[en] This work aims to provide new insights into the link between the growth mechanisms of functionalized plasma polymer films (PPFs) and the substrate temperature (TS). By means of AFM-based techniques, it has been demonstrated that the mechanical behavior of the coatings is dramatically affected by TS and the precursor employed (i.e., 1-propanethiol or 1-propylamine). While propylamine-based PPFs behave as hard elastic materials regardless of TS, propanethiol-based PPFs evolve from viscous liquids to elastic solids with increasing TS. This behavior can be understood considering the glass transition temperature of PPF. For both precursors, the latter is correlated to the cross-linking density controlled through the energy density brought by positive ions to the growing film.
Disciplines :
Chemistry
Author, co-author :
Vinx, Nathan ; Université de Mons - UMONS > Administration > Service d'Appui Pédagogique
Leclère, Philippe; Laboratoire de Physique des Nanomatériaux et Energie (LPNE), Institut Matériaux, Université de Mons, Mons, Belgium
Poleunis, Claude; Bio- and Soft Matter (BSMA), Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain, Louvain-la-Neuve, Belgium
Delcorte, Arnaud; Bio- and Soft Matter (BSMA), Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain, Louvain-la-Neuve, Belgium
Mathieu, Pierre ; Université de Mons - UMONS > Faculté des Science > Service de Chimie des Interactions Plasma-Surface
Cossement, Damien ; Université de Mons - UMONS ; Materia Nova Research Center, Mons, Belgium
Snyders, Rony ; Université de Mons - UMONS > Faculté des Science > Service de Chimie des Interactions Plasma-Surface ; Materia Nova Research Center, Mons, Belgium
Thiry, Damien ; Université de Mons - UMONS > Faculté des Science > Service de Chimie des Interactions Plasma-Surface
Language :
English
Title :
The influence of the substrate temperature on the growth mechanism of amine- and thiol-based plasma polymers: A comparative study
D. Thiry, F. J. Aparicio, P. Laha, H. Terryn, R. Snyders, J. Vac. Sci. Technol. A 2014, 32, 050602.
C. Vandenabeele, M. Buddhadasa, P.-L. Girard-Lauriault, R. Snyders, Thin Solid Films 2017, 630, 100.
L. M. Watkins, A. F. Lee, J. Moir, K. Wilson, ACS Biomater. Sci. Eng. 2017, 3, 88.
R. Morent, N. De Geyter, S. Van Vlierberghe, A. Beaurain, P. Dubruel, E. Payen, Prog. Org. Coat. 2011, 70, 336.
E. Makhneva, A. Manakhov, P. Skládal, L. Zajíčková, Surf. Coat. Technol. 2016, 290, 116.
Y. W. Chan, K. S. Siow, P. Y. Ng, U. Gires, B. Yeop Majlis, Mater. Sci. Eng.: C 2016, 68, 861.
B. Joseph, N. Ninan, R. M. Visalakshan, C. Denoual, R. Bright, N. Kalarikkal, Y. Grohens, K. Vasilev, S. Thomas, Compos. Sci. Technol. 2021, 202, 108544.
D. Thiry, S. Konstantinidis, J. Cornil, R. Snyders, Thin Solid Films 2016, 606, 19.
R. Snyders, D. Hegemann, D. Thiry, O. Zabeida, J. Klemberg-Sapieha, L. Martinu, Plasma Sources Sci. Technol. 2023, 32, 074001.
H. Biederman, Plasma Polymer Films, World Scientific, Singapore, 2004.
N. Inagaki, Plasma Surface Modification and Plasma Polymerization, CRC Press, Boca Raton, USA, 1996.
J. Ryssy, E. Prioste-Amaral, D. F. N. Assuncao, N. Rogers, G. T. S. Kirby, L. E. Smith, A. Michelmore, Phys. Chem. Chem. Phys. 2016, 18, 4496.
D. Hegemann, E. Körner, N. Blanchard, M. Drabik, S. Guimond, Appl. Phys. Lett. 2012, 101, 211603.
H. Deutsch, H. Kersten, S. Klagge, A. Rutscher, Contrib. Plasma Phys. 1988, 28, 149.
R. D'Agostino, F. Cramarossa, F. Fracassi, E. Desimoni, L. Sabbatini, P. G. Zambonin, G. Caporiccio, Thin Solid Films 1986, 143, 163.
F. J. Aparicio, D. Thiry, P. Laha, R. Snyders, Plasma Processes Polym. 2016, 13, 814.
D. Thiry, F. J. Aparicio, N. Britun, R. Snyders, Surf. Coat. Technol. 2014, 241, 2.
N. Vinx, P. Damman, P. Leclère, B. Bresson, C. Fretigny, C. Poleunis, A. Delcorte, D. Cossement, R. Snyders, D. Thiry, Soft Matter 2021, 17, 10032.
D. Thiry, N. Vinx, P. Damman, F. J. Aparicio, P. Y. Tessier, D. Moerman, P. Leclère, T. Godfroid, S. Desprez, R. Snyders, Plasma Processes Polym. 2020, 17, 2000119.
M. Li, J. Liang, X. Wang, M. Zhang, Sensors. 2020, 20, 371.
I. Hopp, A. Michelmore, L. E. Smith, D. E. Robinson, A. Bachhuka, A. Mierczynska, K. Vasilev, Biomaterials 2013, 34, 5070.
A. J. S. Ribeiro, Y.-S. Ang, J.-D. Fu, R. N. Rivas, T. M. A. Mohamed, G. C. Higgs, D. Srivastava, B. L. Pruitt, Proc. Natl. Acad. Sci. USA 2015, 112, 12705.
D. Thiry, N. Britun, S. Konstantinidis, J.-P. Dauchot, M. Guillaume, J. Cornil, R. Snyders, J. Phys. Chem. C 2013, 117, 9843.
C. Poleunis, V. Cristaudo, A. Delcorte, J. Am. Soc. Mass Spectrom. 2017, 29, 4.
K. L. Johnson, K. Kendall, A. Roberts, Proc. R. Soc. A. Math. Phys. Sci. 1971, 324, 301.
H. Yasuda, C. Wang, J. Polym. Sci., Part A: Polym. Chem. 1985, 23, 87.
T. B. Casserly, K. K. Gleason, Chem. Vap. Deposition 2006, 12, 59.
A. Kwaśniewska, M. Świetlicki, A. Prószyński, G. Gładyszewski, Polymers 2021, 13, 244.
P. Trtik, J. Kaufmann, U. Volz, Cem. Concr. Res. 2012, 42, 215.
S. Ligot, E. Bousser, D. Cossement, J. Klemberg-Sapieha, P. Viville, P. Dubois, R. Snyders, Plasma Processes Polym. 2015, 12, 508.
V. R. Gowariker, N. Viswanathan, J. Sreedhar, Polymer Science, New Age International, New Delhi, India 1986.
K. Bandzierz, L. Reuvekamp, J. Dryzek, W. Dierkes, A. Blume, D. Bielinski, Materials 2016, 9, 607.
K. L. Ngai, Physical Properties of Polymers, 3rd ed., Cambridge University Press, Cambridge, 2004.
H. H. Winter, F. Chambon, J. Rheol. 1986, 30, 367.
M. K. Mundra, C. J. Ellison, P. Rittigstein, J. M. Torkelson, Eur. Phys. J.: Spec. Top. 2007, 141, 143.
D. Cossement, F. Renaux, D. Thiry, S. Ligot, R. Francq, R. Snyders, Appl. Surf. Sci. 2015, 355, 842.
T. R. Gengenbach, Z. R. Vasic, S. Li, R. C. Chatelier, H. J. Griesser, Plasmas and Polym. 1997, 2, 91.
T. R. Gengenbach, H. J. Griesser, J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 985.
T. R. Gengenbach, Z. R. Vasic, R. C. Chatelier, H. J. Griesser, J. Polym. Sci., Part A: Polym. Chem. 1994, 32, 1399.
M. Buddhadasa, P.-L. Girard-Lauriault, Thin Solid Films 2015, 591, 76.
D. Thiry, A. Chauvin, A. A. El Mel, C. Cardinaud, J. Hamon, E. Gautron, N. Stephant, A. Granier, P. Y. Tessier, Plasma Processes Polym. 2017, 14, 1700042.
E. Kasparek, D. Thiry, J. R. Tavares, M. R. Wertheimer, R. Snyders, P. L. Girard-Lauriault, Plasma Processes Polym. 2018, 15, 1800036.
D. Thiry, R. Francq, D. Cossement, D. Guerin, D. Vuillaume, R. Snyders, Langmuir. 2013, 29, 13183.
D. Thiry, F. Reniers, R. Snyders, Surface Modification of Polymers: Methods and Applications, Wiley, Hoboken, USA 2019, p. 67.
A. von Keudell, Plasma Sources Sci. Technol. 2000, 9, 455.
J. Friedrich, Plasma Processes Polym. 2011, 8, 783.
M. Scheffler, C. Stampfl, Electron. Struct. 2000, 2, 286.
A. S. Raman, A. Vojvodic, Handbook of Materials Modeling: Applications: Current and Emerging Materials, Springer, New York, USA 2020, p. 1321.
B. A. De Moor, M.-F. Reyniers, G. B. Marin, Phys. Chem. Chem. Phys. 2009, 11, 2939.
D. Thiry, R. Francq, D. Cossement, M. Guillaume, J. Cornil, R. Snyders, Plasma Processes Polym. 2014, 11, 606.
R. H. S. Winterton, Contemp. Phys. 1970, 11, 559.
D. Hegemann, J. Phys. D: Appl. Phys. 2013, 46, 205204.
D. Hegemann, U. Schütz, E. Körner, Plasma Processes Polym. 2011, 8, 689.