Anti-corrosion; Zinc alloys coated steel; Zn–Al hydrotalcite conversion films; Al hydrotalcite; Alloy coated steel; Anti-corrosion property; Conversion film; Hot dip galvanized steels; Hydrotalcites; Zinc alloy coated steel; Zn-Al coated steel; Zn–al hydrotalcite conversion film; Chemical Engineering (all); Surfaces, Coatings and Films; Organic Chemistry; Materials Chemistry; General Chemical Engineering
Abstract :
[en] The Zn-Al-CO32− hydrotalcite (HT) conversion film was developed on hot-dip galvanized steel (HDG), Zn–Al coated steel (ZA), and Zn-Al-Mg coated steel (ZAM) substrates by “in situ” growth process for Al3+/Zn2+ ratio of 5/3 at pH 12. The characteristics of all the Zn–Al HT film-coated samples before and after exposure to 0.1 M NaCl for 24 h were investigated by means of Fourier-transform infrared (FT-IR), X-Ray Diffraction (XRD), electron microscopy/energy dispersive X-ray spectroscopy SEM/EDS, and X-ray photoelectron spectroscopy (XPS). The corrosion properties of all the samples were studied by open circuit potential measurements (OCP), polarization curves, and electrochemical impedance spectroscopy (EIS). The electrochemical tests indicated that the HT film-coated can significantly restrain the corrosion of the HDG, ZA, and ZAM substrates but this efficiency was depending on the alloying compounds of the sacrificial layer. The inhibitive effect of HT film-coated on all the corrosion substrates was discussed in detail.
Research center :
CRIM - Ingénierie des matériaux
Disciplines :
Materials science & engineering
Author, co-author :
Pham, Thu Thuy; Institute for Tropical Technology, Vietnam Academy of Science and Technology, Hanoi, Viet Nam ; Université de Mons, Materials Science Department, Mons, Belgium
Nguyen, Thuy Duong; Institute for Tropical Technology, Vietnam Academy of Science and Technology, Hanoi, Viet Nam
Nguyen, Anh Son; Institute for Tropical Technology, Vietnam Academy of Science and Technology, Hanoi, Viet Nam
Gonon, Maurice; Université de Mons, Materials Science Department, Mons, Belgium
Noirfalise, Xavier ; Université de Mons - UMONS > Unités externes > Materia Nova ASBL ; Materia Nova, Parc Initialis, Mons, Belgium
Paint, Yoann ; Université de Mons - UMONS ; Materia Nova, Parc Initialis, Mons, Belgium
To, Thi Xuan Hang; Institute for Tropical Technology, Vietnam Academy of Science and Technology, Hanoi, Viet Nam ; Graduate University of Science and Technology, Vietnam Academy of Science and Technology, Hanoi, Viet Nam
Olivier, Marie-Georges ; Université de Mons - UMONS > Faculté Polytechnique > Service de Science des Matériaux ; Université de Mons - UMONS > Faculté Polytechnique > Science des Matériaux ; Université de Mons - UMONS ; Materia Nova, Parc Initialis, Mons, Belgium
Language :
English
Title :
Study of the formation and anti-corrosion properties of Zn–Al hydrotalcite conversion films grown “in situ” on different zinc alloys coated steel
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Name of the research project :
4617 - ARES PRD 2020 - Vietnam - Renforcement de l'expertise du centre de compétences en protection contre la corrosion et en éléctrochimie - Fédération Wallonie Bruxelles
Funders :
ARES - Académie de Recherche et d'Enseignement Supérieur
Funding text :
This project attributed a PhD grant to Pham Thu Thuy for coming in Belgium for a part of her research (six months per year).The Université of Mons has received a financial funding coming from the ARES (Belgium) in the framework of the PRD Project “RENFORCEMENT DE L'EXPERTISE ENVIRONNEMENTALE DU CENTRE DE COMPÉTENCES EN PROTECTION CONTRE LA CORROSION ET EN ÉLECTROCHIMIE”, Institute of Tropical Technology, Vietnam”, 2020–2025.
Meng, Y., Liu, L., Zhang, D., Dong, C., Yan, Y., Volinsky, A.A., Wang, L.N., Initial formation of corrosion products on pure zinc in saline solution. Bioact. Mater 4 (2019), 87–96.
Rodriguez, J., Chenoy, L., Roobroeck, A., Godet, S., Olivier, M.G., Effect of the electrolyte pH on the corrosion mechanisms of zn-mg coated steel. Corros. Sci. 108 (2016), 47–59.
Andreatta, F., Rodriguez, J., Mouanga, M., Lanzutti, A., Fedrizzi, L., Olivier, M.G., Corrosion protection by zinc-magnesium coatings on steel studied by electrochemical methods. Mater. Corros. 70 (2018), 793–801.
Persson, D., Thierry, D., LeBozec, N., Prosek, T., In situ infrared reflection spectroscopy studies of the initial atmospheric corrosion of Zn–Al–Mg coated steel. Corros. Sci. 72 (2013), 54–63.
Salgueiro Azevedo, M., Allély, C., Ogle, K., Volovitch, P., Corrosion mechanisms of Zn(Mg, Al) coated steel in accelerated tests and natural exposure: 1. The role of electrolyte composition in the nature of corrosion products and relative corrosion rate. Corros. Sci. 90 (2015), 472–481.
Thuy, D.Nguyen, To Thi Xuan, H., Nicolay, A., Paint, Y., Olivier, M.-G., Corrosion protection of carbon steel by solvent free epoxy coating containing hydrotalcites intercalated with different organic corrosion inhibitors. Prog. Org. Coat. 101 (2016), 331–341.
Nguyen, D.T., To, H.T.X., Gervasi, J., Paint, Y., Gonon, M., Olivier, M.-G., Corrosion inhibition of carbon steel by hydrotalcites modified with different organic carboxylic acids for organic coatings. Prog. Org. Coat. 124 (2018), 256–266.
Rodriguez, J., Bollen, E., Nguyen, T.D., Portier, A., Paint, Y., Olivier, M.G., Incorporation of layered double hydroxides modified with benzotriazole into an epoxy resin for the corrosion protection of zn-mg coated steel. Prog. Org. Coat., 149, 2020, 105894.
Su, Y., Qiu, S., Wei, J., Zhu, X., Zhao, H., Xue, Q., Sulfonated polyaniline assisted hierarchical assembly of graphene-LDH nanohybrid for enhanced anticorrosion performance of waterborne epoxy coatings. Chem. Eng. J., 426, 2021, 131269.
Collazo, A., Hernández, M., Nóvoa, X.R., Pérez, C., Effect of the addition of thermally activated hydrotalcite on the protective features of sol–gel coatings applied on AA2024 aluminium alloys. Electrochim. Acta 56 (2011), 7805–7814.
Álvarez, D., Collazo, A., Hernández, M., Nóvoa, X.R., Pérez, C., Characterization of hybrid sol–gel coatings doped with hydrotalcite-like compounds to improve corrosion resistance of AA2024-T3 alloys. Prog. Org. Coat. 68 (2010), 91–99.
Zhang, Y., Yu, P., Wu, J., Chen, F., Li, Y., Zhang, Y., Zuo, Y., Qi, Y., Enhancement of anticorrosion protection via inhibitor-loaded zn-AlCe-LDH nanocontainers embedded in sol–gel coatings. J. Coat. Technol. Res. 15 (2017), 303–313.
Tang, Y., Wu, F., Fang, L., Guan, T., Hu, J., Zhang, S., A comparative study and optimization of corrosion resistance of zn-Al layered double hydroxides films intercalated with different anions on AZ31 mg alloys. Surf. Coat. Technol. 358 (2019), 594–603.
Wang, F., Guo, Z., Insitu growth of durable superhydrophobic Mg–Al layered double hydroxides nanoplatelets on aluminum alloys for corrosion resistance. J. Alloys Compd. 767 (2018), 382–391.
Shi, R., Yang, P., Yin, Y., Dong, X., Li, J., Fabrication of porous microspheres and network arrays of Zn–Al hydrotalcite-like compounds on Al substrate via facile hydrothermal method. Ceram. Int. 40 (2014), 6855–6863.
Chen, H., Zhang, F., Fu, S., Duan, X., In situ microstructure control of oriented layered double hydroxide monolayer films with curved hexagonal crystals as superhydrophobic materials. Adv. Mater. 18 (2006), 3089–3093.
Iqbal, M.A., Sun, L., LaChance, A.M., Ding, H., Fedel, M., In situ growth of a CaAl-NO3–layered double hydroxide film directly on an aluminum alloy for corrosion resistance. Dalton Trans. 49 (2020), 3956–3964.
Zeng, R.-C., Liu, Z.-G., Zhang, F., Li, S.-Q., Cui, H.-Z., Han, E.-H.J.J.O.M.C.A., Corrosion of molybdate intercalated hydrotalcite coating on AZ31 Mg alloy. J. Mater. Chem. A 2 (2014), 13049–13057.
Wang, X., Li, L., Xie, Z.-H., Yu, G., Duplex coating combining layered double hydroxide and 8-quinolinol layers on mg alloy for corrosion protection. Electrochim. Acta 283 (2018), 1845–1857.
Mikhailau, A., Maltanava, H., Poznyak, S.K., Salak, A.N., Zheludkevich, M.L., Yasakau, K.A., Ferreira, M.G.S., One-step synthesis and growth mechanism of nitrate intercalated zn-Al LDH conversion coatings on zinc. Chem. Commun. 55 (2019), 6878–6881.
Bouali, A.C., Iuzviuk, M.H., Serdechnova, M., Yasakau, K.A., Wieland, D.C.F., Dovzhenko, G., Maltanava, H., Zobkalo, I.A., Ferreira, M.G.S., Zheludkevich, M.L., Zn-Al LDH growth on AA2024 and zinc and their intercalation with chloride: comparison of crystal structure and kinetics. Appl. Surf. Sci., 501, 2020, 144027.
Buchheit, R., Guan, H., Formation and characteristics of Al-zn hydrotalcite coatings on galvanized steel. J. Coat. Technol. Res. 1 (2004), 277–290.
Hoshino, K., Furuya, S., Buchheit, R.G., Effect of NO3− intercalation on corrosion resistance of conversion coated zn-Al-CO3 LDHs on electrogalvanized steel. J. Electrochem. Soc. 165 (2018), C461–C468.
Hoshino, K., Furuya, S., Buchheit, R.G., Effect of solution pH on layered double hydroxide formation on electrogalvanized steel sheets. J. Mater. Eng. Perform. 28 (2019), 2237–2244.
Pham, T.T., Nguyen, T.D., Nguyen, A.S., Paint, Y., Gonon, M., To, T.X.H., Olivier, M.-G., A comparative study of the structure and corrosion resistance of zn-Al hydrotalcite conversion layers at different Al3+/Zn2+ ratios on electrogalvanized steel. Surf. Coat. Technol., 429, 2022, 127948.
Lin, J., Hsia, C., Uan, J., Characterization of mg, Al-hydrotalcite conversion film on mg alloy and Cl− and CO32- anion-exchangeability of the film in a corrosive environment. Scr. Mater. 56 (2007), 927–930.
Lin, J., Uan, J., Formation of mg, Al-hydrotalcite conversion coating on mg alloy in aqueous HCO3−/CO32− and corresponding protection against corrosion by the coating. Corros. Sci. 51 (2009), 1181–1188.
Yu, B.-L., Lin, J.-K., Uan, J.-Y., Applications of carbonic acid solution for developing conversion coatings on mg alloy. Trans. Nonferrous Metals Soc. China 20 (2010), 1331–1339.
Chen, J., Song, Y., Shan, D., Han, E.-H., Study of the in situ growth mechanism of Mg–Al hydrotalcite conversion film on AZ31 magnesium alloy. Corros. Sci. 63 (2012), 148–158.
Chen, J., Song, Y., Shan, D., Han, E.-H., In situ growth of Mg–Al hydrotalcite conversion film on AZ31 magnesium alloy. Corros. Sci. 53 (2011), 3281–3288.
Kuang, J., Ba, Z., Li, Z., Jia, Y., Wang, Z., Fabrication of a superhydrophobic mg-mn layered double hydroxides coating on pure magnesium and its corrosion resistance. Surf. Coat. Technol. 361 (2019), 75–82.
Ahmed, A.A.A., Talib, Z.A., Bin Hussein, M.Z., Zakaria, A., Zn–Al layered double hydroxide prepared at different molar ratios: preparation, characterization, optical and dielectric properties. J. Solid State Chem. 191 (2012), 271–278.
Comparelli, R., Fanizza, E., Curri, M., Cozzoli, P., Mascolo, G., Agostiano, A., UV-induced photocatalytic degradation of azo dyes by organic-capped ZnO nanocrystals immobilized onto substrates. Appl. Catal., B 60 (2005), 1–11.
Li, Z., Chen, M., Hu, H., Zhang, Q., Tao, D., Mechanochemical synthesis of novel pt modified zn-Al-LDH for effective ciprofloxacin photodegradation. J. Solid State Chem., 290, 2020, 121594.
Gomes, C., Mir, Z., Sampaio, R., Bastos, A., Tedim, J., Maia, F., Rocha, C., Ferreira, M., Use of zn-Al-layered double hydroxide (LDH) to extend the service life of reinforced concrete. Materials (Basel), 13, 2020, 1769.
Yan, T., Xu, S., Peng, Q., Zhao, L., Zhao, X., Lei, X., Zhang, F., Self-healing of layered double hydroxide film by dissolution/recrystallization for corrosion protection of aluminum. J. Electrochem. Soc., 160, 2013, C480.
Zhang, G., Wu, L., Tang, A., Ma, Y., Song, G.-L., Zheng, D., Jiang, B., Atrens, A., Pan, F., Active corrosion protection by a smart coating based on a MgAl-layered double hydroxide on a cerium-modified plasma electrolytic oxidation coating on mg alloy AZ31. Corros. Sci. 139 (2018), 370–382.
Nguyen, T.D., Tran, B.A., Vu, K.O., Nguyen, A.S., Trinh, A.T., Pham, G.V., To, T.X.H., Phan, M.V., Phan, T.T., Corrosion protection of carbon steel using hydrotalcite/graphene oxide nanohybrid. J. Coat. Technol. Res. 16 (2018), 585–595.
Nishimura, K., Shindo, H., Kato, K., Morimoto, Y., Microstructure and corrosion behaviour of Zn–Mg–Al hot-dip galvanized steel sheet. Proceedings of the Galvatech ’98, International Conference on Zinc and Zinc Alloy Coated Steel, Chiba, Japan, September 20–23, 1998, 437–442.
Schürz, S., Luckeneder, G.H., Fleischanderl, M., Mack, P., Gsaller, H., Kneissl, A.C., Mori, G., Chemistry of corrosion products on Zn–Al–Mg alloy coated steel. Corros. Sci. 52 (2010), 3271–3279.
Nikhil, G., Ji, R., Prakash, hydrothermal synthesis of zn-mg-based layered double hydroxide coatings for the corrosion protection of copper in chloride and hydroxide media. Int. J. Miner. Metall. Mater. 28 (2021), 1991–2000.
