötzschel, R.; Kiriy, A. Macromolecules 2008, 41, 7383-7389.
Koeckelberghs, G.; Vangheluwe, M.; Samyn, C.; Persoons, A.; Verbiest, T. Macromolecules 2005, 38, 5554-5559.
Vandeleene, S.; Van denBergh, K.; Verbiest, T.; Koeckelberghs, G. Macromolecules 2008, 41, 5123-5131.
Miyakoshi, R.; Yokoyama, A.; Shimono, K.; Yokozawa, T. J. Am. Chem. Soc. 2006, 128, 16012-16013.
Koeckelberghs, G.; Vangheluwe, M.; Van Doorsselaere, K.; Robijns, E.; Persoons, A.; Verbiest, T. Macromol. Rapid Commun. 2006, 27, 1920-1925.
Since 1H NMR spectroscopy indicates that no deprotection of the functional groups occurs during the polymerization, the deprotection, as observed in the MALDI-ToF spectra, must originate from the ionization during the MALDI-ToF experiment and not from the polymerization itself.
Crabtree, R. H. In The Organometallic Chemistry of the Transition Metals, 3rd ed.; John Wiley & Sons: New York, 2001; p 534.