Vibronic effect and influence of aggregation on the photophysics of graphene quantum dots.

Liu, Thomas; {"lastName":"Tonnelé", "firstNames":"Claire","affiliations":["CMN, Université MONS, Belgium"],"ids":["SC:36469058500""OR:0000-0003-0791-8239"]}; Zhao, Shen; {"lastName":"Rondin", "firstNames":"Loïc","affiliations":["Université Paris-Saclay, ENS Paris-Saclay, CentraleSupélec, CNRS, LuMIn, Orsay, France. lauret@ens-paris-saclay.fr"],"ids":["SC:36437558800""OR:0000-0002-4833-2886"]}; Elias, Christine; Medina-Lopez, Daniel; Okuno, Hanako; {"lastName":"Narita", "firstNames":"Akimitsu","affiliations":["Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany"],"ids":["SC:55169529600""OR:0000-0002-3625-522X"]}; Chassagneux, Yannick; {"lastName":"Voisin", "firstNames":"Christophe","affiliations":["LPENS, PSL, CNRS, Université de Paris, Sorbonne Université, 75005 Paris, France"],"ids":["SC:57205273245""OR:0000-0003-3175-9311"]}; {"lastName":"Campidelli", "firstNames":"Stéphane","affiliations":["Université Paris-Saclay, CEA, CNRS, NIMBE, LICSEN, 91191, Gif-sur-Yvette, France"],"ids":["SC:12762946600""OR:0000-0001-6060-4891"]}; {"lastName":"Beljonne", "firstNames":"David","affiliations":["Université de Mons - UMONS"],"ids":["SC:7004588449""OR:0000-0001-5082-9990"]}; {"lastName":"Lauret", "firstNames":"Jean-Sébastien","affiliations":["Université Paris-Saclay, ENS Paris-Saclay, CentraleSupélec, CNRS, LuMIn, Orsay, France. lauret@ens-paris-saclay.fr"],"ids":["SC:15048347800""OR:0000-0003-1309-4977"]}

doi:10.1039/d1nr08279e

Article (Scientific journals)

Vibronic effect and influence of aggregation on the photophysics of graphene quantum dots.

Liu, Thomas; {"lastName":"Tonnelé", "firstNames":"Claire","affiliations":["CMN, Université MONS, Belgium"],"ids":["SC:36469058500""OR:0000-0003-0791-8239"]}; Zhao, Shen et al.

2022 • In Nanoscale, 14 (10), p. 3826 - 3833

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/20.500.12907/44673

DOI
10.1039/d1nr08279e

PubMed
35194627

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

cmn1084.pdf

Author postprint (2.33 MB)

Download

All documents in ORBi UMONS are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

Bio-imaging; Emission process; Nano-objects; Optical study; Photophysical properties; Photophysics; Photovoltaics; Quantum light emitters; Single molecule level; Vibronic effect; Materials Science (all); General Materials Science

Abstract :

[en] Graphene quantum dots, atomically precise nanopieces of graphene, are promising nano-objects with potential applications in various domains such as photovoltaics, quantum light emitters and bio-imaging. Despite their interesting prospects, precise reports on their photophysical properties remain scarce. Here, we report on a study of the photophysics of C96H24(C12H25) graphene quantum dots. A combination of optical studies down to the single molecule level with advanced molecular modelling demonstrates the importance of coupling to vibrations in the emission process. Optical fingerprints for H-like aggregates are identified. Our combined experimental-theoretical investigations provide a comprehensive description of the light absorption and emission properties of nanographenes, which not only represents an essential step towards precise control of sample production but also paves the way for new exciting physics focused on twisted graphenoids.

Disciplines :

Chemistry

Author, co-author :

Liu, Thomas; Université Paris-Saclay, ENS Paris-Saclay, CentraleSupélec, CNRS, LuMIn, Orsay, France. lauret@ens-paris-saclay.fr

{"lastName":"Tonnelé", "firstNames":"Claire","affiliations":["CMN, Université MONS, Belgium"],"ids":["SC:36469058500""OR:0000-0003-0791-8239"]}

Zhao, Shen; Université Paris-Saclay, ENS Paris-Saclay, CentraleSupélec, CNRS, LuMIn, Orsay, France. lauret@ens-paris-saclay.fr

{"lastName":"Rondin", "firstNames":"Loïc","affiliations":["Université Paris-Saclay, ENS Paris-Saclay, CentraleSupélec, CNRS, LuMIn, Orsay, France. lauret@ens-paris-saclay.fr"],"ids":["SC:36437558800""OR:0000-0002-4833-2886"]}

Elias, Christine; Université Paris-Saclay, ENS Paris-Saclay, CentraleSupélec, CNRS, LuMIn, Orsay, France. lauret@ens-paris-saclay.fr

Medina-Lopez, Daniel; Université Paris-Saclay, CEA, CNRS, NIMBE, LICSEN, 91191, Gif-sur-Yvette, France

Okuno, Hanako; University Grenoble Alpes, CEA INAC-MEM, F-38000 Grenoble, France

{"lastName":"Narita", "firstNames":"Akimitsu","affiliations":["Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany"],"ids":["SC:55169529600""OR:0000-0002-3625-522X"]}

Chassagneux, Yannick; LPENS, PSL, CNRS, Université de Paris, Sorbonne Université, 75005 Paris, France

{"lastName":"Voisin", "firstNames":"Christophe","affiliations":["LPENS, PSL, CNRS, Université de Paris, Sorbonne Université, 75005 Paris, France"],"ids":["SC:57205273245""OR:0000-0003-3175-9311"]}

More authors (3 more)

Language :

English

Title :

Vibronic effect and influence of aggregation on the photophysics of graphene quantum dots.

Publication date :

10 March 2022

Journal title :

Nanoscale

ISSN :

2040-3364

eISSN :

2040-3372

Publisher :

Royal Society of Chemistry, England

Volume :

Issue :

Pages :

3826 - 3833

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D1NR08279E

Research unit :

S817 - Chimie des matériaux nouveaux

Research institute :

Complexys
Matériaux

Funders :

Agence Nationale de la Recherche
Deutsche Forschungsgemeinschaft
Fonds De La Recherche Scientifique - FNRS
Fédération Wallonie-Bruxelles

Funding text :

This work was financially supported by the FLAG-ERA Grant OPERA by DFG 437130745 and ANR-19-GRF1-0002-01, by the ANR-DFG NLE Grant GRANAO, by DFG 431450789 and ANR-19-CE09-0031-01, and by a public grant overseen by the French National Research Agency (ANR) as part of the “Investissements d'Avenir” program (Labex NanoSaclay, reference: ANR-10-LABX-0035). Computational resources were provided by the Consortium des Équipements de Calcul Intensif (CÉCI), funded by the Fonds de la Recherche Scientifiques de Belgique (F.R.S.-FNRS) under Grant No. 2.5020.11, and the Tier-1 supercomputer of the Fédération Wallonie-Bruxelles. The infrastructure was funded by the Walloon Region under the grant agreement n1117545. D. B. is a FNRS Research Director.

Available on ORBi UMONS :

since 13 January 2023

Statistics

Number of views

5 (0 by UMONS)

Number of downloads

22 (0 by UMONS)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

Bibliography

K. Müllen, ACS Nano, 2014, 8, 6531-6541.
J. Wu, W. Pisula and K. Müllen, Chem. Rev., 2007, 107, 718-747.
A. Xu, G. Wang, Y. Li, H. Dong, S. Yang, P. He and G. Ding, Small, 2020, 16, 2004621.
G. M. Paterno, Q. Chen, X. Y. Wang, J. Liu, S. G. Motti, A. Petrozza, X. Feng, G. Lanzani, K. Müllen, A. Narita and F. Scotognella, Angew. Chem., Int. Ed., 2017, 56, 6753-6757.
X. Yan, X. Cui, B. Li and L. S. Li, Nano Lett., 2010, 10, 1869-1873.
M. R. Younis, G. He, J. Lin and P. Huang, Front. Chem., 2020, 8, 1-25.
L. Li, G. Wu, G. Yang, J. Peng, J. Zhao and J. J. Zhu, Nanoscale, 2013, 5, 4015-4039.
Q. Xu, Q. Zhou, Z. Hua, Q. Xue, C. Zhang, X. Wang, D. Pan and M. Xiao, ACS Nano, 2013, 7, 10654-10661.
Z. Tomovic, M. D. Watson and K. Müllen, Angew. Chem., Int. Ed., 2004, 43, 755-758.
X. Yan, X. Cui and L. S. Li, J. Am. Chem. Soc., 2010, 132, 5944-5945.
R. Rieger and K. Müllen, J. Phys. Org. Chem., 2010, 23, 315-325.
M. Imran, C. M. Wehrmann and M. S. Chen, J. Am. Chem. Soc., 2020, 142, 38-43.
F. Lombardi, A. Lodi, J. Ma, J. Liu, M. Slota, A. Narita, W. K. Myers, K. Müllen, X. Feng and L. Bogani, Science, 2019, 366, 1107-1110.
S. Zhao, J. Lavie, L. Rondin, L. Orcin-Chaix, C. Diederichs, P. Roussignol, Y. Chassagneux, C. Voisin, K. Müllen, A. Narita, S. Campidelli and J.-S. Lauret, Nat. Commun., 2018, 9, 3470.
M. Semeniuk, Z. Yi, V. Poursorkhabi, J. Tjong, S. Jaffer, Z.-H. Lu and M. Sain, ACS Nano, 2019, 13, 6224-6255.
M. L. Mueller, X. Yan, J. A. McGuire and L.-S. Li, Nano Lett., 2010, 10, 2679-2682.
S. Zhu, L. Wang, B. Li, Y. Song, X. Zhao, G. Zhang, S. Zhang, S. Lu, J. Zhang, H. Wang, H. Sun and B. Yang, Carbon, 2014, 77, 462-472.
H. Riesen, C. Wiebeler and S. Schumacher, J. Phys. Chem. A, 2014, 118, 5189-5195.
Y. Li, H. Shu, S. Wang and J. Wang, J. Phys. Chem. C, 2015, 119, 4983-4989.
V. S. Iyer, M. Wehmeier, J. D. Brand, M. A. Keegstra and K. Müllen, Angew. Chem., Int. Ed. Engl., 1997, 36, 1604-1607.
M. Wehmeier, M. Wagner and K. Müllen, Chemistry, 2001, 7, 2197-2205.
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, G. A. Petersson, H. Nakatsuji, X. Li, M. Caricato, A. V. Marenich, J. Bloino, B. G. Janesko, R. Gomperts, B. Mennucci, H. P. Hratchian, J. V. Ortiz, A. F. Izmaylov, J. L. Sonnenberg, D. Williams-Young, F. Ding, F. Lipparini, F. Egidi, J. Goings, B. Peng, A. Petrone, T. Henderson, D. Ranasinghe, V. G. Zakrzewski, J. Gao, N. Rega, G. Zheng, W. Liang, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, K. Throssell, J. A. Montgomery Jr., J. E. Peralta, F. Ogliaro, M. J. Bearpark, J. J. Heyd, E. N. Brothers, K. N. Kudin, V. N. Staroverov, T. A. Keith, R. Kobayashi, J. Normand, K. Raghavachari, A. P. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, J. M. Millam, M. Klene, C. Adamo, R. Cammi, J. W. Ochterski, R. L. Martin, K. Morokuma, O. Farkas, J. B. Foresman and D. J. Fox, Gaussian 16, Revision B.01, 2016.
J. C. Phillips, R. Braun, W. Wang, J. Gumbart, E. Tajkhorshid, E. Villa, C. Chipot, R. D. Skeel, L. Kalé and K. Schulten, J. Comput. Chem., 2005, 26, 1781-1802.
U. Essmann, L. Perera, M. L. Berkowitz, T. Darden, H. Lee and L. G. Pedersen, J. Chem. Phys., 1995, 103, 8577-8593.
J. Wang, R. M. Wolf, J. W. Caldwell, P. A. Kollman and D. A. Case, J. Comput. Chem., 2004, 25, 1157-1174.
C. Cocchi, D. Prezzi, A. Ruini, M. J. Caldas and E. Molinari, J. Phys. Chem. A, 2014, 118, 6507-6513.
F. Terenziani, A. Painelli, C. Katan, M. Charlot and M. Blanchard-Desce, J. Am. Chem. Soc., 2006, 128, 15742-15755.
F. Terenziani, C. Sissa and A. Painelli, J. Phys. Chem. B, 2008, 112, 5079-5087.
W. Verbouwe, M. Van der Auweraer, F. C. De Schryver, J. J. Piet and J. M. Warman, J. Am. Chem. Soc., 1998, 120, 1319-1324.
B. Dereka, D. Svechkarev, A. Rosspeintner, A. Aster, M. Lunzer, R. Liska, A. M. Mohs and E. Vauthey, Nat. Commun., 2020, 11, 1925.
X. Feng, V. Marcon, W. Pisula, M. Ryan Hansen, J. Kirkpatrick, F. Grozema, D. Andrienko, K. Kremer and K. Müllen, Nat. Mater., 2009, 8, 12.
J. A. McGuire, Phys. Status Solidi RRL, 2016, 10, 91-101.
K. Zhang, J. Liu, Y. Zhang, J. Fan, C.-K. Wang and L. Lin, J. Phys. Chem. C, 2019, 123, 24705-24713.