Electronic, Optical and Magnetic Materials; Catalysis; Ceramics and Composites; Chemistry (all); Surfaces, Coatings and Films; Metals and Alloys; Materials Chemistry
Abstract :
[en] The lacunary monocharged anion [{Mo6Cli8}Cla5□a]- presents concomitantly a strongly electrophilic site and a nucleophilic one. This Janus character in terms of reactivity is confirmed by its gas phase reaction with [Br6Cs4K]- to form [{Mo6Cli8}Cla5Bra]2- and by its unusual self-reactivity leading to [{Mo6Cli8}Cla6]2- dianions.
Disciplines :
Chemistry
Author, co-author :
Denis, Antoine; Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique - UMR 6164, Rennes F-35000, France. david.rondeau@univ-rennes.fr
Tymínska, Nina; Univ Rennes, Institut des Sciences Chimiques de Rennes - UMR 6226, Rennes F-35000, France. karine.costuas@univ-rennes.fr
Delhaye, Thomas; Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique - UMR 6164, Rennes F-35000, France. david.rondeau@univ-rennes.fr
Molard, Yann ; Univ Rennes, Institut des Sciences Chimiques de Rennes - UMR 6226, Rennes F-35000, France. karine.costuas@univ-rennes.fr
Gerbaux, Pascal ; Université de Mons - UMONS > Faculté des Sciences > Service de Synthèse et spectrométrie de masse organiques
De winter, Julien ; Université de Mons - UMONS > Faculté des Sciences > Service de Synthèse et spectrométrie de masse organiques
Himdi, Mohamed; Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique - UMR 6164, Rennes F-35000, France. david.rondeau@univ-rennes.fr
Castel, Xavier ; Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique - UMR 6164, Rennes F-35000, France. david.rondeau@univ-rennes.fr
Costuas, Karine ; Univ Rennes, Institut des Sciences Chimiques de Rennes - UMR 6226, Rennes F-35000, France. karine.costuas@univ-rennes.fr
Cordier, Stéphane ; Univ Rennes, Institut des Sciences Chimiques de Rennes - UMR 6226, Rennes F-35000, France. karine.costuas@univ-rennes.fr
Rondeau, David; Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique - UMR 6164, Rennes F-35000, France. david.rondeau@univ-rennes.fr
Language :
English
Title :
Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo6Cl8}Cl5□]- (□ = lacuna).
Nguyen N. T. K. Lebastard C. Wilmet M. Dumait N. Renaud A. Cordier S. Ohashi N. Uchikoshi T. Grasset F. Sci. Technol. Adv. Mate. 2022 23 547 578 10.1080/14686996.2022.2119101 36212682
Kirakci K. Shestopalov M. A. Lang K. Coord. Chem. Rev. 2023 481 215048 10.1016/j.ccr.2023.215048
Pinkard A. Champsaur A. M. Roy X. Acc. Chem. Res. 2018 51 919 929 10.1021/acs.accounts.8b00016 29605996
Jena P. Sun Q. Chem. Rev. 2018 51 5755 5870 10.1021/acs.chemrev.7b00524
Castleman A. W. Khanna S. N. J. Phys. Chem. C 2009 113 2664 2675 10.1021/jp806850h
Su P. Warneke Z. Volke D. Espenship M. F. Hu H. Kawa S. Kirakci K. Hoffmann R. Laskin J. Wiebeler C. Warneke J. J. Am. Soc. Mass Spectrom. 2023 34 161 170 10.1021/jasms.2c00243 36630296
Kochnev V. K. Avdeeva V. V. Malinina E. A. Kuznetsov N. T. Russ. J. Inorg. Chem. 2014 59 1268 1275 10.1134/S0036023614110102
Rohdenburg M. Mayer M. Grellmann M. Jenne C. Borrmann T. Kleemiss F. Azov V. A. Asmis K. R. Grabowsky S. Warneke J. Angew. Chem., Int. Ed. 2017 56 7980 7985 10.1002/anie.201702237 28560843
Mayer M. van Lessen V. Rohdenburg M. Hou G. L. Yang Z. Exner R. M. Apra E. Azov V. A. Grabowsky S. Xantheas S. S. Asmis K. R. Wang X. B. Jenne C. Warneke J. Proc. Natl. Acad. Sci. U. S. A. 2019 116 8167 8172 10.1073/pnas.1820812116 30952786
Rohdenburg M. Azov V. A. Warneke J. Front. Chem. 2020 8 580295 10.3389/fchem.2020.580295 33282830
Zhong M. M. Fang H. Deepika Jena P. Phys. Chem. Chem. Phys. 2021 23 21496 21500 10.1039/D1CP01969D 34296724
Morokuma K. J. Chem. Phys. 1971 55 1236 10.1063/1.1676210
Kitaura K. Morokuma K. Int. J. Quantum Chem. 1976 10 325 340 10.1002/qua.560100211
Ziegler T. Rauk A. Theor. Chim. Acta 1977 46 1 10 10.1007/BF02401406
Ziegler T. Rauk A. Inorg. Chem. 1979 18 1755 1759 10.1021/ic50197a006
Ziegler T. Rauk A. Inorg. Chem. 1979 18 1558 1565 10.1021/ic50196a034
Raupach M. Tonner R. J. Chem. Phys. 2015 142 1-14 194105 10.1063/1.4919943 26001445
Parr R. G. Yang W. T. J. Am. Chem. Soc. 1984 106 4049 4050 10.1021/ja00326a036
Warneke J. Dulcks T. Knapp C. Gabel D. Phys. Chem. Chem. Phys. 2011 13 5712 5721 10.1039/C0CP02386H 21311775
Zhao T. S. Zhou J. Wang Q. Jena P. J. Phys. Chem. Lett. 2016 7 2689 2695 10.1021/acs.jpclett.6b00981 27351125
Harrison A. G. Rapid Commun. Mass Spectrom. 1999 13 1663 1670 10.1002/(SICI)1097-0231(19990830)13:16<1663::AID-RCM695>3.0.CO;2-T 10440985
Lock C. M. Dyer E. W. Rapid Commun. Mass Spectrom. 1999 13 422 431 10.1002/(SICI)1097-0231(19990315)13:5<422::AID-RCM503>3.0.CO;2-M
Klumpp D. A. Anokhin M. V. Molecules 2020 25 1-25 3281 10.3390/molecules25143281 32707680
Denis A., Rondeau D., Himdi M., Castel X. and Cordier S., Antennas having ion cluster type sensors, WO2021/175796A1 (PCT/EP2021/055080), 2021
