Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers : synthesis by organic catalysis, thermal properties and microscopic morphology

Grancharov, Georgy; Coulembier, Olivier; Surin, Mathieu; Lazzaroni, Roberto; Dubois, Philippe

doi:10.1021/ma1012336

Article (Scientific journals)

Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers : synthesis by organic catalysis, thermal properties and microscopic morphology

Grancharov, Georgy; Coulembier, Olivier; Surin, Mathieu et al.

2010 • In Macromolecules, 43 (21), p. 8957-8964

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/20.500.12907/964

DOI
10.1021/ma1012336

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

399 Dubois et al Macromolecules 2010 43 8957_8964.pdf

Author postprint (3.04 MB)

Request a copy

All documents in ORBi UMONS are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Abstract :

[en] A new approach to control the supramolecular organization of conjugated polymers is proposed, based on stereocomplex formation. It is illustrated by mixing polymer solutions of block copolymers, i.e., poly(3-hexylthiophene)-b-poly(l-lactide) and poly(3-hexylthiophene)-b-poly(d-lactide). The block copolymers were successfully synthesized via a three-step procedure including the use of metal-free organic catalysts in the ring-opening polymerization of l- and d-lactide. The thermal properties and microscopic morphology of sterecomplexed diblock copolymers show that the stereocomplexation of the polylactide blocks is able to prevent the crystallization of the regioregular poly(3-hexylthiophene) block into long-range ordered parallel fibrillar structures. Stereocomplexation is also observed when mixing poly(d-lactide) homopolymer and poly(3-hexylthiophene)-b-poly(l-lactide) block copolymer.

Disciplines :

Chemistry

Author, co-author :

Grancharov, Georgy

Coulembier, Olivier ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Surin, Mathieu ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux

Lazzaroni, Roberto ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Language :

English

Title :

Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers : synthesis by organic catalysis, thermal properties and microscopic morphology

Publication date :

15 October 2010

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society (ACS), United States - District of Columbia

Volume :

Issue :

Pages :

8957-8964

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites
S817 - Chimie des matériaux nouveaux

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publiée en ligne le 13 octobre 2010

Available on ORBi UMONS :

since 25 January 2011

Statistics

Number of views

23 (0 by UMONS)

Number of downloads

0 (0 by UMONS)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

Bibliography

McCullough, R. D. Adv. Mater. 1998, 10, 93-116
Schilinsky, P.; Asawapirom, U.; Scherf, U.; Biele, M.; Brabec, C. Chem. Mater. 2005, 17, 2175-2180
Osaka, I.; McCullough, R. D. Acc. Chem. Res. 2008, 41, 1202-1214
Sirringhaus, H.; Tessler, N.; Friend, R. H. Science 1998, 280, 1741-1744
Wang, G.; Swensen, J.; Moses, D.; Heeger, A. J. J. Appl. Phys. 2003, 93, 6137-6141
Sirringhaus, H. Adv. Mater. 2005, 17, 2411-2425
Panzer, M. J.; Frisbie, C. D. Adv. Funct. Mater. 2006, 16, 1051-1056
Padinger, F.; Rittberger, R. S.; Saraciftci, N. S. Adv. Funct. Mater. 2003, 13, 85-88
Li, G.; Shrotriya, V.; Huang, J.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y. Nature Mater. 2005, 4, 864-868
Kim, J. Y.; Lee, K.; Coates, N. E.; Moses, D.; Nguyen, T.; Dante, M.; Heeger, A. J. Science 2007, 317, 222-225
Heremans, P.; Cheyns, D.; Rand, B. P. Acc. Chem. Res. 2009, 42, 1740-1747
Sundararaman, A.; Victor, M.; Varughese, R.; Jakle, F. J. Am. Chem. Soc. 2005, 127, 13748-13749
Grimsdale, A. C.; Chan, K. L.; Martin, R. E.; Jokisz, P. G.; Holmes, A. B. Chem. Rev. 2009, 109, 897-1091
Sugimoto, R.; Takeda, S.; Gu, H. B.; Yoshino, K. Chem. Express 1986, 1, 635-638
Hotta, S.; Soga, M.; Sonoda, N. Synth. Met. 1988, 26, 267-279
Hotta, S.; Rughooputh, S. D. D. V.; Heeger, A. J.; Wudl, F. Macromolecules 1987, 20, 212-215
McCullough, R. D.; Lowe, R. D. J. Chem. Soc., Chem. Commun. 1992, 1, 70-72
Chen, T. A.; Rieke, R. D. J. Am. Chem. Soc. 1992, 114, 10087-10088
Loewe, R. S.; Khersonsky, S. M.; McCullough, R. D. Adv. Mater. 1999, 11, 250-253
Jeffries-EL, M.; Sauve, G.; McCullough, R. D. Adv. Mater. 2004, 16, 1017-1019
Jeffries-EL, M.; Sauve, G.; McCullough, R. D. Macromolecules 2005, 38, 10346-10352
McCullough, R. D.; Tristram-Nagle, S.; Williams, S. P.; Lowe, R. D.; Jayaraman, M. J. Am. Chem. Soc. 1993, 115, 4910-4911
Chen, T. A.; Wu, X.; Rieke, R. D. J. Am. Chem. Soc. 1995, 117, 233-244
Liu, J.; Arif, M.; Zou, J.; Khondaker, S. I.; Zhai, L. Macromolecules 2009, 42, 9390-9393
Sauve, G.; McCullough, R. D. Adv. Mater. 2007, 19, 1822-1825
Iovu, M. C.; Craley, C. R.; Jeffries-EL, M.; Krankowski, A. B.; Zhang, R.; Kowalewski, T.; McCullough, R. D. Macromolecules 2007, 40, 4733-4735
Iovu, M. C.; Jeffries-EL, M.; Sheina, E. E.; Cooper, J. R.; McCullough, R. D. Polymer 2005, 46, 8582-8586
Iovu, M. C.; Jeffries-EL, M.; Zhang, R.; Kowalewski, T.; McCullough, R. D. J. Macromol. Sci., Part A: Pure Appl. Chem. 2006, 43, 1991-2000
Dai, C.; Yen, W.; Lee, Y.; Ho, C.; Su, W. J. Am. Chem. Soc. 2007, 129, 11036-11038
Liu, J.; Sheina, E.; Kowalewski, T.; McCullough, R. D. Angew. Chem., Int. Ed. 2002, 41, 329-332
Craley, C. R.; Zhang, R.; Kowalewski, T.; McCullough, R. D.; Stefan, M. C. Macromol. Rapid Commun. 2009, 30, 11-16
Boudouris, B. W.; Frisbie, C. D.; Hillmyer, M. A. Macromolecules 2008, 41, 61-75
Botiz, I.; Darling, S. B. Macromolecules 2009, 42, 8211-8217
Ikada, Y.; Tsuji, H. Macromol. Rapid Commun. 2000, 21, 117-132
Tsuji, H. In Polyesters 3; Doi, Y.,; Steinbuchel, A., Eds.; Wiley-VCH: Weinheim, 2002; Vol. 4, p 129.
Pachence, J.; Kohn, J. In Principle of Tissue Engineering, 2 nd ed.; Lanza, R.; Langer, R.; Vacanti, J., Eds.; Academic Press: San Diego, 2000; p 263.
Ma, P. Mater. Today 2004, 7, 30-40
Xiang, Z.; Sarazin, P.; Favis, B. D. Biomacromolecules 2009, 10, 2053-2066
Auras, R.; Harte, B.; Selke, S. Macromol. Biosci. 2004, 4, 835-864
Ikada, Y.; Jamshidi, K.; Tsuji, H.; Hyon, S.-H. Macromolecules 1987, 20, 904-906
Tsuji, H. Macromol. Biosci. 2005, 5, 569-597
Okihara, T.; Tsuji, M.; Kawaguchi, A.; Katayama, K.-I.; Tsuji, H.; Hyon, S.-H.; Ikada, Y. J. Macromol. Sci., Part B: Phys. 1991, 30, 119-140
Brizzolara, D.; Cantow, H.-J.; Diederichs, K.; Keller, E.; Domb, A. J. Macromolecules 1996, 29, 191-197
Dowe, A. P. Chem. Commun. 2008, 48, 6446-6470
Loewe, R. S.; Ewbank, P. C.; Liu, J.; Zhai, L.; McCullough, R. D. Macromolecules 2001, 34, 4324-4333
Yokoyama, A.; Miyakoshi, R.; Yokozawa, T. Macromolecules 2004, 37, 1169-1171
Miyakoshi, R.; Yokoyama, A.; Yokozawa, T. J. Am. Chem. Soc. 2005, 127, 17542-17547
Iovu, M. C.; Sheina, E. E.; Gil, R. R.; McCullough, R. D. Macromolecules 2005, 38, 8649-8656
Parakka, J. P.; Cava, M. P. Tetrahedron 1995, 51, 2229-2242
Liu, J.; Loewe, R. S.; McCullough, R. D. Macromolecules 1999, 32, 5777-5785
Pratt, R. C.; Lohmeijer, B. G. G.; Long, D. A.; Waymouth, R. M.; Hedrick, J. L. J. Am. Chem. Soc. 2006, 128, 4556-4557
Lohmeijer, B. G. G.; Pratt, R. C.; Leibhart, F.; Logan, J. W.; Long, D. A.; Dove, A. P.; Nederberg, F.; Choi, J.; Wade, C.; Waymouth, R. M.; Hedrick, J. L. Macromolecules 2006, 39, 8574-8583
Tsuji, H.; Hyon, S.-H.; Ikada, Y. Macromolecules 1991, 24, 5651-5656
Bouapao, L.; Tsuji, H. Macromol. Chem. Phys. 2009, 210, 993-1002
Tsuji, H.; Okumura, A. Macromolecules 2009, 42, 7263-7266
Sarasua, J.-R.; Prud'homme, R. E.; Wisniewsky, M.; Le Borgne, A.; Spassky, N. Macromolecules 1998, 31, 3895-3905
Tsuji, H.; Horii, F.; Nakagawa, M.; Ikada, Y.; Odani, H.; Kitamaru, R. Macromolecules 1992, 25, 4114-4118
Prosa, T. J.; Winokur, M. J.; Moulton, J.; Smith, P.; Heeger, A. J. Macromolecules 1992, 25, 4364-4372
Sugiyama, K.; Kojima, T.; Fukuda, H.; Yashiro, H.; Matsuura, T.; Shimoyama, Y. Thin Solid Films 2008, 516, 2691-2694
Zhang, R.; Li, B.; Iovu, M. C.; Jeffries-EL, M.; Sauve, G.; Cooper, J.; Jia, S.; Tristram-Nagle, S.; Smilgies, D. M.; Lambeth, D. N.; McCullough, R. D.; Kowalewski, T. J. Am. Chem. Soc. 2006, 128, 3480-3481
Surin, M.; Coulembier, O.; Tran, K.; De Winter, J.; Leclere, P.; Gerbaux, P.; Lazzaroni, R.; Dubois, P. Org. Electron. 2010, 11, 767-774