Heeger, A.J., Semiconducting polymers: the third generation. Chem. Soc. Rev. 39 (2010), 2354–2371.
Grimsdale, A.C., Leok Chan, K., Martin, R.E., Jokisz, P.G., Holmes, A.B., Synthesis of light-emitting conjugated polymers for applications in electroluminescent devices. Chem. Rev. 109 (2009), 897–1091.
Wang, C., Dong, H., Hu, W., Liu, Y., Zhu, D., Semiconducting π-Conjugated systems in field-effect transistors: a material odyssey of organic electronics. Chem. Rev. 112 (2012), 2208–2267.
Guo, X., Baumgarten, M., Müllen, K., Designing π-conjugated polymers for organic electronics. Prog. Polym. Sci. 38 (2013), 1832–1908.
Marrocchi, A., Lanari, D., Facchetti, A., Vaccaro, L., Poly(3-hexylthiophene): synthetic methodologies and properties in bulk heterojunction solar cells. Energy Environ. Sci. 5 (2012), 8457–8474.
Kleinschmidt, A.T., Root, S.E., Lipomi, D.J., Poly(3-hexylthiophene) (P3HT): fruit fly or outlier in organic solar cell research?. J. Mater. Chem. A Mater. Energy Sustain. 5 (2017), 11396–11400.
Chevrier, M., Di Ciuccio, R., Coulembier, O., Dubois, P., Richeter, S., Mehdi, A., Clément, S., Functionalization of P3HT-based hybrid materials for photovoltaic applications. Chauhan, B.P., (eds.) NOvel Nanoscale Hybrid Materials, 2018, John Wiley & Sons, Hoboken, NJ.
Wadsworth, A., Hamid, Z., Bidwell, M., Ashraf, R.S., Khan, J.I., Anjum, D.H., Cendra, C., Yan, J., Rezasoltani, E., Guilbert, A.A.Y., Azzouzi, M., Gasparini, N., Bannock, J.H., Baran, D., Wu, H., de Mello, J.C., Brabec, C.J., Salleo, A., Nelson, J., Laquai, F., McCulloch, I., Progress in poly (3-hexylthiophene) organic solar cells and the influence of its molecular weight on device performance. Adv. Energy Mater., 8, 2018, 1801001.
Yokozawa, T., Nanashima, Y., Kohno, H., Suzuki, R., Nojima, M., Ohta, Y., Catalyst-transfer condensation polymerization for precision synthesis of π-conjugated polymers. Pure Appl. Chem., 2012, 573.
Agbolaghi, S., Zenoozi, S., A comprehensive review on poly(3-alkylthiophene)-based crystalline structures, protocols and electronic applications. Org. Electron. 51 (2017), 362–403.
Koch, F.P.V., Rivnay, J., Foster, S., Müller, C., Downing, J.M., Buchaca-Domingo, E., Westacott, P., Yu, L., Yuan, M., Baklar, M., Fei, Z., Luscombe, C., McLachlan, M.A., Heeney, M., Rumbles, G., Silva, C., Salleo, A., Nelson, J., Smith, P., Stingelin, N., The impact of molecular weight on microstructure and charge transport in semicrystalline polymer semiconductors–poly(3-hexylthiophene), a model study. Prog. Polym. Sci. 38 (2013), 1978–1989.
Bates, F.S., Fredrickson, G.H., Block copolymer thermodynamics: theory and experiment. Annu. Rev. Phys. Chem. 41 (1990), 525–557.
Liu, J., Sheina, E., Kowalewski, T., McCullough, R.D., Tuning the electrical conductivity and self-assembly of regioregular polythiophene by block copolymerization: nanowire morphologies in new Di- and triblock copolymers. Angew. Chem. Int. Ed. 41 (2002), 329–332.
Kaul, E., Senkovskyy, V., Tkachov, R., Bocharova, V., Komber, H., Stamm, M., Kiriy, A., Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)−polystyrene block copolymer therefrom. Macromolecules 43 (2010), 77–81.
Britze, A., Möllmann, V., Grundmeier, G., Luftmann, H., Kuckling, D., Synthesis of blockcopolymers P3HT-b-PS using a combination of Grignard-metathesis and nitroxide-mediated radical polymerization. Macromol. Chem. Phys. 212 (2011), 679–690.
Pessoni, L., De Winter, J., Surin, M., Hergué, N., Delbosc, N., Lazzaroni, R., Dubois, P., Gerbaux, P., Coulembier, O., Synthesis of polyphthalaldehyde-based block copolymers: utilization of a thermo-sacrificial segment for an easy access to fine-tuned poly(3-hexylthiophene) nanostructured films. Macromolecules 49 (2016), 3001–3008.
Moon, H.C., Anthonysamy, A., Kim, J.K., Hirao, A., Facile synthetic route for well-defined poly(3-hexylthiophene)-block-poly(methyl methacrylate) copolymer by anionic coupling reaction. Macromolecules 44 (2011), 1894–1899.
Gilroy, J.B., Lunn, D.J., Patra, S.K., Whittell, G.R., Winnik, M.A., Manners, I., Fiber-like micelles via the crystallization-driven solution self-assembly of poly(3-hexylthiophene)-block-Poly(methyl methacrylate) copolymers. Macromolecules 45 (2012), 5806–5815.
Ji, E., Pellerin, V., Rubatat, L., Grelet, E., Bousquet, A., Billon, L., Self-assembly of Ionizable “clicked” P3HT-b-PMMA copolymers: ionic bonding group/counterion effects on morphology. Macromolecules 50 (2017), 235–243.
Lohwasser, R.H., Thelakkat, M., Synthesis of amphiphilic rod–coil P3HT-b-P4VP carrying a long conjugated block using NMRP and click chemistry. Macromolecules 45 (2012), 3070–3077.
Gernigon, V., Lévêque, P., Richard, F., Leclerc, N., Brochon, C., Braun, C.H., Ludwigs, S., Anokhin, D.V., Ivanov, D.A., Hadziioannou, G., Heiser, T., Microstructure and optoelectronic properties of P3HT-b-P4VP/PCBM blends: impact of PCBM on the copolymer self-assembly. Macromolecules 46 (2013), 8824–8831.
Surin, M., Coulembier, O., Tran, K., Winter, J.D., Leclère, P., Gerbaux, P., Lazzaroni, R., Dubois, P., Regioregular poly(3-hexylthiophene)-poly(ε-caprolactone) block copolymers: Controlled synthesis, microscopic morphology, and charge transport properties. Org. Electron. 11 (2010), 767–774.
Grancharov, G., Coulembier, O., Surin, M., Lazzaroni, R., Dubois, P., Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers: synthesis by organic catalysis, thermal properties, and microscopic morphology. Macromolecules 43 (2010), 8957–8964.
Tsuchiya, K., Ando, K., Shimomura, T., Ogino, K., Synthesis and characterization of poly(3-hexylthiophene)-block-poly(dimethylsiloxane) for photovoltaic application. Polymer 92 (2016), 125–132.
Reichstein, P.M., Gödrich, S., Papastavrou, G., Thelakkat, M., Influence of composition of amphiphilic double-crystalline P3HT-b-PEG block copolymers on structure formation in aqueous solution. Macromolecules 49 (2016), 5484–5493.
Erothu, H., Sohdi, A.A., Kumar, A.C., Sutherland, A.J., Dagron-Lartigau, C., Allal, A., Hiorns, R.C., Topham, P.D., Facile synthesis of poly(3-hexylthiophene)-block-poly(ethylene oxide) copolymers via Steglich esterification. Polym. Chem. 4 (2013), 3652–3655.
Kang, S., Ono, R.J., Bielawski, C.W., Synthesis of poly(3-hexylthiophene)-block-poly(ethylene)-block-poly(3-hexylthiophene) via a combination of ring-opening olefin metathesis polymerization and grignard metathesis polymerization. J. Polym. Sci. A Polym. Chem. 51 (2013), 3810–3817.
Brazard, J., Ono, R.J., Bielawski, C.W., Barbara, P.F., Vanden Bout, D.A., Mimicking conjugated polymer thin-film photophysics with a well-defined triblock copolymer in solution. J. Phys. Chem. B 117 (2013), 4170–4176.
Peng, R., Pang, B., Hu, D., Chen, M., Zhang, G., Wang, X., Lu, H., Cho, K., Qiu, L., An ABA triblock copolymer strategy for intrinsically stretchable semiconductors, J. Mater. Chem. C 3 (2015), 3599–3606.
Babudri, F., Farinola, G.M., Naso, F., Ragni, R., Fluorinated organic materials for electronic and optoelectronic applications: the role of the fluorine atom. Chem. Commun., 2007, 1003–1022.
Clément, S., Meyer, F., De Winter, J., Coulembier, O., Vande Velde, C.M.L., Zeller, M., Gerbaux, P., Balandier, J.-Y., Sergeyev, S., Lazzaroni, R., Geerts, Y., Dubois, P., Synthesis and supramolecular organization of regioregular polythiophene block oligomers. J. Org. Chem. 75 (2010), 1561–1568.
Voet, V.S.D., ten Brinke, G., Loos, K., Well-defined copolymers based on poly(vinylidene fluoride): from preparation and phase separation to application. J. Polym. Sci. A Polym. Chem. 52 (2014), 2861–2877.
Meyer, F., Fluorinated conjugated polymers in organic bulk heterojunction photovoltaic solar cells. Prog. Polym. Sci. 47 (2015), 70–91.
Liu, J., Haynes, D., Balliet, C., Zhang, R., Kowalewski, T., McCullough, R.D., Self encapsulated poly(3-hexylthiophene)-poly(fluorinated alkyl methacrylate) rod-coil block copolymers with high field effect mobilities on bare SiO2. Adv. Funct. Mater. 22 (2012), 1024–1032.
Lim, B., Jo, J., Na, S.-I., Kim, J., Kim, S.-S., Kim, D.-Y., A morphology controller for high-efficiency bulk-heterojunction polymer solar cells. J. Mater. Chem. 20 (2010), 10919–10923.
Kim, J.S., Lee, Y., Lee, J.H., Park, J.H., Kim, J.K., Cho, K., High-efficiency organic solar cells based on end-functional-goup-modified poly(3-hexylthiophene). Adv. Mater. 22 (2010), 1355–1360.
Jia, Z., Xu, G., Li, Q., Zhang, Y., Liu, B., Pan, Y., Wang, X., Wang, T., Li, F., Boosting the efficiency and stability of polymer solar cells using poly(3-hexylthiophene)-based all-conjugated diblock copolymers containing pentafluorophenyl groups. J. Mater. Sci. Mater. Electron. 29 (2018), 10337–10345.
Zhang, Y., Tajima, K., Hirota, K., Hashimoto, K., Synthesis of all-conjugated diblock copolymers by quasi-living polymerization and observation of their microphase separation. J. Am. Chem. Soc. 130 (2008), 7812–7813.
Beckmann, U., Hägele, G., Frank, W., Square-planar 2-toluenido(triphenylphosphane)nickel(ii) complexes containing bidentate N,O ligands: an example of planar chirality. Eur. J. Inorg. Chem. 2010 (2010), 1670–1678.
Park, N.H., Teverovskiy, G., Buchwald, S.L., Development of an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates. Org. Lett. 16 (2014), 220–223.
Lopez, G., Guerre, M., Schmidt, J., Talmon, Y., Ladmiral, V., Habas, J.-P., Améduri, B., An amphiphilic PEG-b-PFPE-b-PEG triblock copolymer: synthesis by CuAAC click chemistry and self-assembly in water. Polym. Chem. 7 (2016), 402–409.
Lopez, G., Améduri, B., Habas, J.-P., A perfluoropolyether-based elastomers library with on-demand thermorheological features. Eur. Polym. J. 95 (2017), 207–215.
Chevrier, M., Richeter, S., Coulembier, O., Surin, M., Mehdi, A., Lazzaroni, R., Evans, R.C., Dubois, P., Clément, S., Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with π-extended porphyrins. Chem. Commun. 52 (2016), 171–174.
Boon, F., Desbief, S., Cutaia, L., Douhéret, O., Minoia, A., Ruelle, B., Clément, S., Coulembier, O., Cornil, J., Dubois, P., Lazzaroni, R., Synthesis and characterization of nanocomposites based on functional regioregular poly(3-hexylthiophene) and multiwall carbon nanotubes. Macromol. Rapid Commun. 31 (2010), 1427–1434.
De Winter, J., Deshayes, G., Boon, F., Coulembier, O., Dubois, P., Gerbaux, P., MALDI-ToF analysis of polythiophene: use of trans-2-[3-(4-t-butyl-phenyl)-2-methyl- 2-propenylidene]malononitrile—DCTB—as matrix. J. Mass Spectrom. 46 (2011), 237–246.
Bronstein, H.A., Luscombe, C.K., Externally initiated regioregular P3HT with controlled molecular weight and narrow polydispersity. J. Am. Chem. Soc. 131 (2009), 12894–12895.
Schiefer, D., Hanselmann, R., Sommer, M., All-conjugated P3HT donor PCDTBT acceptor graft copolymers synthesised via a grafting through approach. Polym. Chem. 8 (2017), 4368–4377.
Li, Z., Ono, R.J., Wu, Z.-Q., Bielawski, C.W., Synthesis and self-assembly of poly(3-hexylthiophene)-block-poly(acrylic acid). Chem. Commun. 47 (2011), 197–199.
Liu, J., Loewe, R.S., McCullough, R.D., Employing MALDI-MS on poly(alkylthiophenes): analysis of molecular weights, molecular weight distributions, end-group structures, and end-group modifications. Macromolecules 32 (1999), 5777–5785.
Rodrigues, A., Castro, M.C.R., Farinha, A.S.F., Oliveira, M., Tomé, J.P.C., Machado, A.V., Raposo, M.M.M., Hilliou, L., Bernardo, G., Thermal stability of P3HT and P3HT:PCBM blends in the molten state. Polymer Test. 32 (2013), 1192–1201.
Ramani, R., Srivastava, J., Alam, S., Application of model-free kinetics to the thermal and thermo-oxidative degradation of poly(3-hexyl thiophene). Thermochim. Acta 499 (2010), 34–39.
Kohn, P., Huettner, S., Komber, H., Senkovskyy, V., Tkachov, R., Kiriy, A., Friend, R.H., Steiner, U., Huck, W.T.S., Sommer, J.-U., Sommer, M., On the role of single regiodefects and polydispersity in regioregular poly(3-hexylthiophene): Defect distribution, synthesis of defect-free chains, and a simple model for the determination of crystallinity. J. Am. Chem. Soc. 134 (2012), 4790–4805.
Yuan, Y., Zhang, J., Sun, J., Hu, J., Zhang, T., Duan, Y., Polymorphism and structural transition around 54 °C in regioregular poly(3-hexylthiophene) with high crystallinity as revealed by infrared spectroscopy. Macromolecules 44 (2011), 9341–9350.
Priola, A., Bongiovanni, R., Malucelli, G., Pollicino, A., Tonelli, C., Simeone, G., UV-curable systems containing perfluoropolyether structures: synthesis and characterisation. Macromol. Chem. Phys. 198 (2003), 1893–1907.
Oosterbaan, W.D., Vrindts, V., Berson, S., Guillerez, S., Douhéret, O., Ruttens, B., D'Haen, J., Adriaensens, P., Manca, J., Lutsen, L., Vanderzande, D., Efficient formation, isolation and characterization of poly(3-alkylthiophene) nanofibres: probing order as a function of side-chain length. J. Mater. Chem. 19 (2009), 5424–5435.
Sundberg, M., Inganäs, O., Stafström, S., Gustafsson, G., Sjögren, B., Optical absorption of poly(3-alkylthiophenes) at low temperatures. Solid State Commun. 71 (1989), 435–439.
Duong, D.T., Wang, C., Antono, E., Toney, M.F., Salleo, A., The chemical and structural origin of efficient p-type doping in P3HT. Org. Electron. 14 (2013), 1330–1336.
Lim, E., Peterson, K.A., Su, G.M., Chabinyc, M.L., Thermoelectric properties of poly(3-hexylthiophene) (P3HT) doped with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) by vapor-phase infiltration. Chem. Mater. 30 (2018), 998–1010.
Lin, Y.-H., Yager, K.G., Stewart, B., Verduzco, R., Lamellar and liquid crystal ordering in solvent-annealed all-conjugated block copolymers. Soft Matter 10 (2014), 3817–3825.
Yang, H., Shin, T.J., Yang, L., Cho, K., Ryu, C.Y., Bao, Z., Effect of mesoscale crystalline structure on the field-effect mobility of regioregular poly(3-hexyl thiophene) in thin-film transistors. Adv. Funct. Mater. 15 (2005), 671–676.
Surin, M., Leclère, P., Lazzaroni, R., Yuen, J.D., Wang, G., Moses, D., Heeger, A.J., Cho, S., Lee, K., Relationship between the microscopic morphology and the charge transport properties in poly(3-hexylthiophene) field-effect transistors. J. Appl. Phys., 100, 2006, 033712.
Berson, S., De Bettignies, R., Bailly, S., Guillerez, S., Poly(3-hexylthiophene) fibers for photovoltaic applications. Adv. Funct. Mater. 17 (2007), 1377–1384.
Usluer, Ö., Abbas, M., Wantz, G., Vignau, L., Hirsch, L., Grana, E., Brochon, C., Cloutet, E., Hadziioannou, G., Metal residues in semiconducting polymers: impact on the performance of organic electronic devices. ACS Macro Lett. 3 (2014), 1134–1138.
